Category: 821-41-0

In 2019,Polymer included an article by Cao, Yufeng; Hu, Guangwei; Lin, Shaohui; Rempel, Garry L.; Pan, Qinmin. Electric Literature of C6H12O. The article was titled 《Synthesis of precisely diphenyl ether-functionalized polyethylene via acyclic diene metathesis polymerization》. The information in the text is summarized as follows:

We demonstrated the facile synthesis of a new class of functionalized polyethylene containing precisely sequenced di-Ph ether moieties via acyclic diene metathesis (ADMET) polymerization of a series of α, ω-diene monomers (M1-M3) with central di-Ph ether segments and subsequent exhaustive hydrogenation. 1H and 13C NMR spectroscopy have provided unambiguous evidence for precise primary architectures of the synthesized monomers and the resulting polymers. The thermal behaviors of all polymers were systematically investigated by thermogravimetric anal. (TGA) and differential scanning calorimetry (DSC). The results indicate that the introduction of di-Ph ether segments significantly enhanced the thermal stability of the polyethylenes. Ring-opening insertion metathesis polymerization (ROIMP) of M1-M3 with cis-cyclooctene was also performed, and after exhaustive hydrogenation, a series of irregularly sequenced copolymers with less regular chain structure and lower di-Ph ether content were yielded. Those copolymers possess a broad and ill-defined melting transition compared with the precisely-defined saturated homopolymers. In the part of experimental materials, we found many familiar compounds, such as 5-Hexen-1-ol(cas: 821-41-0Electric Literature of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Electric Literature of C6H12O

Referemce:
Alcohol – Wikipedia,
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《Visible-Light-Induced Nickel-Catalyzed Cross-Coupling with Alkylzirconocenes from Unactivated Alkenes》 was published in Chem in 2020. These research results belong to Gao, Yadong; Yang, Chao; Bai, Songlin; Liu, Xiaolei; Wu, Qingcui; Wang, Jing; Jiang, Chao; Qi, Xiangbing. Application of 821-41-0 The article mentions the following:

Visible-light-induced single nickel-catalyzed C(sp3)-C(sp3), C(sp3)-C(sp2) and C(sp3)-C(sp) cross-coupling reactions were reported using alkylzirconocenes, which were easily generated in-situ from terminal or internal unactivated alkenes through hydrozirconation and chain walking. This method was mild and applicable for a large range of substrates including primary, secondary, tertiary alkyl, aryl, alkenyl, alkynyl halides and a variety of alkenes. Mechanistic studies suggested a novel nickel-catalyzed radical cross-coupling pathway, which represented the first visible-light-induced transformation of alkylzirconocenes. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Application of 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Application of 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Synlett included an article by Miura, Tomoya; Moriyama, Daisuke; Funakoshi, Yuuta; Murakami, Masahiro. Computed Properties of C6H12O. The article was titled 《Photoinduced 1,2-Hydro(cyanomethylation) of Alkenes with a Cyanomethylphosphonium Ylide》. The information in the text is summarized as follows:

An efficient method was developed for the 1,2-hydro(cyanomethylation) of alkenes, in which a cyanomethyl radical species was generated from a cyanomethylphosphonium ylide by irradiation with visible light in the presence of an iridium complex, a thiol, and ascorbic acid. The cyanomethyl radical species then adds across the C:C double bond of an alkene to form an elongated alkyl radical species that accepts a hydrogen atom from the thiol to produce an elongated aliphatic nitrile. The ascorbic acid acts as the reductant to complete the catalytic cycle. In the experimental materials used by the author, we found 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Computed Properties of C6H12O

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Alcohol – Wikipedia,
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The author of 《Synthesis of new polyesters by acyclic diene metathesis polymerization of bio-based α,ω-dienes prepared from eugenol and castor oil (undecenoate)》 were Le, Duy; Samart, Chanatip; Kongparakul, Suwadee; Nomura, Kotohiro. And the article was published in RSC Advances in 2019. Computed Properties of C6H12O The author mentioned the following in the article:

