Tag: M.W=300-400

Reference of 647-42-7, In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl functional group (−OH) bound to a saturated carbon atom. 647-42-7, name is 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula CnH2n+1OH.

Cai, Aijie;Yan, Wenhao;Wang, Chao;Liu, Wei research published 《 Copper-Catalyzed Difluoromethylation of Alkyl Iodides Enabled by Aryl Radical Activation of Carbon-Iodine Bonds》, the research content is summarized as follows. A novel strategy that leveraged the halogen abstraction ability of aryl radicals, thereby engaging a diverse range of alkyl iodides in copper-catalyzed Negishi-type cross-coupling reactions at room temperature Specifically, aryl radicals generated via copper catalysis efficiently initiate the cleavage of the carbon-iodide bonds of alkyl iodides. The alkyl radicals thus generated enter the copper catalytic cycles to couple with a difluoromethyl zinc reagent, thus furnished the alkyl difluoromethane products. This unprecedented Negishi-type difluoromethylation approach was applied to the late-stage modification of densely functionalized pharmaceutical agents and natural products.

647-42-7, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, also known as 1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol , is a useful research compound. Its molecular formula is C8H5F13O and its molecular weight is 364.1 g/mol. The purity is usually 95%.

1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol is a material used to improve nanotube composites. It is also used in the synthesis of a recyclable fluorous hydrazine carbothioate compound with NCS to catalyze the acetalization of aldehydes.

1H,1H,2H,2H-Tridecafluoro-1-n-octanol is a potent and selective halogenated hydrocarbon. It binds to DNA at the dinucleotide phosphate site, which is an important site for polymerase chain reaction (PCR) activation. 1HFN has been shown to be more effective than other halogenated hydrocarbons in vitro assays on rat liver microsomes. It has been used as an additive in wastewater treatment to remove organic contaminants and metal ions. In vivo studies have been carried out in CD-1 mice to determine the effects of 1HFN on the liver and kidneys; these studies showed no toxicological effects on these organs. 1HFN also has been shown to inhibit enzymes such as cytochrome P450 and monoamine oxidase B that are involved in drug metabolism and may lead to adverse reactions with drugs metabolized by these enzymes., Reference of 647-42-7

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Simple alcohols are found widely in nature. Ethanol is the most prominent because it is the product of fermentation, a major energy-producing pathway. 647-42-7, formula is C8H5F13O, Other simple alcohols, chiefly fusel alcohols, are formed in only trace amounts. More complex alcohols however are pervasive, as manifested in sugars, some amino acids, and fatty acids. , HPLC of Formula: 647-42-7

Ayala-Cabrera, J. F.;Contreras-Llin, A.;Moyano, E.;Santos, F. J. research published 《 A novel methodology for the determination of neutral perfluoroalkyl and polyfluoroalkyl substances in water by gas chromatography-atmospheric pressure photoionization-high resolution mass spectrometry》, the research content is summarized as follows. Here, we developed and validated a new gas chromatog.-atm. pressure photoionization-high-resolution mass spectrometry (GC-APPI-HRMS) method combined with headspace solid-phase microextraction (HS-SPME) for the determination of neutral perfluoroalkyl and polyfluoroalkyl substances (PFASs) in water samples. The method includes fluorotelomer olefins (FTOs), fluorotelomer alcs. (FTOHs), fluoroctanesulfonamides (FOSAs) and sulfonamido-ethanols (FOSEs). The feasibility of the GC-APPI interface for the ionization of the target compounds was evaluated, achieving the best results using neg.-ion dopant-assisted ionization with acetone and a source and capillary temperatures of 225°C and 175°C, resp. Under optimal conditions, FTOs and FTOHs mass spectra showed intense in-source CID fragment ions from the fluoroalkyl chain but also the superoxide [M+O₂]^-• adduct ion. For FOSAs, [M-H]^– was the main ion generated, while FOSEs mass spectra showed fragment ions corresponding to the different cleavages of the functional group. The high ionization efficiency achieved with the GC-APPI interface provided limits of the detection lower than those obtained using traditional GC-MS ionization techniques, with a high sensitivity, selectivity and precision. For water anal., a fast and simple HS-SPME procedure was developed, avoiding evaporation steps, which could lead to the loss of the most volatile compounds The developed HS-SPME GC-APPI-HRMS method showed a good anal. performance for the anal. of river water samples, providing very low limits of detection (0.02-15 ng L^-1), good repeatability (RSD < 11%) and trueness (relative error < 12%).

HPLC of Formula: 647-42-7, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, also known as 1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol , is a useful research compound. Its molecular formula is C8H5F13O and its molecular weight is 364.1 g/mol. The purity is usually 95%.

1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol is a material used to improve nanotube composites. It is also used in the synthesis of a recyclable fluorous hydrazine carbothioate compound with NCS to catalyze the acetalization of aldehydes.

1H,1H,2H,2H-Tridecafluoro-1-n-octanol is a potent and selective halogenated hydrocarbon. It binds to DNA at the dinucleotide phosphate site, which is an important site for polymerase chain reaction (PCR) activation. 1HFN has been shown to be more effective than other halogenated hydrocarbons in vitro assays on rat liver microsomes. It has been used as an additive in wastewater treatment to remove organic contaminants and metal ions. In vivo studies have been carried out in CD-1 mice to determine the effects of 1HFN on the liver and kidneys; these studies showed no toxicological effects on these organs. 1HFN also has been shown to inhibit enzymes such as cytochrome P450 and monoamine oxidase B that are involved in drug metabolism and may lead to adverse reactions with drugs metabolized by these enzymes., 647-42-7.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Simple alcohols are found widely in nature. Ethanol is the most prominent because it is the product of fermentation, a major energy-producing pathway. 647-42-7, formula is C8H5F13O, Other simple alcohols, chiefly fusel alcohols, are formed in only trace amounts. More complex alcohols however are pervasive, as manifested in sugars, some amino acids, and fatty acids. , Product Details of C8H5F13O

Ayala-Cabrera, J. F.;Moyano, E.;Santos, F. J. research published 《 Gas chromatography and liquid chromatography coupled to mass spectrometry for the determination of fluorotelomer olefins, fluorotelomer alcohols, perfluoroalkyl sulfonamides and sulfonamido-ethanols in water》, the research content is summarized as follows. In this work, the suitability of gas chromatog.-mass spectrometry (GC-MS) and liquid chromatog.-tandem mass spectrometry (LC-MS/MS) for the multi-class determination of different families of neutral per- and polyfluoroalkyl substances (PFASs), such as fluorotelomer olefins (FTOs), alcs. (FTOHs) and fluorooctanesulfonamides (FOSAs) and sulfonamido-ethanolxs (FOSEs), was investigated and compared. Regarding GC-MS, the use of a semi-polar GC column (DB-624, 6%-cyanopropilphenyl 94%-di-Me polysiloxane) allowed the adequate separation of all the compounds while chem. ionization (CI) of pos. ions as ionization technique provided the best responses. Concerning UHPLC-MS/MS, atm. pressure chem. ionization (APCI) and photoionization (APPI) sources allowed the ionization of all studied neutral PFASs, including FTOs for the first time. High vaporizer temperatures (450°C) and acetonitrile/water mobile phase mixtures were required to favor the ionization of FTOs, with adequate ionization for FTOHs, FOSAs and FOSEs. The chromatog. separation, performed on a totally porous column (Luna C18), allowed the successful separation of the four families of neutral PFASs. After comparing the performance of the studied methods, the highest detectability was achieved using UHPLC-APCI-MS/MS and it was chosen in combination with a solid-phase extraction (SPE) procedure for the anal. of neutral PFASs in water samples. The whole method provided low limits of detection (0.003-6μg L^-1), good precision (RSD < 9%) and trueness (relative error < 10%). The methodol. was applied to the anal. of river water samples and the presence of some neutral PFASs were detected (8:2 FTO) and quantified (4:2 FTOH and N-EtFOSA) at low concentration levels (ng L^-1).

647-42-7, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, also known as 1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol , is a useful research compound. Its molecular formula is C8H5F13O and its molecular weight is 364.1 g/mol. The purity is usually 95%.

1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol is a material used to improve nanotube composites. It is also used in the synthesis of a recyclable fluorous hydrazine carbothioate compound with NCS to catalyze the acetalization of aldehydes.

1H,1H,2H,2H-Tridecafluoro-1-n-octanol is a potent and selective halogenated hydrocarbon. It binds to DNA at the dinucleotide phosphate site, which is an important site for polymerase chain reaction (PCR) activation. 1HFN has been shown to be more effective than other halogenated hydrocarbons in vitro assays on rat liver microsomes. It has been used as an additive in wastewater treatment to remove organic contaminants and metal ions. In vivo studies have been carried out in CD-1 mice to determine the effects of 1HFN on the liver and kidneys; these studies showed no toxicological effects on these organs. 1HFN also has been shown to inhibit enzymes such as cytochrome P450 and monoamine oxidase B that are involved in drug metabolism and may lead to adverse reactions with drugs metabolized by these enzymes., Product Details of C8H5F13O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Simple alcohols are found widely in nature. Ethanol is the most prominent because it is the product of fermentation, a major energy-producing pathway. 647-42-7, formula is C8H5F13O, Other simple alcohols, chiefly fusel alcohols, are formed in only trace amounts. More complex alcohols however are pervasive, as manifested in sugars, some amino acids, and fatty acids. , Computed Properties of 647-42-7

Targeted Single-Cell RNA and DNA Sequencing With Fluorescence-Activated Droplet Merger
Analyzing every cell in a diverse sample provides insight into population-level heterogeneity, but abundant cell types dominate the anal. and rarer populations are scarcely represented in the data. To focus on specific cell types, the current paradigm is to phys. isolate subsets of interest prior to anal.; however, it remains difficult to isolate and then single-cell sequence such populations because of compounding losses. Here, we describe an alternative approach that selectively merges cells with reagents to achieve enzymic reactions without having to phys. isolate cells. We apply this technique to perform single-cell transcriptome and genome sequencing of specific cell subsets. Our method for analyzing heterogeneous populations obviates the need for pre- or post-enrichment and simplifies single-cell workflows, making it useful for other applications in single-cell biol., combinatorial chem. synthesis, and drug screening.

647-42-7, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, also known as 1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol , is a useful research compound. Its molecular formula is C8H5F13O and its molecular weight is 364.1 g/mol. The purity is usually 95%.

1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol is a material used to improve nanotube composites. It is also used in the synthesis of a recyclable fluorous hydrazine carbothioate compound with NCS to catalyze the acetalization of aldehydes.

1H,1H,2H,2H-Tridecafluoro-1-n-octanol is a potent and selective halogenated hydrocarbon. It binds to DNA at the dinucleotide phosphate site, which is an important site for polymerase chain reaction (PCR) activation. 1HFN has been shown to be more effective than other halogenated hydrocarbons in vitro assays on rat liver microsomes. It has been used as an additive in wastewater treatment to remove organic contaminants and metal ions. In vivo studies have been carried out in CD-1 mice to determine the effects of 1HFN on the liver and kidneys; these studies showed no toxicological effects on these organs. 1HFN also has been shown to inhibit enzymes such as cytochrome P450 and monoamine oxidase B that are involved in drug metabolism and may lead to adverse reactions with drugs metabolized by these enzymes., Computed Properties of 647-42-7

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, In chemistry, an alcohol is a type of organic compound that carries at least one hydroxyl functional group (−OH) bound to a saturated carbon atom. 647-42-7, name is 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, An important class of alcohols, of which methanol and ethanol are the simplest examples, includes all compounds which conform to the general formula CnH2n+1OH.

The effect of weathering on per- and polyfluoroalkyl substances (PFASs) from durable water repellent (DWR) clothing
To assess the effects of weathering on per- and polyfluoroalkyl substances (PFASs) from durable water repellent (DWR) clothing, thirteen com. textile samples were exposed to elevated ultra violet (UV) radiation, humidity, and temperature in an aging device for 300 h, which mimics the lifespan of outdoor clothing. Before and after aging, the textile samples were extracted and analyzed for the ionic PFASs (perfluoroalkyl acids (PFAAs), perfluorooctane sulfonamide (FOSA)) and volatile PFASs (fluorotelomer alcs. (FTOHs), acrylates (FTACs) and methacrylates (FTMACs)). Results showed that weathering can have an effect on PFASs used in DWR of outdoor clothing, both on the PFAS profile and on the measured concentrations In most weathered samples the PFAA concentrations increased by 5- to more than 100-fold, while PFAAs not detected in the original textiles were detected in the weathered samples. DWR chemistries are based on side-chain fluorinated polymers. A possible explanation for the increase in concentration of the PFAAs is hydrolysis of the fluorotelomer based polymers (FTPs), or degradation of the FTOHs, which are used in the manufacturing of the FTPs. The concentrations of volatile PFASs also increased, by a factor up to 20. Suggested explanations are the degradation of the DWR polymers, making non-extractable fluorines extractable, or the transformation or degradation of unknown precursors. Further research is needed to unravel the details of these processes and to determine the transformation routes. This study shows that setting maximum tolerance limits only for a few individual PFASs is not sufficient to control these harmful substances in outdoor clothing.

Recommanded Product: 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, 3,3,4,4,5,5,6,6,7,7,8,8,8-Tridecafluorooctan-1-ol, also known as 1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol , is a useful research compound. Its molecular formula is C8H5F13O and its molecular weight is 364.1 g/mol. The purity is usually 95%.

1H,1H, 2H, 2H-Tridecafluoro-1-n-octanol is a material used to improve nanotube composites. It is also used in the synthesis of a recyclable fluorous hydrazine carbothioate compound with NCS to catalyze the acetalization of aldehydes.

1H,1H,2H,2H-Tridecafluoro-1-n-octanol is a potent and selective halogenated hydrocarbon. It binds to DNA at the dinucleotide phosphate site, which is an important site for polymerase chain reaction (PCR) activation. 1HFN has been shown to be more effective than other halogenated hydrocarbons in vitro assays on rat liver microsomes. It has been used as an additive in wastewater treatment to remove organic contaminants and metal ions. In vivo studies have been carried out in CD-1 mice to determine the effects of 1HFN on the liver and kidneys; these studies showed no toxicological effects on these organs. 1HFN also has been shown to inhibit enzymes such as cytochrome P450 and monoamine oxidase B that are involved in drug metabolism and may lead to adverse reactions with drugs metabolized by these enzymes., 647-42-7.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis, Coordination and Electrochemistry of a Ferrocenyl-Tagged Aminobisphosphane Ligand, published in 2021-09-24, which mentions a compound: 12080-32-9, Name is Dichloro(1,5-cyclooctadiene)platinum(II), Molecular C8H12Cl2Pt, Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II).

Group 10 element diphosphine square planar complexes [FcN(CH2PPh2)2MY2] (Fc = ferrocenyl; M = Ni, Pd, Pt; Y = Cl, Br), Group 11 tetraphosphine tetrahedral complexes [[FcN(CH2PPh2)2]2M]X (M = Cu, Ag, Au; X = BF4, SbF6) and gold binuclear complexes [FcN(CH2PPh2AuCl)2], [FcN(CH2PPh2)2Au]2[SbF6]2 were prepared and examined for their redox activity. Introducing a ferrocene moiety into a mol. results in the incorporation of a metal center and a redox active moiety. The ligand FcN(CH2PPh2)2 (1) was prepared by alkylation of ferrocenamine FcNH2 with hydroxymethylphosphine HOCH2PPh2 and converted to diselenide FcN(CH2P(Se)Ph2)2 (1-Se) for crystallog. identification. Furthermore, a pair of open and cyclic digold(I) complexes containing bis-phosphane 1 as a P,P-bridging ligand, were isolated. Ligand 1, the corresponding phosphane selenide 1-Se and all complexes (except for the poorly soluble [(μ(P,P’)-1)2Au2][SbF6] and unstable [Ag(1-κ2P,P’)2][SbF6]) were further analyzed by cyclic voltammetry.

Although many compounds look similar to this compound(12080-32-9)Quality Control of Dichloro(1,5-cyclooctadiene)platinum(II), numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

SDS of cas: 12080-32-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Laser-induced deposition of plasmonic Ag and Pt nanoparticles, and periodic arrays. Author is Mamonova, Daria V.; Vasileva, Anna A.; Petrov, Yuri V.; Danilov, Denis V.; Kolesnikov, Ilya E.; Kalinichev, Alexey A.; Bachmann, Julien; Manshina, Alina A..

Surfaces functionalized with metal nanoparticles (NPs) are of great interest due to their wide potential applications in sensing, biomedicine, nanophotonics, etc. However, the precisely controllable decoration with plasmonic nanoparticles requires sophisticated techniques that are often multistep and complex. Here, we present a laser-induced deposition (LID) approach allowing for single-step surface decoration with NPs of controllable composition, morphol., and spatial distribution. The formation of Ag, Pt, and mixed Ag-Pt nanoparticles on a substrate surface was successfully demonstrated as a result of the LID process from com. available precursors. The deposited nanoparticles were characterized with SEM, TEM, EDX, X-ray diffraction, and UV-VIS absorption spectroscopy, which confirmed the formation of crystalline nanoparticles of Pt (3-5 nm) and Ag (ca. 100 nm) with plasmonic properties. The advantageous features of the LID process allow us to demonstrate the spatially selective deposition of plasmonic NPs in a laser interference pattern, and thereby, the formation of periodic arrays of Ag NPs forming diffraction grating.

Although many compounds look similar to this compound(12080-32-9)SDS of cas: 12080-32-9, numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Epoxy compounds usually have stronger nucleophilic ability, because the alkyl group on the oxygen atom makes the bond angle smaller, which makes the lone pair of electrons react more dissimilarly with the electron-deficient system. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Bimetallic Platinum Group Complexes of a Macrocyclic Pyrazolate/NHC Hybrid Ligand.Safety of Dichloro(1,5-cyclooctadiene)platinum(II).

Authors present the synthesis, structural characterization, and photophys. properties of dinuclear PdII and PtII-NHC complexes Pd2L(PF6)2 and Pt2L(PF6)2 based on a macrocyclic calix[4]imidazolylidene[2]pyrazolate ligand obtained by in situ deprotonation of the tetraimidazolium salt H6L(PF6)4. The PtII congener was also prepared by transmetalation from previously published AgI pillarplex Ag8L2(PF6)4. NMR spectroscopy (1H, 13C, 195Pt) combined with SC-XRD studies elucidated the structure of the PdII and PtII complexes in the solid state and in solution The d8 metal ions of both congeners are coordinated in a slightly distorted square-planar arrangement. Similar to the previously reported NiII complex Ni2L(PF6)2, the heavier metal homologues adopt a bent, saddle-shaped structure. As observed for structurally similar PtII complexes in solution, bimetallic Pt2L(PF6)2 showed photoluminescence in the blue region. In the solid state, emission was observed at a similar energy with unusually short lifetimes compared to other monometallic PtII complexes. DFT and TDDFT studies shed light on the nature of the most bathochromic transitions, suggesting a significant pyrazolate- and NHC-centered π-π* character.

Although many compounds look similar to this compound(12080-32-9)Safety of Dichloro(1,5-cyclooctadiene)platinum(II), numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Electric Literature of C8H12Cl2Pt. The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Transmetalation Reactions of Aromatic Dilithionickelole: Synthesis of Heterobimetallic Complexes Featuring Metalloles as Diene Ligands. Author is Huang, Zhe; Zheng, Yu; Zhong, Mingdong.

Transmetalation of dilithionickelole I (1) with metal sources [MCl2Ln] afforded nickel-coordinated metallacycles II [2-6; MLn = Mg(THF)2, AlCl(THF), ScCp(THF), LuCp*ClLi(THF)3, Pt(COD)]. The aromatic metallole dianions are important metallaarom. compounds because of their various reactivities and extensive synthetic applications. Herein we report the reactions of dilithionickelole with MgCl2, EtAlCl2, Cp*ScCl2, Cp*LuCl2 and Pt(COD)Cl2 (COD = 1,5-cyclooctadiene) affording a series of Ni/M heterobimetallic complexes of the general formula [(η4-C4R4M)Ni(COD)], in which the metalloles act as diene ligands, as suggested by single-crystal X-ray, NMR and theor. analyses. In these reactions, two electrons of the nickelole dianion transferred to Ni, representing different reactivity compared with main-group metallole dianions.

Although many compounds look similar to this compound(12080-32-9)Electric Literature of C8H12Cl2Pt, numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Recommanded Product: 12080-32-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Synthesis and structure of thienyl Fischer carbene complexes of PtII for application in alkyne hydrosilylation. Author is Lamprecht, Zandria; Malan, Frederick P.; Lotz, Simon; Bezuidenhout, Daniela I..

Transmetalation of Group 6 thienylene Fischer carbene complexes to Pt(II) precursors yielded new examples of neutral Pt(II) bisethoxycarbene complexes with either 2-thienyl (T) or 5-thieno[2,3-b]thienylene (TT) carbene substituents. The use of analogous aminocarbene group 6 precursors proceeded to give isomeric Pt(II) product mixtures where the resultant bisaminocarbene ligands displayed different orientations due to restricted rotation around the Pt-aminocarbene bond caused by the sterically demanding TT substituents. The well-defined Pt(II) ethoxycarbene complexes were screened as catalyst precursors in the benchmark hydrosilylation reaction employing phenylacetylene and triethylsilane substrates. Marked selectivity for the β-E isomer (E)-triethyl(styryl)silane was observed, and the (pre)catalysts proved recyclable, active in solvent-free reactions, and displaying a high alkyne functional group tolerance.

Although many compounds look similar to this compound(12080-32-9)Recommanded Product: 12080-32-9, numerous studies have shown that this compound(SMILES:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-]), has unique advantages. If you want to know more about similar compounds, you can read my other articles.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts