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The chemical properties of alicyclic heterocycles are similar to those of the corresponding chain compounds. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Conjugated Macrocycles in Organic Electronics, the main research direction is conjugated macrocycle organic electronics fullerene.Electric Literature of C8H12Cl2Pt.

This Account describes a body of research on the design, synthesis, and application of a new class of electronic materials made from conjugated macrocycles. Our macrocyclic design takes into consideration the useful attributes of fullerenes and what properties make fullerenes efficient n-type materials. We identified four electronic and structural elements: (1) a three-dimensional shape; (2) a conjugated and delocalized π-space; (3) the presence of an interior and exterior to the π-surface; and (4) low-energy unoccupied MOs allowing them to accept electrons. The macrocyclic design incorporates some of these properties, including a three-dimensional shape, an interior/exterior to the π-surface, and low-lying LUMOs maintaining the n-type semiconducting behavior, yet we also install synthetic flexibility in our approach in order to tune the properties further. Each of the macrocycles comprises perylenediimide cores wound together with linkers. The perylenediimide building block endows each macrocycle with the ability to accept electrons, while the synthetic flexibility to install different linkers allows us to create macrocycles with different electronic properties and sizes. We have created three macrocycles that all absorb well into the visible range of the solar spectrum and possess different shapes and sizes. We then use these materials in an array of applications that take advantage of their ability to function as n-type semiconductors, absorb in the visible range of the solar spectrum, and possess intramol. cavities. This Account will discuss our progress in incorporating these new macrocycles in organic solar cells, organic photodetectors, organic field effect transistors, and sensors. The macrocycles outperform acyclic controls in organic solar cells. We find the more rigid macrocyclic structure results in less intrinsic charges and lower dark current in organic photodetectors. Our macrocyclic-based photodetector has the highest detectivity of non-fullerene acceptors. The macrocycles also function as sensors and are able to recognize nuanced differences in analytes. Perylenediimide-based fused oligomers are efficient materials in both organic solar cells and field effect transistors. We will use the oligomers to construct macrocycles for use in solar energy conversion. In addition, we will incorporate different electron-rich linkers in our cycles in an attempt to engineer the HOMO/LUMO gap further. Looking further into the future, we envision opportunities in applying these conjugated macrocycles as electronic host/guest materials, as concatenated electronic materials by threading the macrocycles with electroactive oligomers, and as a locus for catalysis that is driven by light and elec. fields.

Here is a brief introduction to this compound(12080-32-9)Electric Literature of C8H12Cl2Pt, if you want to know about other compounds related to this compound(12080-32-9), you can read my other articles.

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Synthetic Route of 92409-15-9, The major producers of chemicals have been the Europe, Japan and China. Due to the growing call for a cleaner, greener environment, people will have to find innovative ways to maintain their relevance. Here is a compound 92409-15-9, name is 2-(2-Methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol. This compound has unique chemical properties. The synthetic route is as follows.

1 part by weight of the compound2- (2-methoxyphenoxy) -1- (4-methoxyphenyl) -1-hydroxy-3-propanol and 1.8 parts by weightAl (NO3) 3 was added to 30 parts by weight of methanol,Set the microwave reactor power of 50W,Microwave frequency of 2450MHz, microwave-assisted heating at 80 for 40min.After completion of the reaction, the reaction was quenched with cold water immediately,The reaction solution was extracted with ethyl acetate,Take organic phase spin dry,Followed by further separation and purification by silica gel column chromatography,The mobile phase of ethyl acetate and n-hexane volume ratio of 1: 1, evaporated to dry the solvent that methylation products.

According to the analysis of related databases, 92409-15-9, the application of this compound in the production field has become more and more popular.

Reference:
Patent; South China University of Technology; Qiu, Xueqing; Ouyang, Xinping; Zhu, Guodian; Chen, Cheng; Jin, Dongxue; Zhao, Ying; (10 pag.)CN106117021; (2016); A;,
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In the next few decades, the world population will flourish. As the population grows rapidly and people all over the world use more and more resources, all industries must consider their environmental impact. 5617-32-3, name is 3,6,9,12,15,18-Hexaoxaicosane-1,20-diol, the common compound, a new synthetic route is introduced below. SDS of cas: 5617-32-3

General procedure: (Using the synthesis of macrocyclic sulfate 6a as an example). To a stirring solution of tetra(ethylene glycol) 5a (40.0 g, 205.95 mmol), triethylamine (100.73 g, 988.56 mmol), and DMAP (1.26 g, 10.30 mmol) in CH2Cl2 (3 L) at 0 °C was slowly added a solution of SOCl2 (50.30 g, 411.90 mmol, in 50 mL CH2Cl2). After the addition, the stirring mixture was warmed to 25 °C and monitored with TLC until the complete consumption of tetra(ethylene glycol). The reaction was quenched with 1.5 L water. The organic layer was collected, filtrated through a pad of silica gel, and concentrated under vacuum to provide the macrocyclic sulfite intermediate as brownish oil which was used directly in the next step. To the solution of macrocyclic sulfite in a mixture of CH2Cl2 (200 mL), CH3CN (200 mL), and water (300 mL) at 0 °C was added NaIO4 (52.86 g, 247.14 mmol) and RuCl3?3H2O (0.27 g, 1.03 mmol). The stirring mixture was gradually warmed to 25 °C and monitored with TLC. Upon complete consumption of the macrocyclic sulfite, the reaction mixture was filtered through a pad of Celite. Organic layer was collected, washed with brine, concentrated under vacuum, and recrystallized in methanol at -20 °C to afford the macrocyclic sulfate 6a as clear crystal (25.14 g, 47percent yield).

The synthetic route of 5617-32-3 has been constantly updated, and we look forward to future research findings.

Reference:
Article; Deng, Tao; Mao, Xianglan; Xiao, Yan; Yang, Zhigang; Zheng, Xing; Jiang, Zhong-Xing; Bioorganic and Medicinal Chemistry Letters; vol. 29; 4; (2019); p. 581 – 584;,
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Application of 5617-32-3 , The common heterocyclic compound, 5617-32-3, name is 3,6,9,12,15,18-Hexaoxaicosane-1,20-diol, molecular formula is C14H30O8, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc., below Introduce a new synthetic route.

6.2 3,6,9,12,15,18,21-Heptaoxahexacos-25-en-1-ol (2) To an anhydrous THF solution of NaH (0.39 g of 45percent in mineral oil, 10.1 mmol) was added heptaethylene glycol (1, 3 g, 9.2 mmol) drop wise at 4 °C. After 30 min, 1-bromopentene (1.18 mL, 10.1 mmol) was added slowly to the above solution. The reaction mixture allowed to warm to room temperature and then stirred under N2 for 14 h. The reaction was quenched by addition of methanol at 0 °C, the solvent was evaporated and 200 mL of water was added to the residue which was then extracted with ethyl acetate (100 mL, 3*). The organic layers were washed with brine, dried over Na2SO4, and the solvent was evaporated under reduced pressure. Purification by flash column chromatography over silica gel with 1percent methanol in dichloromethane gave pure color less oil 2: Rf: 0.41 (4percent MeOH in DCM); yield: 1.86 g, 52percent, 1H NMR (400 MHz; CDCl3) delta 5.82 (ddtd, J = 16.9, 10.2, 6.6, 1.9 Hz, 1H), 5.07-4.90 (m, 2H), 3.79-3.53 (m, 28H), 3.47 (td, J = 6.7, 1.8 Hz, 2H), 2.61 (t, J = 6.2 Hz, 1H), 2.11 (dtt, J = 8.0, 6.7, 1.4 Hz, 2H), 1.74-1.62 (m, 2H); 13C NMR (CDCl3; 100 MHz) delta 132.2, 114.6, 77.4, 76.9, 76.6, 70.6, 70.5, 70.0, 69.9, 50.6, 30.2, 28.7; MS m/z [M+H]+ calcd for C19H39O8 394.2, found 394.2; MS m/z [M+Na]+ calcd for C19H38O8Na 417.2, found 417.2.

The synthetic route of 5617-32-3 has been constantly updated, and we look forward to future research findings.

Reference:
Article; Biswas, Souvik; Medina, Scott H.; Barchi, Joseph J.; Carbohydrate Research; vol. 405; (2015); p. 93 – 101;,
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Reference of 92409-15-9, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 92409-15-9, name is 2-(2-Methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol, molecular formula is C17H20O5, The compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.

The 152 mg type g shown in lignin of beta – O – 4 model compound, 8 mg double rhodium catalyst, 80 mg NaOH added 1 ml distilled water, under protection of argon 110 C reaction 18 hours, to complete the lignin complete degradation, wherein the degradation product to the methoxy acetophenone of yield is 24%, P-acetone to yield 34%, O-methoxyphenol of yield is 62%.

While traditionally a conservative industry, chemical producers will need to modernize their PR strategies to stay relevant.we look forward to future research findings about 92409-15-9, 2-(2-Methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol.

Reference:
Patent; Shaanxi Normal University; Dalian Institute of Chemical Physics; Wang Chao; Liu Yuxuan; Li Changzhi; Xiao Jianliang; Wang Aiqin; Zhang Tao; Li Junjun; Xue Dong; Tang Weijun; (9 pag.)CN107253904; (2017); A;,
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Electric Literature of 92409-15-9 ,Some common heterocyclic compound, 92409-15-9, molecular formula is C17H20O5, its traditional synthetic route has been very mature, but the traditional synthetic route has various shortcomings, such as complicated route, low yield, poor purity, etc., below Introduce a new synthetic route.

General procedure: The catalytic hydrogenolysis of lignin model compounds was performedusing a 50 mL Zr-alloy autoclave provided by Anhui KemiMachinery Technology Co., Ltd. For a typical procedure, lignin modelcompounds (0.5 mmol or 1 mmol) or organosolv lignin (35 mg), heterogeneousFe catalyst (100 mg), and solvent (20 mL) were added intothe autoclave with a quartz lining. After purging the reactor with H2,the reaction was conducted with 1 MPa H2 (at room temperature) at240 C for 12 h with a stirring speed of 800 rpm. After reaction, internalstandards are added to the product solution, and then the liquid productswere analyzed by using both GC and GC-MS. For the conversionof alpha-O-4 lignin model compound, 2-phenylethanol is used as internalstandard to determine the yields of benzyl alcohol and phenol, anddodecane is used to determine the yield of toluene. For the conversionof beta-O-4 lignin model compounds, benzyl alcohol and dodecane areused as internal standards to determine the yields of phenolic fragmentsand aromatic fragments, respectively. A representative GC spectrumcan be seen in Fig. S11 in supporting information. GC-MS analyses wereperformed on an Agilent 7890 Gas Chromatograph equipped with a DBWAXETR30m×0.25 mm×0.25mm capillary column (Agilent) or aHP-5MS 30m×0.25 mm×0.25mm capillary column (Agilent).Although HP-5MS column is unsuitable for the determination of productsyields due to the low polarity, it can be used to confirm whethersome complex lignin model compounds were completely converted.The GC was directly interfaced to an Agilent 5977 mass selective detector(EI, 70 eV). The following GC oven temperature programs wereused: 40 C hold for 1 min, ramp 5 C min-1 to a temperature of 120 C,and then ramp 10 C min-1 to 300 C and hold for 5 min. To get the representative GC spectrum of gaseous products, the gaseous phase wascollected and injected into a Fuli 9790II Gas Chromatograph equippedwith a TDX-01 packed column and a thermal conductivity detector(TCD) through a six-way valve to analyze the composition.

These compound has a wide range of applications. It is believed that with the continuous development of the source of the synthetic route,92409-15-9, its application will become more common.

Reference:
Article; Li, Jiang; Sun, Hui; Liu, Jia-xing; Zhang, Jun-jie; Li, Zhen-xing; Fu, Yao; Molecular catalysis; vol. 452; (2018); p. 36 – 45;,
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Each compound has different characteristics, and only by selecting the characteristics of the compound suitable for a specific situation can the compound be applied on a large scale. 94687-10-2, name is Ethyl 3-(3,4-dimethoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propanoate. This compound has unique chemical properties. The synthetic route is as follows. Computed Properties of C20H24O7

£’rytftro-l-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)-l,3-propanediol (2g): (0178) (0179) 2g (0180) Scheme 8. Synthesis of i?? i zro-l-(3,4-dimethoxyphenyl)-2-(2-methoxyphenoxy)-l,3- propanediol (2g). This compound was prepared according to a literature procedure. (Buendia, J. ; (0181) Mottweiler, J.; Bolm, C. Chem. Eur. J. 2011, 17, 13877.) Spectral data were consistent with those reported in the literature. *H NMR (400 MHz, CDC13) delta 7.07 (ddd, J = 8.2 Hz, 7.2, 1.6, 1.6 Hz, 1H), 7.02-6.84 (M, 5H), 6.82 (D, J = 8.2 Hz, 1H), 4.98 (b t, J = 4.8 Hz, 1 H), 4.16 (ddd, J = 6.0, 4.8, 3.5 Hz, 1 H), 3.95-3.90 (m, 1H), 3.87 (s, 3H), 3.86 (s, 6H), 3.66 (ddd, J = 12.0, 7.2, 3.5 Hz, 1H), 2.87 ppm (b s, 1H). HRMS (EI) calculated for C18H2206Na [M + Na]+ 357.1314, found 357.1311.

If you are interested in these compounds, you can also browse my other articles.Thank you for taking the time to read this article. I hope you enjoyed it, 94687-10-2, Ethyl 3-(3,4-dimethoxyphenyl)-3-hydroxy-2-(2-methoxyphenoxy)propanoate.

Reference:
Patent; WISCONSIN ALUMNI RESEARCH FOUNDATION; STAHL, Shannon, S.; COON, Joshua; RAHIMI, Alireza; ULBRICH, Arne; WO2015/138563; (2015); A1;,
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Application of 92409-15-9, As we all know, there are many different methods for the synthesis of a compound, and people can choose the synthesis method that suits their own laboratory according to the actual situation. 92409-15-9, name is 2-(2-Methoxyphenoxy)-1-(4-methoxyphenyl)propane-1,3-diol, molecular formula is C17H20O5, The compound is widely used in many fields, so it is necessary to find a new synthetic route. The downstream synthesis method of this compound is introduced below.

In 5 ml of quartz optical reaction tube, adding 0.05 mmol 2-(2-methoxyphenoxy)-1-(4-methoxyphenyl)-1,3-propanediol, 5 mg mpg-C3N4Catalyst, magneton, and add 1 ml solvent acetonitrile (substrate concentration is 0.05 mol/L). Air above the oxygen displacement reaction tube, and the opening is sealed, is arranged in the integrated light in the reaction device, the rotating speed of 500 r/min, the illumination wavelength is 405 nm (the power of 6 W), temperature constant at 40C, reaction 8 h. After the reaction, gas chromatography – mass spectrum detecting the product, and for high performance liquid chromatography quantitative, substrate conversion and product yield is shown in table 1.

According to the analysis of related databases, 92409-15-9, the application of this compound in the production field has become more and more popular.

Reference:
Patent; Dalian Institute of Chemical Physics; Wang Feng; Liu Huifang; Wang Min; Li Hongji; Luo Nengchao; Su Kaiyi; (14 pag.)CN109456160; (2019); A;,
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Synthetic Route of 24131-31-5, With the rapid development and complex challenges of chemical substances, the synthesis of new drugs is usually one of the most effective ways to increase yield.24131-31-5, name is (3,5-Bis(benzyloxy)phenyl)methanol, molecular formula is C21H20O3, molecular weight is 320.3817, as common compound, the synthetic route is as follows.

General procedure: 3-Hydroxybenzaldehyde (5.00 g, 0.041 mol) was dissolved in anhydrous acetonitrile (130 mL) under argon atmosphere. Cesium carbonate (20.01 g, 0.061 mol) was added and the suspension stirred for 5 min. Benzyl bromide (11.69 mL, 0.102 mol) was then added and the solution heated at reflux for 16 h. The solution was concentrated on rotary evaporator, water was added and the mixture was extracted with EtOAc. The organic phase was washed twice with water, once with brine, dried over MgSO4, filtered and concentrated. Water was added and the mixture was extracted with CH2Cl2. The crude product was purified by flash chromatography on silica gel with hexanes/EtOAc (80/20) to yield 3a as a white solid (8.59 g). 1H NMR delta (CDCl3) 5.13 (s, 2H, PhCH2O), 5.33 (s, 2H, COOCH2Ph), 7.35-7.50 (m, 9H, 2-CH, 4-CH, 5-CH, 6-CH and PhCH2O), 10.00 (s, 1H, PhCHO). The aldehyde 3a was dissolved in anhydrous THF (200 mL) under argon and cooled to 0 C. Lithium aluminum hydride (1.55 g, 0.041 mol) was added in small portions and the solution stirred at room temperature for 2 h. The reaction was then quenched using water (0.8 mL), a 10% wt aqueous NaOH solution (1.15 mL) and water again (1.9 mL) and left to settle. The suspension was then filtered and concentrated. Water was added and the mixture extracted with EtOAc, the organic phase dried over MgSO4, filtered and concentrated to yield 7.07 g crude alcohol 3b. 1H NMR delta (CDCl3) 4.68 (s, 2H, PhCH2OH), 5.08 (s, 2H, PhCH2O), 6.90-7.46 (m, 9H, 2-CH, 4-CH, 5-CH, 6-CH and PhCH2O). Crude alcohol 3b (7.06 g) was dissolved in anhydrous CH2Cl2 (330 mL) and the solution cooled to 0 C. Triphenylphosphine (17.28 g, 0.066 mol) and carbon tetrabromide (21.85 g, 0.066 mol) were then added and the solution stirred at room temperature for 2 h. The reaction mixture was quenched with water and extracted with CH2Cl2. The organic phase was dried over MgSO4, filtered and concentrated. The product was purified by flash chromatography on silica gel with hexanes/EtOAc (9/1) to yield 5.85 g (64%) of bromide 3c.

Statistics shows that 24131-31-5 is playing an increasingly important role. we look forward to future research findings about (3,5-Bis(benzyloxy)phenyl)methanol.

Reference:
Article; Fournier, Diane; Poirier, Donald; European Journal of Medicinal Chemistry; vol. 46; 9; (2011); p. 4227 – 4237;,
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Researchers who often do experiments know that organic synthesis is a process of preparing more complex target molecules from simple raw materials through one or more chemical reactions. Generally, it requires fewer steps,and cheap raw materials. 647-42-7, name is 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol. A new synthetic method of this compound is introduced below., Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol

STR4 2-(Perfluorohexyl)ethanol 18.2 g (0.05 mol), 5% Pd-C (pH 7.2) 1.5 g as a catalyst were charged in a 70 ml autoclave equipped with a hydrogen gas inlet and a stirrer, to which was added dropwise dodecylaldehyde 13.8 g (0.075 mol) under atmospheric pressure over 6 hours and stirring was conducted at 105 C. for 8 hours while hydrogen was flowed continuously at 15 ml/min. After reaction was completed, the catalyst was removed by filtration, and an excess of dodecylaldehyde was removed under reduced pressure to provide the objective dodecyl{2-(perfluorohexyl)ethyl}ether 25.3 g (0.048 mol) as a colorless, transparent liquid. Isolation yield was 95%.

If you are interested in these compounds, you can also browse my other articles.Thank you for taking the time to read this article. I hope you enjoyed it, 647-42-7, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol.

Reference:
Patent; Kao Corporation; US6002048; (1999); A;,
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