Synthesis of new polyesters by acyclic diene metathesis (ADMET) polymerization of α,ω-diene, 4-allyl-2-methoxyphenyl 10-undecenoate (M1), prepared from bio-renewable eugenol and castor oil (undecenoate), have been demonstrated. Ruthenium-carbene (called second generation Grubbs) catalyst afforded polymers with unimodal mol. weight distributions (Mn = 12 700, Mw/Mn = 1.85). The polymerization in the presence of a triarm crosslinker, 5-formylbenzene-1,2,3-triyl tris(undec-10-enoate), also afforded polymers with certain uniform network structures. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Computed Properties of C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Computed Properties of C6H12O

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Alcohol – Wikipedia,
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In 2022,Weil, Tatjana; Kirupakaran, Abbna; Le, My-Hue; Rebmann, Philipp; Mieres-Perez, Joel; Issmail, Leila; Conzelmann, Carina; Mueller, Janis A.; Rauch, Lena; Gilg, Andrea; Wettstein, Lukas; Gross, Ruediger; Read, Clarissa; Bergner, Tim; Palsson, Sandra Axberg; Uhlig, Nadja; Eberlein, Valentina; Woell, Heike; Klaerner, Frank-Gerrit; Stenger, Steffen; Kuemmerer, Beate M.; Streeck, Hendrik; Fois, Giorgio; Frick, Manfred; Braubach, Peter; Spetz, Anna-Lena; Grunwald, Thomas; Shorter, James; Sanchez-Garcia, Elsa; Schrader, Thomas; Muench, Jan published an article in JACS Au. The title of the article was 《Advanced Molecular Tweezers with Lipid Anchors against SARS-CoV-2 and Other Respiratory Viruses》.COA of Formula: C6H12O The author mentioned the following in the article:

The COVID-19 pandemic caused by SARS-CoV-2 presents a global health emergency. Therapeutic options against SARS-CoV-2 are still very limited but urgently required. Mol. tweezers are supramol. agents that destabilize the envelope of viruses resulting in a loss of viral infectivity. Here, we show that first-generation tweezers, I and II, disrupt the SARS-CoV-2 envelope and abrogate viral infectivity. To increase the antiviral activity, a series of 34 advanced mol. tweezers were synthesized by insertion of aliphatic or aromatic ester groups on the phosphate moieties of the parent mol. I. A structure activity relationship study enabled the identification of tweezers with a markedly enhanced ability to destroy lipid bilayers and to suppress SARS-CoV-2 infection. Selected tweezer derivatives retain activity in airway mucus and inactivate the SARS-CoV-2 wildtype and variants of concern as well as respiratory syncytial, influenza, and measles viruses. Moreover, inhibitory activity of advanced tweezers against respiratory syncytial virus and SARS-CoV-2 was confirmed in mice. Thus, potentiated tweezers are broad-spectrum antiviral agents with great prospects for clin. development to combat highly pathogenic viruses. In the experiment, the researchers used many compounds, for example, 5-Hexen-1-ol(cas: 821-41-0COA of Formula: C6H12O)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.COA of Formula: C6H12O

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Alcohol – Wikipedia,
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Yan, Feng-Zhi; Shao, Yuan-Guang; Zhang, Zibin; Shen, Yan-Feng; Huang, Xue-Chun; Zhang, Pei-Ling; Li, Shijun published their research in Synthesis in 2021. The article was titled 《Synthesis of Catenanes from a BMP32C10-Based Cryptand Tuned by the Linkage Length of Paraquat Salts》.Quality Control of 5-Hexen-1-ol The article contains the following contents:

A series of catenanes was synthesized through olefin metathesis from a BMP32C10-based cryptand and paraquat guests attached with two terminal alkenes. Distribution of catenane products could be significantly affected by linkage length on paraquat guests. In presence of BMP32C10-based cryptand, paraquat salt with a long linkage facilitates intramol. olefin metathesis to release a [2]catenane as sole catenation product, while use of a paraquat salt with a shorter linkage led to simultaneous generation of [2]-, [3]-, and [4]-catenanes. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Quality Control of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Quality Control of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Li, Xin; He, Songtao; Song, Qiuling published their research in Organic Letters in 2021. The article was titled 《Diethylzinc-Mediated Radical 1,2-Addition of Alkenes and Alkynes》.Category: alcohols-buliding-blocks The article contains the following contents:

A novel diethylzinc-mediated radical 1,2-addition of perfluoroalkyl iodides to unactivated alkenes and alkynes was presented, which demonstrates a novel way to generate an Et difluoroacetate radical. This method was highly efficient and gives full conversions of the substrates, high yields of the products and negligible byproducts and requires no column chromatog. purifications. The mild conditions enable this protocol to exhibited excellent functional group compatibility. The experimental process involved the reaction of 5-Hexen-1-ol(cas: 821-41-0Category: alcohols-buliding-blocks)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.Category: alcohols-buliding-blocks

Referemce:
Alcohol – Wikipedia,
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Abuhadba, Sara; Tsuji, Miu; Mani, Tomoyasu; Esipova, Tatiana V. published an article in 2021. The article was titled 《meso-Antracenyl-BODIPY Dyad as a New Photocatalyst in Atom-Transfer Radical Addition Reactions》, and you may find the article in ACS Omega.Application In Synthesis of 5-Hexen-1-ol The information in the text is summarized as follows:

We demonstrate that because of the efficient generation of triplet excited state under UV or visible-light irradiation, meso-antracenyl-BODIPY donor-acceptor dyad can catalyze atom-transfer radical addition (ATRA) reactions between bromomalonate and alkenes. This finding paves the way for the design and application of the new type of heavy atom-free organic chromophores for photocatalysis. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0Application In Synthesis of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Application In Synthesis of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sun, Bin; Zhu, Rui; Zhuang, Xiaohui; Shi, Xiayue; Huang, Panyi; Yan, Zhiyang; Yu, Chuanming; Jin, Can published their research in Organic Letters in 2021. The article was titled 《Visible Light/Tertiary Amine Promoted Synergistic Hydroxydifluoroacetamidation of Unactivated Alkenes under Air》.SDS of cas: 821-41-0 The article contains the following contents:

An efficient and novel method for regioselective hydroxydifluoroacetamidation of alkenes with bromodifluoroacetamides were achieved via a tandem radical pathway mediated by photoredox catalysis under metal-free conditions. This transformation proceeded smoothly in the presence of rhodamine 6G, which afforded a series of α,α-difluoro-γ-hydroxyacetamides in moderate to excellent yields. The significant advantages of this protocol was the low-cost photocatalyst, readily available starting materials, synthetic convenience and wide functional group compatibility. The results came from multiple reactions, including the reaction of 5-Hexen-1-ol(cas: 821-41-0SDS of cas: 821-41-0)

5-Hexen-1-ol(cas: 821-41-0) is a volatile organic compound. Further, it is used to prepare 6-bromo-hex-1-ene by reaction with phosphorus tribromide.SDS of cas: 821-41-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Reference of 5-Hexen-1-olIn 2021 ,《Spreading Dynamics of a Precursor Film of Ionic Liquid or Water on a Micropatterned Polyelectrolyte Brush Surface》 was published in Langmuir. The article was written by Shiomoto, Shohei; Higuchi, Hayato; Yamaguchi, Kazuo; Takaba, Hiromitsu; Kobayashi, Motoyasu. The article contains the following contents:

Time evolution of the microscopic wetting velocity of 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMI-TFSI) or water on a micrometer-scale line-patterned surface with a poly(3-sulfopropyl methacrylate) brush and a hydrophobic perfluoroalkyl monolayer was precisely measured by direct observation using optical microscopy and a selective dyeing method over a long period (178 days). When a liquid droplet was placed on the dyed line-patterned brush surface, the liquid penetrated and spread into the polymer brush layer, forming a precursor thin film that extended beyond the macroscopic contact line. The elongation proceeded in two stages by an adiabatic process followed by a diffusive process. The elongation distance X increased with time in proportion to t2.6 for water and t0.81 for EMI-TFSI during the adiabatic process. In a diffusive process, the advancing velocity of the precursor film was markedly reduced to be expressed as X t0.66 for water and Xn t0.21 for EMI-TFSI, indicating that the diffusive process was affected by the energy dissipation of the wetting system. The high viscosity and the strong mol. interaction of EMI-TFSI with the polymer brush gave a large entropy change during the wetting process to result in a slower spreading velocity. After reading the article, we found that the author used 5-Hexen-1-ol(cas: 821-41-0Reference of 5-Hexen-1-ol)

5-Hexen-1-ol(cas: 821-41-0) is used in cyclization to a tetrahydropyran by phenylselenoetherification. It is also used as a building block in synthetic chemistry.Reference of 5-Hexen-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts