Category: 821-41-0

Zhu, Kaili; Xu, Xudong; Xu, Mengqiu; Deng, Ping; Wu, Wenbo; Ye, Wei; Weng, Zihui; Su, Yue; Wang, Huijie; Xiao, Fei; Fang, Zeping; Gao, Peng published their research in ChemElectroChem in 2021. The article was titled 《One-Pot Synthesis of Tensile-Strained PdRuCu Icosahedra toward Electrochemical Hydrogenation of Alkene》.Related Products of 821-41-0 The article contains the following contents:

Electrochem. hydrogenation (ECH) uses electricity to drive proton (H+) reduction for hydrogenation, which can greatly reduce energy supply and environmental pollution, representing an ideal alternative to traditional thermal hydrogenation. In this work, we put forward tensile-strained PdRuCu alloy to promote ECH. Tensile strain promotes the adsorption of C=C by changing the d-band center. Meanwhile, alloying Ru and Cu into Pd lattice facilitates hydrogenation by weakening Pd-H bonding. Therefore, PdRuCu icosahedra display excellent ECH performance of 2-methyl-3-buten-2-ol (MBE) with specific activity of 227.4μmolMBE nm-2 min-1 at -0.3 V vs. reversible hydrogen electrode (RHE), about 16.1 and 10.5 times higher than that of com. Pd/C and Ru/C, resp. In addition, PdRuCu icosahedra was excellent in the scaling up of substrate concentration combined with anisyl alc. oxidation to produce high-value added anisaldehyde at anode. This work provides a guideline for the rational design of highly active and durable metallic catalyst in ECH. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Nanosized Organo-Silica Particles with “”Built-In”” Surface-Initiated Atom Transfer Radical Polymerization Capability as a Platform for Brush Particle Synthesis》 was written by Han, Jin; Zhai, Yue; Wang, Zongyu; Bleuel, Markus; Liu, Tong; Yin, Rongguan; Wu, Wenjie; Hakem, Ilhem F.; Karim, Alamgir; Matyjaszewski, Krzysztof; Bockstaller, Michael R.. SDS of cas: 821-41-0 And the article was included in ACS Macro Letters in 2020. The article conveys some information:

A facile synthetic method was developed to prepare sub-5 nm organo-silica (oSiO2) nanoparticles through the self-condensation of atom transfer radical polymerization (ATRP)-initiator-containing silica precursors. The obtained oSiO2 nanoparticles were characterized by a combination of NMR, thermogravimetric anal. (TGA), transmission electron microscopy (TEM), dynamic light scattering (DLS), and small-angle neutron scattering (SANS). The accessibility of the surface-Br initiating sites was evaluated by the polymerization of poly(Me methacrylate) (PMMA) ligands from the surface of the oSiO2 nanoparticles using surface-initiated atom transfer radical polymerization (SI-ATRP). The ultrasmall size, tunable composition, and ease of surface modification may render these organo-silica nanoparticle systems with built-in SI-ATRP capability an interesting alternative to conventional silica nanoparticles for functional material design. The experimental part of the paper was very detailed, including the reaction process of 5-Hexen-1-ol(cas: 821-41-0SDS of cas: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.SDS of cas: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Chromium-catalyzed linear-selective alkylation of aldehydes with alkenes》 was published in Organic Letters in 2020. These research results belong to Hirao, Yuki; Katayama, Yuri; Mitsunuma, Harunobu; Kanai, Motomu. Application In Synthesis of 5-Hexen-1-ol The article mentions the following:

We developed a chromium-catalyzed, photochem., and linear-selective alkylation of aldehydes with alkylzirconium species generated in situ from a wide range of alkenes and Schwartz’s reagent. Photochem. homolysis of the C-Zr bond afforded alkyl radicals, which were then trapped by a chromium complex catalyst to generate the alkylchromium(III) species for polar addition to aldehydes. The reaction proceeded with high functional group tolerance at ambient temperature under visible-light irradiation In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application In Synthesis of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Eco-friendly mechanochemical preparation of Ag2O-MnO2/graphene oxide nanocomposite: an efficient and reusable yst for the base-free, aerial oxidation of alcohols》 was published in Catalysts in 2020. These research results belong to Adil, Syed Farooq; Assal, Mohamed E.; Khan, Mujeeb; Shaik, Mohammed Rafi; Kuniyil, Mufsir; Sekou, Doumbia; Dewidar, Ahmed Z.; Al-Warthan, Abdulrahman; Siddiqui, Mohammed Rafiq H.. Related Products of 821-41-0 The article mentions the following:

Recently, the development of eco-friendly mechanochem. approaches for the preparation of novel ysts with enhanced activity and selectivity has gained considerable attention. Herein, we developed a rapid and solvent-less mechanochem. method for the preparation of mixed metal oxide (Ag2O-MnO2) decorated graphene oxide (GRO)-based nanocomposites (Ag2O-MnO2/(X weight%)GRO), as the Ag2O-MnO2/(X weight%)GRO nanocomposite was fabricated by the phys. grinding of freshly prepared GRO and pre-annealed (300°C) mixed metal oxide nanoparticles (NPs) (Ag2O-MnO2) using an eco-friendly milling procedure. The as-prepared nanoysts were characterized by using various techniques. Furthermore, the nanocomposites were applied as a heterogeneous yst for the oxidation of alc. by employing gaseous O2 as an eco-friendly oxidant under base-free conditions. The mechanochem. obtained GRO-based composite exhibited noticeable enhancement in the surface area and ytic performance compared to the pristine Ag2O-MnO2. The results revealed that (1%)Ag2O-MnO2/(5 weight%)GRO yst exhibited higher specific performance (13.3 mmol.g-1.h-1) with a 100% conversion of benzyl alc. (BnOH) and >99% selectivity towards benzaldehyde (BnH) within 30 min. The enhancement of the activity and selectivity of GRO-based nanoyst was attributed to the presence of various oxygen-containing functional groups, a large number of defects, and a high sp. surface area of GRO. In addition, the as-prepared nanoyst also demonstrated excellent ytic activity towards the conversion of a variety of other alcs. to resp. carbonyls under optimal conditions. Besides, the yst ((1%)Ag2O-MnO2/(5 weight%)GRO) could be efficiently recycled six times with no noticeable loss in its performance and selectivity. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Related Products of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Related Products of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Bispentiptycenyl-Diimine-Nickel Complexes for Ethene Polymerization and Copolymerization with Polar Monomers》 were Kanai, Yuki; Foro, Sabine; Plenio, Herbert. And the article was published in Organometallics in 2019. Application In Synthesis of 5-Hexen-1-ol The author mentioned the following in the article:

Ni2+ coordinated within a bowl-shaped diimine ligand with two pentiptycenyl-substituents [(ArN:CRCRN:Ar)NiBr2] (Ar = pentiptycenyl, 3a, RR = 1,8-naphthalenediyl, 3b, R = Me) displays excellent activity for the polymerization of ethene (7 atm) with activities of up to 34 × 103 kg(mol Ni)-1 h-1 following activation with Et2AlCl. The resulting polymer is characterized by high mol. weights (Mn = 150 × 103 g·mol-1), low branching (12/1000 C), and a high m.p. (Tm = 133 °C). The polymerization of ethene with polar comonomers leads to the formation of the resp. polar polymers with very efficient incorporation of comonomer. The activity of the catalyst critically depends on the molar ratio of Et2AlCl activator and the polar functional group. In the experiment, the researchers used 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application In Synthesis of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,ChemPhysChem included an article by Bouraoui, Amal; Ghanem, Rosy; Berchel, Mathieu; Vie, Veronique; Le Guen, Yann; Paboeuf, Gilles; Deschamps, Laure; Le Gall, Tony; Montier, Tristan; Jaffres, Paul-Alain. HPLC of Formula: 821-41-0. The article was titled 《Bis-thioether-containing lipid chains in cationic amphiphiles cationic amphiphiles: Physicochemical properties and applications in gene delivery》. The information in the text is summarized as follows:

Cationic amphiphiles featuring two thioether functions in each lipid chain of bicatenar cationic amphiphiles are reported here for the first time. The physicochem. properties and transfection abilities of these new amphiphiles were compared with those of already reported analogs featuring either (i) saturated, (ii) unsaturated or (iii) mono-thioether containing lipid chains. The homogeneity of the series of new compounds allowed to clearly underscore the effect of bis-thioether containing lipid chains. This study shows that besides previous strategies based on unsaturation or ramification, the incorporation of two thioether functions per lipid chain constitutes an original complementary alternative to tune the supramol. properties of amphiphilic compounds The potential of this strategy was evaluated in the context of gene delivery and report that two cationic amphiphiles (i. e. 4 a and 4 b) can be proposed as new efficient transfection reagents. The experimental part of the paper was very detailed, including the reaction process of 5-Hexen-1-ol(cas: 821-41-0HPLC of Formula: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.HPLC of Formula: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Molecules included an article by Markwart, Jens C.; Battig, Alexander; Velencoso, Maria M.; Pollok, Dennis; Schartel, Bernhard; Wurm, Frederik R.. Quality Control of 5-Hexen-1-ol. The article was titled 《Aromatic vs. aliphatic hyperbranched polyphosphoesters as flame retardants in epoxy resins》. The information in the text is summarized as follows:

The current trend for future flame retardants (FRs) goes to novel efficient halogen-free materials, due to the ban of several halogenated FRs. Among the most promising alternatives are phosphorus-based FRs, and of those, polymeric materials with complex shape have been recently reported. Herein, the authors present novel halogen-free aromatic and aliphatic hyperbranched polyphosphoesters (hbPPEs), which were synthesized by olefin metathesis polymerization and investigated them as a FR in epoxy resins. The authors compare their efficiency (aliphatic vs. aromatic) and further assess the differences between the monomeric compounds and the hbPPEs. The decomposition and vaporizing behavior of a compound is an important factor in its flame-retardant behavior, but also the interaction with the pyrolyzing matrix has a significant influence on the performance. Therefore, the challenge in designing a FR is to optimize the chem. structure and its decomposition pathway to the matrix, with regards to time and temperature This behavior becomes obvious in this study, and explains the superior gas phase activity of the aliphatic FRs. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Quality Control of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2022,Wang, Xiao-Xu; Yu, Lu; Lu, Xi; Zhang, Zhi-Lin; Liu, De-Guang; Tian, Changlin; Fu, Yao published an article in CCS Chemistry. The title of the article was 《NiH-catalyzed reductive hydrocarbonation of enol esters and ethersã€?Application of 821-41-0 The author mentioned the following in the article:

Chiral dialkyl carbinols and their derivatives are significant synthetic building blocks in organic chem. and related fields. The development of convenient and efficient methods to access these compounds has long been an important endeavor. Herein, authors report a NiH-catalyzed reductive hydroalkylation and hydroarylation of enol esters and ethers. α-Oxoalkyl organonickel species were generated in situ in a catalytic mode and then participated in cross-coupling with alkyl or aryl halides. This approach enabled C(sp3)-C(sp3) and C(sp3)-C(sp2) bond formation under mild reductive conditions with simple operations, thereby boosting a broad substrate scope and good functional compatibility. Esters of enantioenriched dialkyl carbinols were accessed in a catalytic asym. version. Mechanistic studies demonstrated that this reaction proceeded through a syn-addition of Ni-H intermediate to an enol ester with high regio- and enantioselectivity. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《A facile synthesis of ZrOx-MnCO3/graphene oxide (GRO) nanocomposites for the oxidation of alcohols using molecular oxygen under base free conditionsã€?was written by Adil, Syed Farooq; Assal, Mohamed E.; Shaik, Mohammed Rafi; Kuniyil, Mufsir; AlOtaibi, Nawaf M.; Khan, Mujeeb; Sharif, Muhammad; Alam, M. Mujah; Al-Warthan, Abdulrahman; Mohammed, Jabair Ali; Sdiqui, Mohammed Rafiq H.; Tahir, Muhammad Nawaz. Recommanded Product: 821-41-0This research focused onzirconium manganese carbonate graphene oxide nanocomposite alc oxidation. The article conveys some information:

Graphene and its nanocomposites are showing excellent potential in improving the catalytic performances of different materials. However, the synthetic protocol and its form, such as graphene oxide (GRO) or highly reduced graphene oxide (HRG), influence the catalytic efficiencies. Here, we present, a facile synthesis of graphene oxide (GRO) and ZrOx-MnCO3-based nanocomposites [(1%)ZrOx-MnCO3/(x%)GRO] and their outcome as an oxidation catalyst for alc. oxidation under mild conditions using O2 as a clean oxidant. The ZrOx-MnCO3/GRO catalyst prepared by incorporating GRO to pre-calcined ZrOx-MnCO3 using ball milling showed remarkable enhancement in the catalytic activities as compared to pristine ZrOx-MnCO3, ZrOx-MnCO3 supported on HRG or ZrOx-MnCO3/GRO prepared by in-situ growth of ZrOx-MnCO3 onto GRO followed by calcination. The catalyst with composition (1%)ZrOx-MnCO3/(1%)GRO exhibited superior specific activity (57.1 mmol/g·h) with complete conversion and >99% selectivity of the product within a short period of time (7 min) and at a relatively lower temperature (100°C). The catalyst could be recycled at least five times with a negligible decrease in efficiency and selectivity. The catalytic study was extended to different aromatic as well as aliphatic alcs. under optimized conditions, which confirmed the efficiency and selectivity of the catalyst. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Recommanded Product: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Recommanded Product: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Visible light-mediated ring-opening polymerization of lactones based on the excited state acidity of ESPT moleculesã€?was written by Zhang, Xun; Hu, Siping; Ma, Qiang; Liao, Saihu. Safety of 5-Hexen-1-ol And the article was included in Polymer Chemistry in 2020. The article conveys some information:

The excited state acidity of ESPT mols. is first demonstrated as a suitable means of catalysis for the light-regulated ring-opening polymerization of lactones, in combination with a photosensitizer as the energy-transfer cocatalyst to harness light. Under blue light irradiation, this method could afford metal-free polyesters with well-controlled mol. weights and narrow dispersities. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0Safety of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Safety of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts