Category: 80-09-1

Wang, Qiuxu published the artcileSimultaneous determination of seven bisphenol analogues in surface water by solid-phase extraction and ultra-performance liquid chromatography-tandem mass spectrometry, Quality Control of 80-09-1, the publication is Microchemical Journal (2022), 107098, database is CAplus.

For the simultaneous determination of seven types of bisphenol analogs (BPs) in surface water, a method combining solid-phase extraction (SPE) with ultra-performance liquid chromatog.-tandem mass spectrometry (UPLC-MS/MS) was developed. The extraction efficiency was improved by optimizing the parameters that affect it, including the sorbent types of SPE cartridge, pH, enrichment factor, flow rate, rinsing and elution volume On the basis of the single factor experiments, an attempt to obtain the result of optimizing by response surface methodol. was made, and the optimal parameters were as follows: at a flow rate of 8 mL/min, 1000 mL of water sample was run through the hydrophilic-lipophilic balance cartridge, rinsed with 10% methanol, eluted with 9 mL methanol, and concentrated with nitrogen using an automatic SPE system. The analytes were separated on an Acquity UPLC BEH C18 column using gradient elution with a mobile phase of acetonitrile and 0.05% (volume/volume) ammonia, and then analyzed using UPLC-MS/MS with multiple reaction monitoring in the neg.-ion mode, with an 8-min chromatog. run time. In the range of 1.0-500μg/L, seven BPs showed good linearity with the correlation coefficient greater than 0.998. The recovery ranged from 82.3 to 96.7%, and the range of matrix effect was 89.2 to 107%. These results indicated excellent recovery and minimal matrix effect. The limits of detection were 0.05-1.5 ng/L, the relative standard deviation ranged from 2.9 to 8.5%. Applying the developed method, seven BPs in Luoma Lake and its inflow rivers were analyzed. Only five BPs were detected in Luoma Lake and four BPs were detected in inflow rivers, and the concentrations of the detected BPs were determined BPA and BPF were the predominant BPs, and the concentration of BPA was the highest.

Microchemical Journal published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C8H6ClF3, Quality Control of 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Wang, Ruihua published the artcileThe bisphenol F and bisphenol S and cardiovascular disease: results from NHANES 2013-2016, Quality Control of 80-09-1, the publication is Environmental Sciences Europe (2022), 34(1), 4, database is CAplus.

Bisphenol F (BPF) and bisphenol S (BPS) have replaced bisphenol A (BPA) in the manufacturing of products containing polycarbonates and epoxy resins; however, the effects of these substitutes on the risk of cardiovascular disease (CVD), including congestive heart failure, coronary heart disease, angina pectoris, heart attack, and stroke, have not been assessed. To examine the association of urinary BPS and BPF with CVD risk in a U.S. representative U.S. population. Cross-sectional data from 1267 participants aged 20-80 years from the 2013-2016 National Health and Nutrition Examination Survey (NHANES) were analyzed. Survey-weighted multiple logistic regression was used to assess the association between BPA, BPF, BPS and CVD. The Bayesian kernel machine regression (BKMR) model was applied to assess the mixture effect. A total of 138 patients with CVD were identified. After adjusting for potential confounding factors, the T3 tertile concentration of BPS increased the risk of total CVD (OR: 1.99, 95% CI 1.16-3.40). When stratified by age, we found that BPS increased the risk of CVD in the 50-80 age group (OR: 1.40, 95% CI 1.05-1.87). BPS was pos. associated with the risk of coronary heart disease, and the T3 tertile concentration of BPS increased the coronary heart disease risk by 2.22 times (95% CI 1.04-4.74). No significant association was observed between BPF and CVD. Although the BKMR model did not identify the mixed exposure effect of BPS, the risk of CVD increased with increasing compound concentration Our results suggest that BPS may increase the risk of total CVD and coronary heart disease in the US population, and prospective studies are needed to confirm the results.

Environmental Sciences Europe published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C19H14O2, Quality Control of 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Li, Shihuan published the artcileHollow fiber membrane-protected amino/hydroxyl bifunctional microporous organic network fiber for solid-phase microextraction of bisphenols A, F, S, and triclosan in breast milk and infant formula, Safety of 4,4′-Sulfonyldiphenol, the publication is Food Chemistry (2022), 133217, database is CAplus and MEDLINE.

Bisphenols and triclosan have been used in various products, and exposure to these chems. may affect human health. The present study proposes a sensitive method for the determination of bisphenols A, F, S, and triclosan. The fiber was coated by amino/hydroxyl bifunctional microporous organic network and protected by polyvinylidene fluoride hollow fiber membrane for direct immersion solid phase microextraction The limit of detection was 0.005μg/L (μg/kg), and the recoveries were in the range of 76.7% to 107.5% (87.4% to 107.6%) for breast milk (infant formula), with intra-day and inter-day precisions <10.5% (7.3%) and 13.6% (8.4%), resp. Fiber-to-fiber reproducibility of < 9.5% and a lifespan of >100 cycles were obtained. The 95th percentile estimated daily intake of total bisphenols was close to temporary tolerable daily intake for infants fed by human milk, which highlighted the needs for further attention on human exposure to BPA and its substitutes.

Food Chemistry published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C12H10O4S, Safety of 4,4′-Sulfonyldiphenol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Gao, Qingwei published the artcileExploring the synergism of sunlight and electrooxidation on persulfate activation for efficient degradation of bisphenol S: Performance, Pathway, and mechanism, SDS of cas: 80-09-1, the publication is Chemical Engineering Journal (Amsterdam, Netherlands) (2022), 437(Part_1), 135318, database is CAplus.

Sulfate radical-based advanced oxidation processes had been widely applied in the water treatment. In this study, a novel solar-assisted electrooxidation process (SEOP) to activate peroxymonosulfate (PMS) or peroxydisulfate (PDS) was conducted for the degradation of bisphenol S (BPS). The SEOP with persulfate (PS) demonstrated its synergistic effect for BPS degradation, compared with the electrooxidation/PS and the solar process. The hydroxyl radical, sulfate radical (SO·-4), and singlet oxygen were regarded as primary active species in BPS degradation in SEOP with PS. The transition structure complex (persulfate*) on the anode promoted the efficiency of BPS degradation via the non-radical mechanism. The activation of PMS and PDS in SEOP was dominated through radical and non-radical mechanism, resp. To effectively supplement exptl. work with quantum chem. calculation, d. function theory (DFT) showed that the active sites mainly focused on the phenol ring of BPS. The energy barrier calculation indicated that BPS was more susceptible to be attacked by SO·-4 through electron transfer. BPS was mainly degraded by ring-opening, substitution, addition, C-C bond breaking, and decarboxylation reactions. Furthermore, the effective decrease in bio-toxicity of BPS intermediates in SEOP with PS was predicted. Experiments under various current densities, initial concentration of PS, electrolyte, and humic acid suggested the feasibility of SEOP with PS. BPS was degraded with lower energy consumption (0.18 kWh·m^-3·order^-1) in SEOP with PMS than that in SEOP with PDS (0.30 kWh·m^-3·order^-1) and without PS (0.38 kWh·m^-3 order^-1), resp. The SEOP with PS poses the feasible, convenient, and economic potential for the degradation of refractory pollutants.

Chemical Engineering Journal (Amsterdam, Netherlands) published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C12H10O4S, SDS of cas: 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Kaya, S. Irem published the artcileSimple preparation of surface molecularly imprinted polymer based on silica particles for trace level assay of bisphenol F, Application In Synthesis of 80-09-1, the publication is Analytical and Bioanalytical Chemistry (2022), 414(19), 5793-5803, database is CAplus and MEDLINE.

A new electrochem. sensor based on molecularly imprinted tetra-Et orthosilicate (TEOS)-based porous interface was developed for selective recognition of bisphenol F (BPF) in this study. The sensor was prepared by depositing the solution containing TEOS and L-tryptophan (L-Trp) in the presence of cetyltrimethylammonium bromide (CTAB) as a pore-maker via hydrolysis/condensation reaction on the glassy carbon electrode (GCE). While the surface morphol. and structure characterization were carried out using Fourier transform IR spectroscopy (FTIR) and SEM (SEM), electrochem. characterization was performed through electrochem. impedance spectroscopy (EIS) and cyclic voltammetry (CV). The resulted MIP(TEOS:L-Trp)@GCE achieved a wide linear range of 1 x 10^-15-1 x 10^-14 M for BPF detection with an excellent detection limit of 0.291 fM. Furthermore, the recovery of BPF from spiked bottled water and serum samples varied between 98.83 and 101.03%. These results demonstrate that MIP(TEOS:L-Trp)@GCE was found to be a simple, sensitive, and selective smart interface to detect trace pollution even from complicated samples.

