Category: 96-76-4

On May 7, 2021, Maurya, Mannar R.; Prakash, Ved; Avecilla, Fernando; Sankar, Muniappan published an article.Reference of 2,4-Di-tert-butylphenol The title of the article was Selective Bromination of β-Positions of Porphyrin by Self-Catalytic Behaviour of VOTPP: Facile Synthesis, Electrochemical Redox Properties and Catalytic Application. And the article contained the following:

Oxidovanadium(IV) complex of β-octabromo-meso-tetraphenylporphyrin, {[VIVO(TPPBr8)], 2} was synthesized by self-catalytic oxidative bromination of meso-tetraphenylporphyrinatooxidovanadium(IV) {[VIVO(TPP)], 1} in excellent yield under mild conditions at 25° and its structure was confirmed by single crystal x-ray study. UV-visible and 1H NMR spectra further confirmed that the meso-Ph rings are not brominated and thus emphasizes on the selectivity as well as synthetic importance of this catalytic method. In the presence of substrates e. g. phenol derivatives, 1 biomimics the vanadium bromoperoxidase (VBPO) enzyme and catalyzes the oxidative bromination of substrates in water at 25°. Remarkably, 2 also catalyzes the oxidative bromination of phenol derivatives under similar reaction conditions with very high turnover frequency (TOF) values (∼29 s-1) along with its recyclability. 2 Showed superior catalytic performance as compared to 1 because of its electron deficient nature due to electron withdrawing bromo substituents and robust saddle shaped nonplanar structure (further supported by DFT studies). The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Reference of 2,4-Di-tert-butylphenol

The Article related to vanadium phenylporphyrin bromination preparation crystal structure epr spectra electrochem, bromination phenol vanadium bromo phenylporphyrin catalyst, Inorganic Chemicals and Reactions: Coordination Compounds and other aspects.Reference of 2,4-Di-tert-butylphenol

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On October 31, 2022, Zhang, Sitong; Dong, Zijian; Shi, Jia; Yang, Chengrui; Fang, Yi; Chen, Guang; Chen, Huan; Tian, Chunjie published an article.Reference of 2,4-Di-tert-butylphenol The title of the article was Enzymatic hydrolysis of corn stover lignin by laccase, lignin peroxidase, and manganese peroxidase. And the article contained the following:

Lignin of high purity and structural integrity was isolated from the enzymic residue of corn stover. Degradation of the lignin by laccase, lignin peroxidase, and manganese peroxidase was investigated. Structural changes in the lignin after degradation were characterized by SEM, nitrogen adsorption and Fourier transform IR spectroscopy, and the enzymic products were systematically analyzed by gas chromatog. mass spectrometry. The highest percentage of lignin degradation was obtained with a mixture of three enzymes (25.79%): laccase (Lac), the starting enzyme of the mixed enzyme reaction, worked with lignin peroxidase (LiP), and manganese peroxidase (MnP) to further degrade lignin. This degradation destroyed the macromol. structure of lignin, broke its key chem. bonds, and opened benzene rings, thus producing more acidic compounds This study elucidated the concept of degrading lignin from corn stover using the Lac, LiP and MnP enzymes synergistically, thus providing a theor. basis for the biodegradation of lignin. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Reference of 2,4-Di-tert-butylphenol

The Article related to lignin isolation enzymic peroxidase catalyst degradation aromatic compound, corn stover, degradation mechanism, degradation products, lignin-degrading enzyme, Cellulose, Lignin, Paper, and Other Wood Products: Lignin and other aspects.Reference of 2,4-Di-tert-butylphenol

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On September 1, 2020, Shi, Jingchun; Xu, Caihong; Xiang, Li; Chen, Jianmin; Cai, Zongwei published an article.Computed Properties of 96-76-4 The title of the article was Tris(2,4-di-tert-butylphenyl)phosphate: an unexpected abundant toxic pollutant found in PM2.5. And the article contained the following:

A novel pollutant, tris(2,4-di-tert-butylphenyl)phosphate (I168O), was identified in urban fine particulate matter (PM2.5) samples in a nontargeted screening based on mass spectrometry for the first time. I168O was detected in all samples collected from two typical cities far away from each other in China. The concentrations of I168O reached up to 851 (median: 153) ng/m3, indicating that it was a widespread and abundant pollutant in the air. The antioxidant Irgafos 168 [I168, tris(2,4-di-tert-butylphenyl)phosphite] popularly added in plastics was the most suspected source for the detected I168O. Simulation studies indicated that heating, UV radiation, and water contact might significantly (p < 0.05) transform I168 to I168O. In particular, I168O might be magnificently evaporated into the air at high temperatures The outdoor inhalation exposure of I168O may exert substantial health risks. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Computed Properties of 96-76-4

The Article related to i168o unexpected abundant toxic pollutant pm, Air Pollution and Industrial Hygiene: Industrial Waste Gases and other aspects.Computed Properties of 96-76-4

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On August 1, 2021, Hauk, Armin; Pahl, Ina; Dorey, Samuel; Menzel, Roberto published an article.Computed Properties of 96-76-4 The title of the article was Using extractables data from single-use components for extrapolation to process equipment-related leachables: The toolbox and justifications. And the article contained the following:

Quant. information on process equipment-related leachables (PERLs) is required for process qualification and within a safety assessment. Extractables data for single-use equipment are suitable and applicable if the extractables study conditions fit or are bracketing the expected conditions of use. It is necessary to extrapolate extractables data when the expected in-use conditions are not covered by the test conditions. Methods for such quant. extrapolation of extractables data toward potential PERLs are therefore needed. They are comprehensively described in this publication and include: scaling of extractables data for devices of different sizes adjusted to process-volumes, extrapolation to temperatures different from the extraction temperature, extrapolations to different solvent compositions, extrapolation to various contact times, and the combination of extractables data from individual components to assess assemblies. These extrapolation methods yield extractables data as if an extractables study had been performed. The methods presented are consistently derived from basic physicochem. principles. The relevant, underlying phys. parameters are obtained from extractables experiments and are compared with published data. The applicability and justification of the proposed calculation methods are discussed and benchmarked against exptl. findings. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Computed Properties of 96-76-4

The Article related to hexadecane dodecane film temperature phase equilibrium algorithm, Biochemical Methods: Other (Not Covered At Other Subsections) and other aspects.Computed Properties of 96-76-4

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Chen, Erbao; Song, Huanlu; Li, Yi; Chen, Haijun; Wang, Bao; Che, Xianing; Zhang, Yu; Zhao, Shuna published an article in 2020, the title of the article was Analysis of aroma components from sugarcane to non-centrifugal cane sugar using GC-O-MS.COA of Formula: C14H22O And the article contains the following content:

A total of 84 volatile aroma components were determined in the 9 samples of sugarcane to non-centrifugal sugar (NCS), including 15 alcs., 12 aldehydes, 10 ketones, 17 carboxylic acids, 11 pyrazines, 7 phenols, 3 esters, 3 hydrocarbons, and 2 sulfur compounds Of these compounds, 10 were with high flavor dilution (FD) factors based on the aroma extract dilution anal. (AEDA). 4-Hydroxy-2,5-dimethyl-3(2H)furanone exhibited the highest FD factor of 2187, followed by (E)-2-nonenal, 2-hydroxy-3-methyl-2-cyclopentene-1-one, and 4-allyl-2,6-dimethoxyphenol with a FD factor of 729. The odor compounds showed no significant change and were similar to that of sugarcane during the first four steps in the production of non-centrifugal cane sugar. In the middle three stages, the heating slightly affected the aroma composition Addnl., a prolonged period of high-temperature heating, lead to the production of the Maillard reaction products, such as pyrazines, pyrroles, and furans, differentiating the step to be unique from the previous seven stages. However, the content of the NCS odorants was significantly reduced due to the loss of odor compounds during the drying process. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).COA of Formula: C14H22O

The Article related to aroma component sugarcane non centrifugal cane sugar, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.COA of Formula: C14H22O

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On December 31, 2020, Fagbohun, Oladapo F.; Oriyomi, Olumayowa V.; Adekola, Mukaila B.; Msagati, Titus A. M. published an article.Computed Properties of 96-76-4 The title of the article was Biochemical applications of Kigelia africana (Lam.) Benth. fruit extracts in diabetes mellitus. And the article contained the following:

Abstract: The use of Kigelia africana plant is beneficial in many medicinal applications. This study investigated the chem. compounds as well as antioxidant and antidiabetic activities of KA fruits in vitro and in vivo. From the result of GC-qTOF-MS, phenol-2,4-bis(1,1-dimethylethyl)-, benzene propanoic acid-3,5-bis(1,1-dimethylethyl)-4-hydroxymethylester, naphthalene-2-methyl-, and oxalic acid-4-chlorophenyl nonyl-ester were newly identified and revealed a strong binding affinity of – 6.1, – 6.3, – 6.8, and – 6.2 kcal/mol resp. The hexane and Et acetate fractions had the highest antioxidant activities with 0.14 and 0.025 mg/mL for DPPH; 91.31 and 99.20 mg AAE/g for FRAP; and 80.61 and 98.88 mg AAE/g for TPC, resp. Hexane fraction (HF) had the lowest IC50 value (1.97 mg/mL) against α-amylase. At low and middle doses, HF showed significant ameliorative activities by restoring islet cells, increasing the number of β cells, and reducing fasting blood glucose levels. Significant differences were observed in the activities of GGT and G-6-PDH. KA fruit exhibited high antidiabetic and antihyperglycemic activities in STZ-induced diabetic rats. According to mol. docking study, the use of the base structure of 2,4-ditert-butylphenol identified from K. africana fruit may serve as the novel approach to the treatment of diabetes mellitus. Graphical abstract: [graphic not available: see fulltext]. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Computed Properties of 96-76-4

The Article related to kigelia fruit extract diabetes mellitus, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.Computed Properties of 96-76-4

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On February 28, 2021, Fan, Xiaojing; Jiao, Xin; Liu, Jinguang; Jia, Meng; Blanchard, Chris; Zhou, Zhongkai published an article.Category: alcohols-buliding-blocks The title of the article was Characterizing the volatile compounds of different sorghum cultivars by both GC-MS and HS-GC-IMS. And the article contained the following:

The current study applied both GC-MS and GC-IMS for characterizing volatile compounds of six Australian sorghum cultivars. For raw sorghum, the result of GC-MS showed that ester compounds were abundant in six raw samples. Among these esters, the content of hexadecanoic acid Et ester was highest in all of the raw samples. Compound 3-octanone only existed in Apollo, Bazley and Liberty, and 2-undecanone was found to be in MR43. Result of GC-IMS showed that signals of benzaldehyde, 2,3-butanedione were generally noted in six raw samples. In general, The Apollo and Buster had more volatile compounds, followed by Bazley and Liberty. In contrast, MR43 and G44 had least volatile compounds For cooked sorghums, more fatty aldehydes are formed compared to its corresponding raw sample, in which current data indicated that 40 volatile compounds were identified by GC-MS, and 11 of them were identified as the key aroma compounds More important, variation in the compounds of hexanal, heptanal, octanal, 2-heptenal, nonanal, trans- 2-octenal, benzeneaceldehyde, (E)-2-nonenal, 1-octen-3-ol, 1-pentanol, 2-methoxy-4-vinylphenol and 2-pentylfuran might be applied for explaining the aroma characteristics among six sorghum cultivars. Result of GC-IMS showed that 26 volatile compounds but not in results from GC-MS detection, indicating advantage of methodol. combination for a better understanding impact of cultivars and cooking on volatile characteristics of sorghums. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Category: alcohols-buliding-blocks

The Article related to sorghum volatile compound gc ms ims, gc-ims, gc-ms, odor-active value, sorghum, volatile compound, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.Category: alcohols-buliding-blocks

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On May 31, 2020, Sezgin, Sema; Dalar, Abdullah; Uzun, Yusuf published an article.Product Details of 96-76-4 The title of the article was Determination of antioxidant activities and chemical composition of sequential fractions of five edible mushrooms from Turkey. And the article contained the following:

Tricholoma scalpturatum, Tricholoma populinum, Neolentinus cyathiformis, Chlorophyllum agaricoides, and Lycoperdon utriforme have been traditionally utilized as food in Turkey for a long time. The present study focused on determining antioxidant activities, total phenolic groups contents (flavonols, hydroxycinnamic acids, proanthocyanidins, and anthocyanins), phenolic compounds and fatty acids of sequential extracts (n-hexane, Et acetate, chloroform, acetone, ethanol, and pure water) obtained from five wild edible macrofungi species. Ethanol and acetone (or Et acetate) were found as the most efficient solvents in terms of antioxidant activities and extraction efficiency. Antioxidant studies showed that L. utriforme, C. agaricoides, and T. populinum exhibited the highest radical scavenging and reducing activities and contained the highest phenolic contents. Chromatog. studies revealed that phenolic acids (protocatechuic, gallic, and chlorogenic acids) and fatty acids (oleic, linoleic, and palmitic acids) were the major contributors of the antioxidant activities of the extracts The results obtained suggest the utilization of these macrofungi species as significant sources of natural antioxidants. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Product Details of 96-76-4

The Article related to antioxidant activity chem composition sequential fraction edible mushroom, antioxidant, extraction, fatty acid, mushroom, phenolic compound, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.Product Details of 96-76-4

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Ni, Hui; Jiang, Qing-Xiang; Zhang, Ting; Huang, Gao-Ling; Li, Li-Jun; Chen, Feng published an article in 2020, the title of the article was Characterization of the aroma of an instant white tea dried by freeze drying.Recommanded Product: 96-76-4 And the article contains the following content:

The aroma of an instant white tea (IWT) was extracted through simultaneous distillation-extraction (SDE) and analyzed by sensory evaluation, gas chromatog.-mass spectrometry-olfactometry (GC-MS-O), aroma reconstruction, omission test and synergistic interaction anal. Sensory evaluation showed the IWT was dominated with floral and sweet notes. The SDE extract had the aroma similar to the IWT. The main volatile components in the SDE extract were benzyl alc., linalool, hotrienol, geraniol, α-terpineol, coumarin, camphene, benzeneacetaldehyde, 2-hexanone, cis-jasmin lactone and phenylethyl alc. GC-MS-O and aroma reconstruction experiments showed 16 aroma-active compounds Linalool, trans-β-damascenone and camphene were the major contributors to floral, sweet and green notes based on flavor dilution anal. and omission test. Linalool and trans-β-damascenone had synergistic effect to promote floral and sweet notes. Camphene and trans-β-damascenone had synergistic effect to reduce green and sweet notes. The study helps to understand the aroma of IWT and antagonism interactions among aroma-active volatiles. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Recommanded Product: 96-76-4

The Article related to aroma instant white tea dried freeze drying, gc-ms, gc-ms-o, aroma reconstruction and omission test, instant white tea, synergistic interactions, Food and Feed Chemistry: Fruits, Vegetables, Legumes, and Nuts and other aspects.Recommanded Product: 96-76-4

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On June 30, 2022, Naeem, Hamna; Ahmad, Khuram Shahzad published an article.Recommanded Product: 2,4-Di-tert-butylphenol The title of the article was Fungal and bacterial assisted bioremediation of environmental toxicant (N-[2-[3-chloro-5-(trifluoromethyl)-2-pyridinyl] ethyl]-2-(trifluoromethyl) benzamide) holding benzamidic genesis elucidating the eco-friendly strategy. And the article contained the following:

Fluopyram (FLP) containing benzamidic genesis utilized for seed detoxification and as a foliar application is associated with low profound toxicity in mammals but long-term toxicol. investigations have revealed that FLP can stimulate tumor growth. FLP attenuation has been the first time scrutinized employing microorganisms originally identified from soils. Biodegrative assays of four fungal strains; Aspergillus fumigatus (AFu), Aspergillus terreus (AT), Aspergillus flavus (AF), Aspergillus niger (AN), and three bacterial strains: Streptococcus pneumoniae (SP) Streptococcus pyogenes (SPy), and Escherichia coli (EC), were employed. Ten milligrams per L FLP concentration was made employing sep. microbe and analyzed for 35 days. The anal. technique was inclusive of UV-visible spectrophotometric and high-performance liquid chromatog. procedure endeavored to test FLP biodegradation SP and AT exhibited maximal potentiality to metabolize FLP. HPLC is indicative of several metabolites formations. FLP degradation by AFu, EC, SPy, AN, AF, AT, SP was observed to be 24.2%, 82.7%, 89.8%, 90.7%, 91.3%, 95.4%, and 99.3%, explicating the efficacy of all strains employed in FLP degradation Current investigations are indicative of significant bioremediation strategies for xenobiotic mitigation. Furthermore, the current examinations are inclusive of the augmentation of biodegradative assays to be utilized on a large scale for efficient environmental management cost-effectively and sustainably. The experimental process involved the reaction of 2,4-Di-tert-butylphenol(cas: 96-76-4).Recommanded Product: 2,4-Di-tert-butylphenol

The Article related to aspergillus streptococcus bioremediation fluopyram environmental toxicant benzamidic genesis, bacteria, benzamide, biodegradation, fungi, microbe, Fermentation and Bioindustrial Chemistry: Industrial Chemicals and other aspects.Recommanded Product: 2,4-Di-tert-butylphenol

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