Tag: M.W=100-150

Recently I am researching about N-PROPYLAMMONIUM PERRUTHENATE; ALCOHOLS, Saw an article supported by the Yasouj University; Iran National Science Foundation (INSF)Iran National Science Foundation (INSF). Quality Control of (4-Methoxyphenyl)methanol. Published in ROYAL SOC CHEMISTRY in CAMBRIDGE ,Authors: Mirbagheri, R; Elhamifar, D; Hajati, S. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A novel method was used to prepare a magnetic phenylene-based periodic mesoporous organosilica nanocomposite with yolk-shell structure (Fe3O4@YSPMO). The Fe3O4@YSPMO nanomaterial was prepared by using easily accessible pluronic-P123 and cetyltrimethylammonium bromide (CTAB) surfactants under basic conditions. This material was employed for effective immobilization of potassium perruthenate to prepare an Fe3O4@YSPMO@Ru nanocatalyst for the aerobic oxidation of alcohols. The physiochemical properties of the designed Fe3O4@YSPMO@Ru nanocomposite were studied using PXRD, FT-IR, TGA, SEM, TEM, ICP, VSM and XPS analyses. Fe3O4@YSPMO@Ru was effectively employed as a highly recoverable nanocatalyst in the selective aerobic oxidation of alcohols.

Quality Control of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Mirbagheri, R; Elhamifar, D; Hajati, S or concate me.

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I found the field of Chemistry; Science & Technology – Other Topics very interesting. Saw the article Bioinspired Radical-Mediated Transition-Metal-Free Synthesis of N-Heterocycles under Visible Light published in 2021. Application In Synthesis of (4-Methoxyphenyl)methanol, Reprint Addresses Adhikari, D (corresponding author), Indian Inst Sci Educ & Res IISER Mohali, Dept Chem Sci, Sas Nagar 140306, Punjab, India.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A redox-active iminoquinone motif connected with pi-delocalized pyrene core has been reported that can perform efficient two-electron oxidation of a class of substrates. The design of the molecule was inspired by the organic redox cofactor topaquinone (TPQ), which executes amine oxidation in the enzyme, copper amine oxidase. Easy oxidation of both primary and secondary alcohols happened in the presence of catalytic KOtBu, which could reduce the ligand backbone to its iminosemiquinonate form under photoinduced conditions. Moreover, this easy oxidation of alcohols under aerobic condition could be elegantly extended to multi-component, one-pot coupling for the synthesis of quinoline and pyrimidine. This organocatalytic approach is very mild (70 degrees C, 8 h) compared to a multitude of transition-metal catalysts that have been used to prepare these heterocycles. A detailed mechanistic study proves the intermediacy of the iminosemiquinonate-type radical and a critical hydrogen atom transfer step to be involved in the dehydrogenation reaction.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Bains, AK; Ankit, Y; Adhikari, D or concate me.

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K in ROYAL SOC CHEMISTRY published article about in [Kon, Yoshihiro; Nakashima, Takuya; Yada, Akira; Fujitani, Tadahiro; Onozawa, Shun-ya; Kobayashi, Shu; Sato, Kazuhiko] Natl Inst Adv Ind Sci & Technol, Interdisciplinary Res Ctr Catalyt Chem, Tsukuba, Ibaraki 3058565, Japan; [Kobayashi, Shu] Univ Tokyo, Sch Sci, Dept Chem, Bunkyo Ku, Tokyo 1130033, Japan in 2021, Cited 41. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The oxidation of alcohols to aldehydes is a powerful reaction pathway for obtaining valuable fine chemicals used in pharmaceuticals and biologically active compounds. Although many oxidants can oxidize alcohols, only a few hydrogen peroxide oxidations can be employed to continuously synthesize aldehydes in high yields using a liquid-liquid two-phase flow reactor, despite the possibility of the application toward a safe and rapid multi-step synthesis. We herein report the continuous flow synthesis of (E)-cinnamaldehyde from (E)-cinnamyl alcohol in 95%-98% yields with 99% selectivity for over 5 days by the selective oxidation of hydrogen peroxide using a catalyst column in which Pt is dispersed in SiO2. The active species for the developed selective oxidation is found to be zero-valent Pt(0) from the X-ray photoelectron spectroscopy measurements of the Pt surface before and after the oxidation. Using Pt black diluted with SiO2 as a catalyst to retain the Pt(0) species with the optimal substrate and H2O2 introduction rate not only enhances the catalytic activity but also maintains the activity during the flow reaction. Optimizing the contact time of the substrate with Pt and H2O2 using a flow reactor is important to proceed with the selective oxidation to prevent the catalytic H2O2 decomposition.

Recommanded Product: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kon, Y; Nakashima, T; Yada, A; Fujitani, T; Onozawa, SY; Kobayashi, S; Sato, K or concate me.

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Wu, D; Bu, QQ; Guo, C; Dai, B; Liu, N in [Wu, Di; Bu, Qingqing; Dai, Bin; Liu, Ning] Shihezi Univ, Sch Chem & Chem Engn, Key Lab Green Proc Chem Engn Xinjiang Bingtuan, North Fourth Rd, Shihezi 832003, Xinjiang, Peoples R China; [Guo, Cheng] Zhejiang Univ, Affiliated Hosp 2, Sch Med, Canc Inst, Hangzhou 310009, Zhejiang, Peoples R China published Cooperative catalysis of molybdenum with organocatalysts for distribution of products between amines and imines in 2021, Cited 73. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Multi-amino groups and nitrogen donors compound was discovered as an organocatalyst for N-alkylation of alcohols with amines in the presence of Mo(CO)6. The Mo(CO)6/organocatalyst binary system has shown to be a highly active catalyst for the N-alkylation reaction between alcohols and amines with excellent tolerance of variable starting materials bearing different functional groups. Of particular note, this method possessing a superiority selectivity in the synthesis of N-alkylated amines or imines, which can be controlled by the reaction temperature. The cooperative catalysis mechanism in combination of Mo(CO)6 with organocatalyst was elucidated by control experiments.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wu, D; Bu, QQ; Guo, C; Dai, B; Liu, N or concate me.. Product Details of 105-13-5

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I found the field of Chemistry very interesting. Saw the article Indium-Catalyzed Deoxygenation of Sulfoxides with Hydrosilanes published in 2021. Product Details of 105-13-5, Reprint Addresses Sakai, N (corresponding author), Tokyo Univ Sci RIKADAI, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Described herein is that a novel InBr3/PhSiH3 reducing system in a 1,4-dioxane solution smoothly and effectively undertook deoxygenation of a variety of sulfoxides leading to the facile preparation of sulfide derivatives. Also, it was demonstrated that the reducing system shows a higher reactivity towards sulfoxides than that towards commonly reducible functional groups, such as carboxylic acids, esters, amides, and sulfones.

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Sakai, N; Shimada, R; Ogiwara, Y or concate me.

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Safety of (4-Methoxyphenyl)methanol. Recently I am researching about DEPENDENT AMINE OXIDASES; AEROBIC OXIDATION; CATALYTIC MECHANISM; ALCOHOL OXIDATION; TOPA QUINONE; ACTIVE-SITE; COPPER; HYDROGEN; MODEL; PYRIMIDINES, Saw an article supported by the SERB (DST), India [ECR/2017/001764]; IISER Mohali. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Bains, AK; Ankit, Y; Adhikari, D. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A redox-active iminoquinone motif connected with pi-delocalized pyrene core has been reported that can perform efficient two-electron oxidation of a class of substrates. The design of the molecule was inspired by the organic redox cofactor topaquinone (TPQ), which executes amine oxidation in the enzyme, copper amine oxidase. Easy oxidation of both primary and secondary alcohols happened in the presence of catalytic KOtBu, which could reduce the ligand backbone to its iminosemiquinonate form under photoinduced conditions. Moreover, this easy oxidation of alcohols under aerobic condition could be elegantly extended to multi-component, one-pot coupling for the synthesis of quinoline and pyrimidine. This organocatalytic approach is very mild (70 degrees C, 8 h) compared to a multitude of transition-metal catalysts that have been used to prepare these heterocycles. A detailed mechanistic study proves the intermediacy of the iminosemiquinonate-type radical and a critical hydrogen atom transfer step to be involved in the dehydrogenation reaction.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Bains, AK; Ankit, Y; Adhikari, D or concate me.. Safety of (4-Methoxyphenyl)methanol

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Authors Li, DF; Wang, JG; Xu, FX; Zhang, NC; Men, Y in ROYAL SOC CHEMISTRY published article about EXPOSED 001 FACETS; SOOT OXIDATION ACTIVITY; VISIBLE PHOTOCATALYST; DOPED TIO2; PERCENTAGE; NANOCOMPOSITES; PERFORMANCE; NANOSHEETS; CATALYSTS; CRYSTALS in [Li, Dianfeng; Wang, Jinguo; Xu, Fengxia; Zhang, Nianchen; Men, Yong] Shanghai Univ Engn Sci, Sch Chem & Chem Engn, Shanghai 201620, Peoples R China in 2021, Cited 46. Recommanded Product: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Selective conversion of aromatic alcohols to value-added chemicals is becoming an emerging research hotspot in heterogeneous photocatalysis, but its critical challenge is how to construct highly efficient photocatalysts. Herein, mesoporous (001)-TiO2 nanocrystals with tailored Ti3+ and surface oxygen vacancies have been fabricated by a facile hydrothermal route, showing remarkably boosted photoactivity for selective conversion of aromatic alcohols to carbonyl compounds in water medium under visible-light irradiation. Results attest that the remarkably boosted photoactivity was mainly correlated with the strong synergetic effect of exposed (001) facets, Ti3+ self-doping, and surface oxygen vacancies, leading to the enhanced reactant (aromatic alcohols and O-2) activation via the high surface energy of (001) facets, the improved visible-light absorbance via the intrinsic band gap narrowing, and the escalated photoelectron-hole separation efficiency via Ti3+ and surface oxygen vacancies acting as electron sinks. Meanwhile, a plausible photocatalytic mechanism for selective conversion of aromatic alcohols to carbonyl compounds has been elucidated in detail based on active species identified by capture experiments. It is hoped that this work can deliver some new insights into the rational design of highly efficient photocatalysts applied in future green organic selective transformation reactions.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Li, DF; Wang, JG; Xu, FX; Zhang, NC; Men, Y or concate me.. Recommanded Product: 105-13-5

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Authors Wu, SP; Zhang, H; Cao, QE; Zhao, QH; Fang, WH in ROYAL SOC CHEMISTRY published article about in [Wu, Shipeng; Zhang, Hao; Cao, Qiue; Zhao, Qihua; Fang, Wenhao] Yunnan Univ, Sch Chem Sci & Technol, Key Lab Med Chem Nat Resource, Minist Educ,Funct Mol Anal & Biotransformat Key L, 2 North Cuihu Rd, Kunming 650091, Yunnan, Peoples R China; [Cao, Qiue; Fang, Wenhao] Yunnan Univ, Natl Demonstrat Ctr Expt Chem & Chem Engn Educ, Kunming 650091, Yunnan, Peoples R China in 2021, Cited 46. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Direct oxidative coupling of alcohols with amines using a non-precious metal oxide catalyst under mild conditions is highly desirable for imine synthesis. In this work, a mesoporous Mn1ZrxOy solid solution catalyst prepared by a co-precipitation method showed excellent catalytic performance in imine synthesis from primary alcohols and amines without base additives in an air atmosphere. XRD, N-2 physisorption, H-2-TPR, O-2-TPD, EPR and XPS were comprehensively used to unravel its structural, redox and amphoteric properties that closely depended on the interaction between MnOy and ZrO2 with a variable Zr ratio. The Mn1Zr0.5Oy catalyst presented the highest fractions of Mn3+ ions and reactive oxygen species on the surface, and the highest concentrations of acidic-basic sites, which were disclosed to play important roles in activating alcohols and molecular O-2 in the rate-determining step. In the model reaction of oxidative coupling of benzyl alcohol with aniline, such enhanced features of the Mn1Zr0.5Oy catalyst can promote the intrinsic catalytic activity (iTOF of 1.87 h(-1)) and boost benzylideneaniline formation (5.56 mmol g(cat).(-1) h(-1)) based on a >99% yield at 80 degrees C respectively at a fast response. It can also work effectively at a room temperature of 30 degrees C, as well as for the gram-grade synthesis. This is one of the best results among all the MnOy-based catalysts in the literature. Moreover, this catalyst showed good stability and a wide substrate scope with good to excellent yields of imines.

COA of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Wu, SP; Zhang, H; Cao, QE; Zhao, QH; Fang, WH or concate me.

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HPLC of Formula: C8H10O2. Bains, AK; Ankit, Y; Adhikari, D in [K. Bains, Amreen; Adhikari, Debashis] Indian Inst Sci Educ & Res IISER Mohali, Dept Chem Sci, Sas Nagar 140306, Punjab, India; [Ankit, Yadav] Indian Inst Sci Educ & Res IISER Mohali, Dept Earth & Environm Sci, Sas Nagar 140306, Punjab, India published Bioinspired Radical-Mediated Transition-Metal-Free Synthesis of N-Heterocycles under Visible Light in 2021, Cited 42. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A redox-active iminoquinone motif connected with pi-delocalized pyrene core has been reported that can perform efficient two-electron oxidation of a class of substrates. The design of the molecule was inspired by the organic redox cofactor topaquinone (TPQ), which executes amine oxidation in the enzyme, copper amine oxidase. Easy oxidation of both primary and secondary alcohols happened in the presence of catalytic KOtBu, which could reduce the ligand backbone to its iminosemiquinonate form under photoinduced conditions. Moreover, this easy oxidation of alcohols under aerobic condition could be elegantly extended to multi-component, one-pot coupling for the synthesis of quinoline and pyrimidine. This organocatalytic approach is very mild (70 degrees C, 8 h) compared to a multitude of transition-metal catalysts that have been used to prepare these heterocycles. A detailed mechanistic study proves the intermediacy of the iminosemiquinonate-type radical and a critical hydrogen atom transfer step to be involved in the dehydrogenation reaction.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Bains, AK; Ankit, Y; Adhikari, D or concate me.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB in AMER CHEMICAL SOC published article about in [Feng, Xuanyu; Pi, Yunhong; Song, Yang; Xu, Ziwan; Lin, Wenbin] Univ Chicago, Dept Chem, Chicago, IL 60637 USA; [Pi, Yunhong; Li, Zhong] South China Univ Technol, Sch Chem & Chem Engn, Guangzhou 510640, Peoples R China in 2021, Cited 63. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report here the construction of two metal-organic frameworks (MOFs), Zr-6-Cu/Fe-1 and Zr-6–Cu/Fe-2, by integrating earth-abundant cuprous photosensitizers (Cu-PSs) and Fe catalysts for photocatalytic aerobic oxidation. Site isolation and pore confinement stabilize both Cu-PSs and Fe catalysts, while the proximity between active centers facilitates electron and mass transfer. Upon visible light irradiation and using O-2 as the only oxidant, Zr-6-Cu/Fe-1 and Zr-6-Cu/ Fe-2 efficiently oxidize alcohols and benzylic compounds to afford corresponding carbonyl products with broad substrate scopes, high turnover numbers of up to 500 with a 9.4-fold enhancement over homogeneous analogues, and excellent recyclability in four consecutive runs. Control experiments, spectroscopic evidence, and computational studies revealed the photooxidation mechanism: oxidative quenching of [Cu-PS]* by O-2 affords [Cu-II-PS], which efficiently oxidizes Fe-III-OH to generate a hydroxyl radical for substrate oxidation. This work highlights the potential of MOFs in promoting earth-abundant metal-based photocatalysis.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Feng, XY; Pi, YH; Song, Y; Xu, ZW; Li, Z; Lin, WB or concate me.

Reference:
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