Tag: M.W=100-150

Product Details of 105-13-5. Authors Nkamba, DM; Wembodinga, G; Bernard, P; Ditekemena, J; Robert, A in BMC published article about in [Nkamba, Dalau Mukadi; Wembodinga, Gilbert; Ditekemena, John] Univ Kinshasa, Fac Med, Kinshasa Sch Publ Hlth, Kinshasa, DEM REP CONGO; [Nkamba, Dalau Mukadi; Robert, Annie] Univ Catholique Louvain UCLouvain, Inst Rech Expt & Clin IREC, Pole Epidemiol & Biostat, Clos Chapelle Aux Champs 30,Bte B1-30-13, B-1200 Brussels, Belgium; [Bernard, Pierre] Univ Catholique Louvain UCLouvain, Inst Rech Expt & Clin IREC, Pole Gynecol & Obstet, Brussels, Belgium in 2021, Cited 23. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

BackgroundPoor awareness of obstetric danger signs is a major contributing factor to delays in seeking obstetric care and hence to high maternal mortality and morbidity worldwide. We conducted the current study to assess the level of agreement on receipt of counseling on obstetric danger signs between direct observations of antenatal care (ANC) consultation and women’s recall in the exit interview. We also identified factors associated with pregnant women’s awareness of obstetric danger signs during pregnancy in the Democratic Republic of Congo (DRC)MethodsWe used data from the 2017-2018 DRC Service Provision Assessment survey. Agreement between the observation and woman’s recall was measured using Cohen’s kappa statistic and percent agreement. Multivariable Zero-Inflated Poisson (ZIP) regression was used to identify factors associated with the number of danger signs during pregnancy the woman knew.ResultsOn average, women were aware of 1.51.34 danger signs in pregnancy (range: 0 to 8). Agreement between observation and woman’s recall was 70.7%, with a positive agreement of 16.9% at the country level but ranging from 2.1% in Bandundu to 39.7% in Sud Kivu. Using multivariable ZIP analysis, the number of obstetric danger signs the women mentioned was significantly higher in multigravida women (Adj.IRR=1.38; 95% CI: 1.23-1.55), in women attending a private facility (Adj.IRR=1.15; 95% CI: 1.01-1.31), in women attending a subsequent ANC visit (Adj.IRR=1.11; 95% CI: 1.01-1.21), and in women counseled on danger signs during the ANC visit (Adj.IRR=1.19; 95% CI: 1.05-1.35). There was a regional variation in the awareness of danger signs, with the least mentioned signs in the middle and the most in the eastern provinces.ConclusionsOur findings indicated poor agreement between directly observed counseling and women’s reports that counseling on obstetric danger signs occurred during the current ANC visit. We found that province of residence, provision of counseling on obstetric danger signs, facility ownership, gravidity and the number of ANC visits were predictors of the awareness of obstetric danger signs among pregnant women. These factors should be considered when developing strategies aim at improving women’s awareness about obstetric danger signs in the DRC

Product Details of 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Nkamba, DM; Wembodinga, G; Bernard, P; Ditekemena, J; Robert, A or concate me.

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Category: alcohols-buliding-blocks. Authors Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY in WILEY-V C H VERLAG GMBH published article about in [Yang, Shouning; Yu, Shaoning; Yang, Huayan] Ningbo Univ, Sch Mat Sci & Chem Engn, Inst Mass Spectrometry, Zhejiang Prov Key Lab Adv Mass Spectrometry & Mol, Ningbo 315211, Zhejiang, Peoples R China; [Zhang, Yanmin; Song, Jian] Henan Normal Univ, Sch Phys, Xinxiang 453007, Henan, Peoples R China; [Yang, Shouning; Liu, Xiaoyang; Lu, Sijia; Li, Zhuo; Yang, Huayan] Henan Normal Univ, Collaborat Innovat Ctr Henan Prov Green Mfg Fine, Key Lab Green Chem Media & React, Minist Educ,Sch Chem & Chem Engn, Xinxiang 453007, Henan, Peoples R China in 2021, Cited 65. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The development of eco-friendly and low cost catalysts is challenging. Here, heterostructures of Bi2S3 quantum dots (QDs) doped onto ultrathin BiOCl nanosheets were synthesized by a facile hydrothermal method to exploit efficient photosensitizers with appropriate electronic states to enhance the transfer of electrons. The obtained Bi2S3-BiOCl showed highly efficient photocatalytic ability for selective oxidation of aromatic alcohols to aldehydes. More oxygen vacancies are formed on the exposed 001 facet of the ultrathin BiOCl, which can effectively trap electrons and form O-.(2)- radicals. The cooperation between the BiOCl and the Bi2S3 QDs effectively separates photogenerated electron-hole pairs at the heterointerface and facilitates the cooperative actions of O-.(2)- radicals and holes, which brings about a desirable photocatalytic eciency for the selective oxidation of aromatic alcohols. This work highlights the synergistic effect of semiconductor QDs and two-dimensional materials on selective conversion processes and provides a new design paradigm using noble metal-free heteromaterials with high photocatalytic activity. This opens new possibilities for photocatalyst design using heteromaterials with high photocatalytic activity.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Yang, SN; Liu, XY; Lu, SJ; Li, Z; Zhang, YM; Yu, SN; Song, J; Ding, CF; Yang, HY or concate me.. HPLC of Formula: C8H10O2

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Kim, SJ; Khomutnyk, Y; Bannykh, A; Nagorny, P in [Kim, Sungjin; Khomutnyk, Yaroslav; Bannykh, Anton; Nagorny, Pavel] Univ Michigan, Dept Chem, Ann Arbor, MI 48109 USA published Synthesis of Glycosyl Fluorides by Photochemical Fluorination with Sulfur(VI) Hexafluoride in 2021, Cited 42. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

This study describes a new convenient method for the photocatalytic generation of glycosyl fluorides using sulfur(VI) hexafluoride as an inexpensive and safe fluorinating agent and 4,4′-dimethoxybenzophenone as a readily available organic photocatalyst. This mild method was employed to generate 16 different glycosyl fluorides, including the substrates with acid and base labile functionalities, in yields of 43%-97%, and it was applied in continuous flow to accomplish fluorination on an 7.7 g scale and 93% yield.

SDS of cas: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Kim, SJ; Khomutnyk, Y; Bannykh, A; Nagorny, P or concate me.

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Nguyen, NK; Ha, MT; Bui, HY; Trinh, QT; Tran, BN; Nguyen, VT; Hung, TQ; Dang, TT; Vu, XH in [Ngoc-Khanh Nguyen; Van Tuyen Nguyen; Tran Quang Hung; Xuan Hoan Vu] Vietnam Acad Sci & Technol, Inst Chem, 18 Hoang Quoc Viet, Hanoi, Vietnam; [Ngoc-Khanh Nguyen; Minh-Tuan Ha; Hoang Yen Bui; Tuan Thanh Dang] VNU Hanoi Univ Sci, Dept Chem, 19 Le Thanh Tong, Hanoi, Vietnam; [Quang Thang Trinh] Duy Tan Univ, Inst Res & Dev, 03 Quang Trung, Danang 550000, Vietnam; [Bich Ngoc Tran] Natl Univ Singapore, Ctr Bioimaging Sci CBIS, Dept Biol Sci, 14 Sci Dr 4, Singapore 117557, Singapore; [Xuan Hoan Vu] Vietnam Petr Inst, 167 Trung Kinh Str, Hanoi, Vietnam published Magnetically recyclable CuFe2O4 catalyst for efficient synthesis of bis (indolyl)methanes using indoles and alcohols under mild condition in 2021, Cited 35. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Bis(3-indolyl)methanes (BIM) are highly valuable and appear in the core structure of many natural products and pharmacologically active compounds (anticancer, anti-inflammatory, antiobesity, antimetastatic, antimicrobial, etc.). Herein, we have disclosed an air stable and highly efficient CuFe2O4 heterogeneous catalyst for alkylation of indoles with alcohols to give bis(3-indolyl)methanes in very good yields. The CuFe2O4 catalyst has been found to be magnetically recycled at least five times without losing significant catalytic activity.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Nguyen, NK; Ha, MT; Bui, HY; Trinh, QT; Tran, BN; Nguyen, VT; Hung, TQ; Dang, TT; Vu, XH or concate me.. HPLC of Formula: C8H10O2

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Name: (4-Methoxyphenyl)methanol. Arslan, B; Gulcemal, S in [Arslan, Burcu; Gulcemal, Suleyman] Ege Univ, Dept Chem, TR-35100 Izmir, Turkey published alpha-Alkylation of arylacetonitriles with primary alcohols catalyzed by backbone modified N-heterocyclic carbene iridium(I) complexes in 2021, Cited 65. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A series of backbone-modified N-heterocyclic carbene (NHC) complexes of iridium(I) (1d-f) have been synthesized and characterized. The electronic properties of the NHC ligands have been assessed by comparison of the IR carbonyl stretching frequencies of the in situ prepared [IrCl(CO)(2)(NHC)] complexes in CH2Cl2. These new complexes (1d-f), together with previously prepared 1a-c, were applied as catalysts for the alpha-alkylation of arylacetonitriles with an equimolar amount of primary alcohols or 2-aminobenzyl alcohol. The catalytic activities of these complexes could be controlled by modifying the N-substituents and backbone of the NHC ligands. The NHC-Ir-I complex 1f bearing 4-methoxybenzyl substituents on the N-atoms and 4-methoxyphenyl groups at the 4,5-positions of imidazole exhibited the highest catalytic activity in the alpha-alkylation of arylacetonitriles with primary alcohols. Various alpha-alkylated nitriles and aminoquinolines were obtained in high yields through a borrowing hydrogen pathway by using 0.1 mol% 1f and a catalytic amount of KOH (5 mol%) under an air atmosphere within significantly short reaction times.

Name: (4-Methoxyphenyl)methanol. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Arslan, B; Gulcemal, S or concate me.

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Computed Properties of C8H10O2. Malatinec, S; Bednarova, E; Tanaka, H; Kotora, M in [Malatinec, Stefan; Bednarova, Eva; Tanaka, Hiroki; Kotora, Martin] Charles Univ Prague, Fac Sci, Dept Organ Chem, Chem, Albertov 6, Prague 12843 2, Czech Republic; [Tanaka, Hiroki] Okayama Univ, Res Inst Interdisciplinary Sci, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan published Highly Enantioselective Ring-Opening of meso-Epoxides with O- and N-Nucleophiles Catalyzed by a Chiral Sc(III)/bipyridine Complex in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

The ring-opening of epoxides is a synthetically significant process widely applied in all kinds of chemistry. Herein, we report the catalytic and highly enantioselective variant of this reaction exploiting our recent endeavors to design and synthesize chiral bipyridine type ligands. A Sc-complex with a newly developed bipyridine ligand exhibited high reactivity and stereocontrol in the desymmetrization of meso-epoxides with various alcohols. The respective enantiomerically enriched 1,2-alkoxyalcohols were obtained with e.r. values of up to 99.5:0.5 for various alcohols regardless of their nature (benzyl, alkyl, cycloalkyl, allyl, propargyl, etc.). We attempted ring-opening of meso-epoxides with anilines as well; however, it proceeded with lower enantioselectivity and was strongly depended on the electronic effect of substituents attached to the aromatic ring.

Computed Properties of C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Malatinec, S; Bednarova, E; Tanaka, H; Kotora, M or concate me.

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Authors Amberchan, G; Snelling, RA; Moya, E; Landi, M; Lutz, K; Gatihi, R; Singaram, B in AMER CHEMICAL SOC published article about AROMATIC CARBOXYLIC-ACIDS; CATALYZED N-ALKYLATION; LITHIUM TRIETHYLBOROHYDRIDE; CORRESPONDING AMINES; REDUCING AGENTS; TERTIARY AMIDES; REDUCTION; NITRILES; ALCOHOLS; SECONDARY in [Amberchan, Gabriella; Snelling, Rachel A.; Moya, Enrique; Landi, Madison; Lutz, Kyle; Gatihi, Roxanne; Singaram, Bakthan] Univ Calif Santa Cruz, Dept Chem & Biochem, Santa Cruz, CA 95064 USA in 2021, Cited 84. SDS of cas: 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The binary hydride, diisobutylaluminum borohydride [(iBu)(2)AlBH4], synthesized from diisobutylaluminum hydride (DIBAL) and borane dimethyl sulfide (BMS) has shown great potential in reducing a variety of organic functional groups. This unique binary hydride, (iBu)(2)AlBH4, is readily synthesized, versatile, and simple to use. Aldehydes, ketones, esters, and epoxides are reduced very fast to the corresponding alcohols in essentially quantitative yields. This binary hydride can reduce tertiary amides rapidly to the corresponding amines at 25 degrees C in an efficient manner. Furthermore, nitriles are converted into the corresponding amines in essentially quantitative yields. These reactions occur under ambient conditions and are completed in an hour or less. The reduction products are isolated through a simple acid-base extraction and without the use of column chromatography. Further investigation showed that (iBu)(2)AlBH4 has potential to be a selective hydride donor as shown through a series of competitive reactions. Similarities and differences between (iBu)(2)AlBH4, DIBAL, and BMS are discussed.

SDS of cas: 105-13-5. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Amberchan, G; Snelling, RA; Moya, E; Landi, M; Lutz, K; Gatihi, R; Singaram, B or concate me.

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Recommanded Product: (4-Methoxyphenyl)methanol. Authors Tabaru, K; Nakatsuji, M; Itoh, S; Suzuki, T; Obora, Y in ROYAL SOC CHEMISTRY published article about in [Tabaru, Kazuki; Nakatsuji, Masato; Itoh, Satoshi; Obora, Yasushi] Kansai Univ, Fac Chem Mat & Bioengn, Dept Chem & Mat Engn, Suita, Osaka 5648680, Japan; [Suzuki, Takeyuki] Osaka Univ, Inst Sci & Ind Res ISIR, Comprehens Anal Ctr, 8-1 Mihogaoka, Osaka 5670057, Japan in 2021, Cited 16. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

We report N,N-dimethylformamide-stabilised Pd nanoparticle (Pd NP)-catalysed transfer vinylation of alcohols from vinyl ether. Pd NPs combined with bathophenanthroline exhibited high catalytic activity. This reaction proceeded with low catalyst loading and the catalyst remained effective even after many rounds of recycling. The observation of the catalyst using transmission electron microscopy and dynamic light scattering implied no deleterious aggregation of Pd NPs.

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Safety of (4-Methoxyphenyl)methanol. Authors Ghosh, R; Jana, NC; Panda, S; Bagh, B in AMER CHEMICAL SOC published article about in [Ghosh, Rahul; Jana, Narayan Ch; Panda, Surajit; Bagh, Bidraha] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India in 2021, Cited 111. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Coordination of 1,4-disubstituted 1,2,3-triazoles L-1 and L-2 with [(p-cymene)RuCl2](2) followed by dehydrochlorination in the presence of a base resulted in the formation of complexes 1 and 2, respectively. Both were tested for the transfer hydrogenation of aldehydes and ketones in air using ecologically benign and cheap ethanol as the hydrogen source in the presence of a catalytic amount of a base. Air-stable complex 1 was proved to be an active catalyst for the transfer hydrogenation of a wide variety of aromatic and aliphatic aldehydes and ketones bearing various functionalities. Catalyst 1 was also effective for the transfer hydrogenation of carbonyls using the simplest primary alcohol, methanol, under aerobic conditions. Under the present catalytic protocol, labile or reducible functionalities such as nitro, cyano, and ester groups were tolerated. Good selectivity was also observed for acyclic alpha,beta-unsaturated carbonyls. However, this catalytic protocol was not selective for 2-cyclohexen-1-one as both alkene and keto moieties were reduced. The transfer hydrogenations are believed to proceed via a ruthenium-hydride intermediate. Finally, transfer hydrogenation of acetophenone using isopropanol as a commonly used hydrogen source was also performed and the sustainable and green credentials of these catalytic protocols utilizing methanol, ethanol, and isopropanol were compared with the help of the CHEM21 green metrics toolkit.

About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Ghosh, R; Jana, NC; Panda, S; Bagh, B or concate me.. Computed Properties of C8H10O2

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Das, S; Mondal, R; Chakraborty, G; Guin, AK; Das, A; Paul, ND in [Das, Siuli; Mondal, Rakesh; Chakraborty, Gargi; Guin, Amit Kumar; Paul, Nanda D.] Indian Inst Engn Sci & Technol, Dept Chem, Howrah 711103, India; [Das, Abhishek] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India published Zinc Stabilized Azo-anion Radical in Dehydrogenative Synthesis of N-Heterocycles. An Exclusively Ligand Centered Redox Controlled Approach in 2021, Cited 79. HPLC of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Herein we report an exclusively ligand-centered redox controlled approach for the dehydrogenation of a variety of N-heterocycles using a Zn(II)-stabilized azo-anion radical complex as the catalyst. A simple, easy-to-prepare, and bench-stable Zn(II)-complex (1b) featuring the tridentate arylazo pincer, 2-((4-chlorophenyl)diazenyl)-1,10-phenanthroline, in the presence of zinc-dust, undergoes reduction to form the azo-anion radical species [1b]which efficiently dehydrogenates various saturated N-heterocycles such as 1,2,3,4-tetrahydro-2-methylquinoline, 1,2,3,4-tetrahydro-isoquinoline, indoline, 2-phenyl-2,3-dihydro-1H-benzoimidazole, 2,3-dihydro-2-phenylquinazolin-4(1H)-one, and 1,2,3,4-tetrahydro-2-phenylquinazolines, among others, under air. The catalyst has further been found to be compatible with the cascade synthesis of these N-heterocycles via dehydrogenative coupling of alcohols with other suitable coupling partners under air. Mechanistic investigation reveals that the dehydrogenation reactions proceed via a one-electron hydrogen atom transfer (HAT) pathway where the zinc-stabilized azo-anion radical ligand abstracts the hydrogen atom from the organic substrate(s), and the whole catalytic cycle proceeds via the exclusive involvement of the ligand-centered redox events where the zinc acts only as the template.

HPLC of Formula: C8H10O2. About (4-Methoxyphenyl)methanol, If you have any questions, you can contact Das, S; Mondal, R; Chakraborty, G; Guin, AK; Das, A; Paul, ND or concate me.

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