Analytical and Bioanalytical Chemistry published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C12H10O4S, Application In Synthesis of 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Harris, Sean M. published the artcileA Data Mining Approach Reveals Chemicals Detected at Higher Levels in Non-Hispanic Black Women Target Preterm Birth Genes and Pathways, HPLC of Formula: 80-09-1, the publication is Reproductive Sciences (2022), 29(7), 2001-2012, database is CAplus and MEDLINE.

Preterm birth occurs disproportionately in the USA non-Hispanic Black population. Black women also face disproportionate exposure to certain environmental chems. The goal of this study was to use publicly available toxicogenomic data to identify chem. exposures that may contribute to preterm birth disparities. We tested 19 chems. observed at higher levels in the blood or urine of non-Hispanic Black women compared to non-Hispanic White women. We obtained chem.-gene interactions from the Comparative Toxicogenomics Database and a list of genes involved in preterm birth from the Preterm Birth Database. We tested chems. for enrichment with preterm birth genes using chi-squared tests. We then conducted pathway enrichment anal. for the preterm birth genes using DAVID software and identified chem. impacts on genes involved in these pathways. Genes annotated to all 19 chems. were enriched with preterm birth genes (FDR-adjusted p value < 0.05). Preterm birth enriched chems. that were detected at the highest levels in non-Hispanic Black women included Me mercury, methylparaben, propylparaben, di-Et phthalate, dichlorodiphenyldichloroethylene, and bisphenol S. The preterm birth genes were enriched for pathways including “inflammatory response” (FDR-adjusted p value = 3 x 10-19), “aging” (FDR-adjusted p value = 4 x 10-8) and “response to estradiol” (FDR-adjusted p value = 2 x 10-4). Chems. enriched with preterm birth genes impacted genes in all three pathways. This study adds to the body of knowledge suggesting that exposures to environmental chems. contribute to racial disparities in preterm birth and that multiple chems. drive these effects. These chems. affect genes involved in biol. processes relevant to preterm birth such as inflammation, aging, and estradiol pathways.

Reproductive Sciences published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C12H10O4S, HPLC of Formula: 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Tkalec, Ziga published the artcileLC-HRMS based method for suspect/non-targeted screening for biomarkers of chemical exposure in human urine, Category: alcohols-buliding-blocks, the publication is Chemosphere (2022), 134550, database is CAplus and MEDLINE.

Every day we are exposed to a cocktail of anthropogenic compounds many of which are biol. active and capable of inducing neg. effects. The simplest way to monitor contaminants in a population is via human biomonitoring (HBM), however conventional targeted approaches require foreknowledge of chems. of concern, often have compound specific extractions and provide information only for those compounds This study developed an extraction process for human biomarkers of interest (BoE) in urine that is less compound specific. Combining this with an ultra-high resolution mass spectrometer capable of operating in full scan, and a suspect and non-targeted anal. (SS/NTA) approach, this method provides a more holistic characterization of human exposure. Sample preparation development was based on enzymically hydrolyzed urine spiked with 34 native standards and extracted by solid-phase extraction (SPE). HRMS data was processed by MzMine2 and 80% of standards were identified in the final data matrix using typical NTA data processing procedures.

Chemosphere published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C11H10N4, Category: alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Yin, Zhenting published the artcileHierarchical Ti3C2Tx@BPA@PCL for flexible polyurethane foam capable of anti-compression, self-extinguishing and flame-retardant, Quality Control of 80-09-1, the publication is Journal of Colloid and Interface Science (2022), 208-220, database is CAplus and MEDLINE.

It is of great importance to fabricate flexible polyurethane foam (FPUF) with superior mech. properties and flame retardancy for practical applications. Herein, organosilicon and Ph phosphorus compounds were synthesized and grafted on the surface of Ti₃C₂T_x (Ti₃C₂T_x@BPA@PCL) via in-situ polymerization Then, the FPUF composites were fabricated, combining intrinsic flame retardancy (9,10-dihydro-9-oxa-10-phosphaphenanthrene 10-oxide-diethanolamine: DH-DOPO) (addition amount: 20 wt%) and Ti₃C₂T_x@BPA@PCL (addition amount: 4 wt%). Attributed to the rigid structure of Ti₃C₂T_x@BPA@PCL, the tensile strength and compression strength of FPUF showed 24.0% and 253% increase, resp. In addition, anti-fatigue properties of FPUF composites during the cyclical test were dramatically enhanced. In contrast to pure FPUF, 36.1% and 44.0% reductions in peak heat release rate (pHRR) and total heat release (THR) were achieved for the FPUF containing Ti₃C₂T_x@BPA@PCL and DH-DOPO, the production rate of carbon dioxide (CO₂) and carbon oxide (CO) also decreased by 40.3% and 52.1%, resp. FPUF4 showed self-extinguishing behavior, and passed the vertical burning test (VBT). This work provides a facile approach to preparing high-performance FPUF with enhanced mech. property and flame retardancy.

Journal of Colloid and Interface Science published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C2H4ClNO, Quality Control of 80-09-1.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Zhang, Yuhuan published the artcileTailoring diameters of carbon nanofibers with optimal mesopores to remarkably promote hemin adsorption toward ultrasensitive detection of bisphenol A, Application of 4,4′-Sulfonyldiphenol, the publication is Food Chemistry (2022), 132628, database is CAplus and MEDLINE.

Bisphenol A (BPA) is a worldwide used endocrine disrupting chem. that can migration from food containers and packaging, resulting in bioaccumulation of BPA in humans and causing adverse health effects. Porous electrodes have been proved with large surface areas and high sensing abilities in electrochem. detection of BPA. However, how to tailor the pore sizes to further improve the sensing performance is still a great challenge. Here, we delicately tailored the diameters of carbon nanofibers (CNFs) by adjusting electrospinning parameters to have optimal mesopore structure for strong adsorption of hemin that has been demonstrated with high electrocatalytic activity for BPA sensing. Benefiting from the optimal mesopores structure of CNFs and the synergistic effect of hemin and CNFs, this hemin@CNFs based sensor achieves an ultrahigh sensitivity of 40.97μA cm-2μM-1, a low detection limit of 3.1 nM and satisfactory recoveries from 90.2% to 104.2% in the direct detection of BPA in liquors. This work offers a promising sensing platform for ultrasensitive monitoring of BPA.

Food Chemistry published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C5H7NO, Application of 4,4′-Sulfonyldiphenol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Memon, Almas F. published the artcileElectrochemical monitoring of bisphenol-s through nanostructured tin oxide/Nafion/GCE: A solution to environmental pollution, Formula: C12H10O4S, the publication is Chemosphere (2022), 303(Part_3), 135170, database is CAplus and MEDLINE.

Over the past few decades, phenolic compounds have been broadly exploited in the industries to be utilized in several applications including polycarbonate plastic, food containers, epoxy resins, etc. One of the major compounds in phenolics is Bisphenol-S (BPS) which has dominantly replaced Bisphenol-A in several applications. Phenolic compounds are extensively drained into the environment without proper treatment and cause several health hazards. Thus, to tackle this serious problem an electrochem. sensor based on SnO2/GCE has been successfully engineered to monitor the low-level concentration of BPS in water samples. The fabrication of SnO₂ nanoparticles (SnO₂ NPs) was confirmed through FTIR, XRD, and TEM to examine the size, crystallinity, internal texture, and functionalities of the prepared material. The fabricated material was exploited as a chem. modified sensor for the determination of BPS in water samples collected from different sources. Under optimal conditions such as scan sweep 100 mV/s, PBS electrolyte pH of 6, potential window (0.3-1.3 V), the proposed sensor manifested an excellent response for BPS. The LOD of the present method for BPS was calculated as 0.007μM, resp. Moreover, the stability and selectivity profile of SnO₂/GCE for BPS in the real matrix was examined to be outstanding.

Chemosphere published new progress about 80-09-1. 80-09-1 belongs to alcohols-buliding-blocks, auxiliary class Ploymers, name is 4,4′-Sulfonyldiphenol, and the molecular formula is C12H10O4S, Formula: C12H10O4S.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts