Tag: M.W=100-150

Formula: C8H10O2. Chahboun, R; Botubol-Ares, JM; Duran-Pena, MJ; Jimenez, F; Alvarez-Manzaneda, R; Alvarez-Manzaneda, E in [Botubol-Ares, Jose Manuel; Jesus Duran-Pena, Maria] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Campus Univ Rio San Pedro S-N,4a Planta, Cadiz 11510, Spain; [Chahboun, Rachid; Jimenez, Fermin; Alvarez-Manzaneda, Enrique] Univ Granada, Fac Ciencias, Inst Biotecnol, Dept Quim Organ, Granada 18071, Spain; [Alvarez-Manzaneda, Ramon] Univ Almeria, Dept Quim & Fis, Area Quim Organ, Almeria 04120, Spain published Deconjugative alpha-Alkylation of Cyclohexenecarboxaldehydes: An Access to Diverse Terpenoids in 2021, Cited 37. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A general and efficient method for the deconjugative alpha-alkylation of alpha,beta-unsaturated aldehydes promoted by a synergistic effect between (BuOK)-Bu-t and NaH, which considerably increases the reaction rate under mild conditions, is reported. The beta,gamma-unsaturated aldehyde, resulting from the alpha-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Chahboun, R; Botubol-Ares, JM; Duran-Pena, MJ; Jimenez, F; Alvarez-Manzaneda, R; Alvarez-Manzaneda, E or concate me.

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Application In Synthesis of (4-Methoxyphenyl)methanol. Authors Uygur, M; Kuhlmann, JH; Perez-Aguilar, MC; Piekarski, DG; Mancheno, OG in ROYAL SOC CHEMISTRY published article about in [Uygur, Mustafa; Kuhlmann, Jan H.; Perez-Aguilar, Maria Carmen; Piekarski, Dariusz G.; Mancheno, Olga Garcia] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Correnstr 36, D-48149 Munster, Germany; [Piekarski, Dariusz G.] Polish Acad Sci, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland in 2021, Cited 80. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A metal- and additive-free methodology for the highly selective, photocatalyzed C-H oxygenation of alkylarenes under air to the corresponding carbonyls is presented. The process is catalyzed by an imide-acridinium that forms an extremely strong photooxidant upon visible light irradiation, which is able to activate inert alkylarenes such as toluene. Hence, this is an easy to perform, sustainable and environmentally friendly oxidation that provides valuable carbonyls from abundant, readily available compounds.

Application In Synthesis of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Uygur, M; Kuhlmann, JH; Perez-Aguilar, MC; Piekarski, DG; Mancheno, OG or concate me.

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I found the field of Chemistry very interesting. Saw the article Highly Regioselective 5-endo-tet Cyclization of 3,4-Epoxy Amines into 3-Hydroxypyrrolidines Catalyzed by La(OTf)(3) published in 2021. Formula: C8H10O2, Reprint Addresses Iwabuchi, Y (corresponding author), Tohoku Univ, Dept Organ Chem, Grad Sch Pharmaceut Sci, Aoba Ku, 6-3 Aoba, Sendai, Miyagi 9808578, Japan.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Highly regioselective intramolecular aminolysis of 3,4-epoxy amines has been achieved. Key features of this reaction are (1) chemoselective activation of epoxides in the presence of unprotected aliphatic amines in the same molecules by a La(OTf)(3) catalyst and (2) excellent regioselectivity for anti-Baldwin 5-endo-tet cyclization. This reaction affords 3-hydroxy-2-alkylpyrrolidines stereospecifically in high yields. DFT calculations revealed that the regioselectivity might be attributed to distortion energies of epoxy amine substrates. The use of this reaction was demonstrated by the first enantioselective synthesis of an antispasmodic agent prifinium bromide.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kuriyama, Y; Sasano, Y; Hoshino, Y; Uesugi, S; Yamaichi, A; Iwabuchi, Y or concate me.

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Formula: C8H10O2. Hosseini, ES; Heydar, KT in [Hosseini, Elham Sadat; Tabar Heydar, Kourosh] Chem & Chem Engn Res Ctr Iran, Fac Clean Technol, Tehran, Iran published Preparation and evaluation a mixed-mode stationary phase with C-18 and 2-methylindole for HPLC in 2021, Cited 42. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A modified C-18 column (Silpr-2MI-C18) was prepared using 2-methylindole and C-18 reagent. The extent of C-18 hydrocarbon chain, conjugative rings and anion exchange site provided multiple retention mechanisms, including reversed-phase liquid chromatography (RPLC), pi-pi interaction, hydrophilic interaction liquid chromatography (HILIC) and anion exchange chromatography (AEC). The separation of protected amino acids was investigated on the commercial C-18 and Silpr-2MI-C18 columns, while the chromatographic conditions, including methanol content and pH of the mobile phase, were studied. The separation arrangement of the hydrophilic amino acids was different on the Silpr-2MI-C18 column compared to the commercial C-18 column under RPLC mode. Furthermore, these amino acids were separated on the Silpr-2MI-C18 column under HILIC mode. The modified C-18 column was employed to separate amino acids, alkylbenzenes and polycyclic aromatic hydrocarbons under RPLC mode and inorganic anion under AEC mode. The results confirm that this new stationary phase of RPLC/HILIC/AEC has multiple interactions with different analytes. Effective retention of biological samples was found on the Silpr-2MI-C18 column by comparing the results obtained from the commercial C-18 column.

Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Hosseini, ES; Heydar, KT or concate me.

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An article Synthesis of Dendritic Ligand Assisted Zn/Cu Bimetallic Nanoparticles as a Highly Active Green Catalyst for Chemoselective Oxidation and Reduction Reaction WOS:000564504600011 published article about AEROBIC OXIDATION; SELECTIVE OXIDATION; ALCOHOL OXIDATION; HYDROGENATION; EFFICIENT; NITROARENES; WATER; NANOCLUSTERS; GENERATION; SUZUKI in [Islam, Sayedul; Khan, Wahab] Bangladesh Univ Engn & Technol BUET, Fac Engn, Dept Chem, Dhaka 1000, Bangladesh in 2021, Cited 46. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

The dendritic ligand 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:1) 4a, 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (1:2) 4b, and 2, 4, 6-tris (di-4-chlorobenzamido)-1, 3, 5-triazine3supported Zn/Cu (2:1) 4cbimetallic nanoparticles (NPs) were synthesized successfully by following the co-complexation route in which the desired molar ratio of Zn and Cu was confirmed by the obtained results of electron diffraction X-ray and X-ray fluorescence spectroscopy analysis. The average particle size of these NPs was detected as 15-20 nm from transmission electron microscopy investigations and agglomerate spherical surface morphology was found by scanning electron microscopy, whereas the face-centered cubic structure of these bimetallic NPs was observed by X-ray diffraction assessment. Also, the formation of the ligand was proven by IR,(HNMR)-H-1,(CNMR)-C-13, and elemental analysis. Remarkably, the chemoselective oxidation of aromatic alcohols to the corresponding aldehydes or ketones at 25 min and reduction of aromatic nitro substituents to the corresponding aniline at 20 min in aqueous medium at room temperature have been studied by the most effective catalyst Zn/Cu (2:1) 4cNPs among other molar ratios of Zn/Cu (1:1)4aand Zn/Cu (1:2) 4bNPs under atmospheric air (O-2) conditions with good to excellent yields. This green catalytic approach of Zn/Cu (2:1) 4cNPs catalytic was easily recovered by simple filtration and recycled at least five consecutive runs without a noticeable loss of its catalytic effectiveness.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Islam, S; Khan, W or concate me.. Computed Properties of C8H10O2

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Name: (4-Methoxyphenyl)methanol. In 2021 POLYHEDRON published article about ONE-POT SYNTHESIS; SELECTIVE ALKYLATION; EFFICIENT; COMPLEX; ANILINES; SUBSTITUTION; OXIDATION; AMIDES in [Feng, Xinshu; Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Guangzhou 510006, Peoples R China in 2021, Cited 40. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A series of air-stable N-heterocyclic carbene (NHC) Ir(III) complexes (Ir1-6), bearing various combinations of chlorine, pyridine and NHC ligands, were assayed for the N-alkylation of amines with alcohols. It was found that Ir3, with two monodentate 1,3-bis-methyl-imidazolylidene (IMe) ligands, emerged as the most active complex. A large variety of amines and primary alcohols were efficiently converted into mono-N-alkylated amines in 53-96% yields. As a special highlight, for the challenging MeOH, selective N-monomethylation could be achieved using KOH as a base under an air atmosphere. Moreover, this catalytic system was successfully applied to the gram-scale synthesis of some valuable compounds. (C) 2021 Elsevier Ltd. All rights reserved.

Name: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Feng, XS; Huang, M or concate me.

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Authors Coufourier, S; Ndiaye, D; Gaillard, QG; Bettoni, L; Joly, N; Mbaye, MD; Poater, A; Gaillard, S; Renaud, JL in PERGAMON-ELSEVIER SCIENCE LTD published article about ASYMMETRIC TRANSFER HYDROGENATION; ENANTIOSELECTIVE TRANSFER HYDROGENATION; MEDIATED 2+2+1 CYCLOADDITIONS; TRIMETHYLAMINE N-OXIDE; METAL-DIENE COMPLEXES; REDUCTIVE AMINATION; SELECTIVE HYDROGENATION; HIGHLY EFFICIENT; ORGANIC-SYNTHESIS; CARBON-MONOXIDE in [Coufourier, Sebastien; Ndiaye, Daouda; Gaillard, Quentin Gaignard; Bettoni, Leo; Joly, Nicolas; Mbaye, Mbaye Diagne; Gaillard, Sylvain; Renaud, Jean-Luc] Normandie Univ, CNRS, UNICAEN, LCMT,ENSICAEN, 6 Blvd Marechal Juin, F-14050 Caen, France; [Ndiaye, Daouda; Mbaye, Mbaye Diagne] Univ Assane Seck Ziguinchor, BP 523, Ziguinchor, Senegal; [Joly, Nicolas; Poater, Albert] Univ Girona, Inst Quim Computac & Catalisi IQCC, Dept Quim, C M Aurelia Capmany 69, Girona 17003, Catalonia, Spain in 2021, Cited 109. Quality Control of (4-Methoxyphenyl)methanol. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A Diaminocyclopentadienone iron tricarbonyl complex has been applied in chemoselective hydrogen transfer reductions. This bifunctional iron complex demonstrated a broad applicability in mild conditions in various reactions, such as reduction of aldehydes over ketones, reductive alkylation of various functionalized amines with functionalized aldehydes and reduction of alpha,beta-unsaturated ketones into the corresponding saturated ketones. A broad range of functionalized substrates has been isolated in excellent yields with this practical procedure. (C) 2021 Elsevier Ltd. All rights reserved.

Quality Control of (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Coufourier, S; Ndiaye, D; Gaillard, QG; Bettoni, L; Joly, N; Mbaye, MD; Poater, A; Gaillard, S; Renaud, JL or concate me.

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An article Stereoselective 1,4-Addition of Primary Alcohols to gamma-Alkoxy-alpha,beta-unsaturated Esters WOS:000572131900002 published article about ASYMMETRIC CONJUGATE ADDITION; ENANTIOSELECTIVE SYNTHESIS; TETRAHYDROPYRAN; HYDRATION; ACIDS in [Inatomi, Saki; Takayanagi, Yuta; Watanabe, Kento; Toita, Akinori; Yamakoshi, Hiroyuki; Nakamura, Seiichi] Nagoya City Univ, Grad Sch Pharmaceut Sci, Mizuho Ku, 3-1 Tanabe Dori, Nagoya, Aichi 4678603, Japan in 2021, Cited 26. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Recommanded Product: 105-13-5

The scope and limitations of the diastereoselective 1,4-addition reaction of primary alcohols to gamma-alkoxy-alpha,beta-unsaturated esters were investigated. We found that a variety of sodium alkoxides, generated from the corresponding primary alcohols with NaH, underwent 1,4-addition reactions with (E)-enoates in CH(2)Cl(2)at -23 degrees C to give beta-alkoxy esters in modest yields with good to excellentsyn-selectivity, whereas stereoselectivity was not observed with the use of glycerol derivatives as nucleophiles. Cyclic acetal protection was found to play a pivotal role for the reaction to proceed.

Recommanded Product: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Inatomi, S; Takayanagi, Y; Watanabe, K; Toita, A; Yamakoshi, H; Nakamura, S or concate me.

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Safety of (4-Methoxyphenyl)methanol. In 2021 WASTE BIOMASS VALORI published article about PARTICLE-SHAPE; BAYER-PROCESS; PHYSICAL-PROPERTIES; CARBON-DIOXIDE; WASTE; NEUTRALIZATION; ADSORBENT; LIME; STABILIZATION; STRENGTH in [Reddy, Peddireddy Sreekanth; Mohanty, Bijayananda] NIT Mizoram, Dept Civil Engn, Aizawl 796012, Mizoram, India; [Reddy, Narala Gangadhara; Rao, Bendadi Hanumantha] ITT Bhubaneswar, Sch Infrastruct, Khorda 752050, Odisha, India; [Reddy, Narala Gangadhara] Shantou Univ, Dept Civil & Environm Engn, Shantou 515063, Guangdong, Peoples R China; [Serjun, Vesna Zalar] Slovenian Natl Bldg & Civil Engn Inst Slovenia, Dept Mat, Ljubljana 1000, Slovenia; [Das, Sarat Kumar] IIT ISM Dhanbad, Dept Civil Engn, Dhanbad 826004, Jharkhand, India; [Reddy, Krishna R.] Univ Illinois, Dept Civil & Mat Engn, Chicago, IL USA in 2021, Cited 205. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

In order to conserve natural resources and prevent waste generation, effective utilization of industrial wastes and/or by-products for beneficial engineering applications becomes inevitable. In order to accomplish this, extensive research studies, exploring properties and new applications of waste materials in a sustainable and environmentally friendly manner, have been initiated worldwide. Red mud (RM, also known as bauxite residue) is one of the wastes generated by the aluminium industry and its disposal and utilization have been traditionally hindered due to the extreme alkalinity (pH about 10.5-13.5). To date, no comprehensive review on various properties of RM of different origin and associated challenges in using it as a beneficial engineering material has been performed. The objective of this study is first to critically appraise the current understanding of properties of RM through a comprehensive literature review and detailed laboratory investigations conducted on Indian RM by the authors, to assess and identify the potential engineering applications, and to finally discuss associated challenges in using it in practical applications. Physical, chemical, mineralogical and geotechnical properties of RMs of different origin and production processes are reviewed. Mechanisms behind the pozzolanic reaction of RM under different chemical and mineralogical compositional conditions are discussed. Environmental concerns associated with the use of RM are also raised. Studies relevant to leachability characteristics reveal that most of the measured chemical concentrations are within the permissible regulatory limits. Overall, the review shows that RM disposal and reuse is complicated by its extreme alkalinity, which is also noticed to be influencing multiple engineering properties. But with selected pH amendments, the treated RM is found to have significant potential to be used as an effective and sustainable geomaterial. The assessment is majorly based on the characteristics of Indian RMs; hence the adaptation of the findings to other RMs should be assessed on a case-by-case basis. Moreover, field studies demonstrating the performance of RM in various engineering applications are warranted. [GRAPHICS] .

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Reddy, PS; Reddy, NG; Serjun, VZ; Mohanty, B; Das, SK; Reddy, KR; Rao, BH or concate me.. Safety of (4-Methoxyphenyl)methanol

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Formula: C8H10O2. Authors Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M in ROYAL SOC CHEMISTRY published article about in [Yoshida, Yasushi; Kukita, Mayu; Omori, Kazuki; Mino, Takashi; Sakamoto, Masami] Chiha Univ, Grad Sch Engn, Mol Chiral Res Ctr, Inage Ku, 1-33 Yayoi Cho, Chiba, Chiba 2638522, Japan in 2021, Cited 96. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Umpolung reactions of imines, especially the asymmetric reactions, have been extensively studied as they provide access to important chiral amines in an efficient manner. The reactions studied range from simple Michael reactions to several kinds of other reactions such as the aza-benzoin reaction, aza-Stetter reaction, addition with MBH carbonate, and Ir-catalysed allylation. Herein, we report the first umpolung alkylation reaction of alpha-iminoesters with alkyl halides mediated by iminophosphorane as an organic superbase. The desired products were obtained in up to 82% yield with almost perfect regioselectivities. The key to the regioselectivity of this reaction was the use of 4-trifluoromethyl benzyl imines as a substrate. The products were successfully derivatised into the more functionalised molecules in good yields.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Yoshida, Y; Kukita, M; Omori, K; Mino, T; Sakamoto, M or concate me.. Formula: C8H10O2

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