Category: 70110-65-5

Xu, Huanjun published the artcileReductive cleavage of inert aryl C-O bonds to produce arenes, COA of Formula: C15H16O3, the publication is Chemical Communications (Cambridge, United Kingdom) (2015), 51(61), 12212-12215, database is CAplus and MEDLINE.

Reductive cleavage of the aryl C-O bonds in various phenolic compounds and aryl ethers was achieved using LiAlH₄ combined with KOtBu and without any other catalysts or additives, solely producing arenes in high yields.

Chemical Communications (Cambridge, United Kingdom) published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C11H10ClNO, COA of Formula: C15H16O3.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Gao, Fang published the artcileFragmentation of Lignin Samples with Commercial Pd/C under Ambient Pressure of Hydrogen, Name: 2-Phenoxy-1-phenylpropane-1,3-diol, the publication is ACS Catalysis (2016), 6(11), 7385-7392, database is CAplus.

We report the reagentless cleavage of prevalent β-O-4 linkages in lignin model compounds, as well as the cleavage of several types of organosolv lignins, catalyzed by com. available Pd/C. Such lignin fragmentation occurred without added reagent if the indigenous double bonds were reduced first or it occurred under conditions in which just 1 atm of hydrogen was added to the system to reduce C=C bonds of the original lignin sample in situ prior to fragmentation. A detailed view of the sites of cleavage of lignin samples from various sources was gained by HSQC NMR experiments Complex model compounds were prepared and shown to form simpler arenes and substituted phenols under catalytic conditions without added reagents. The hydrogen generated in situ from alc. functionalities provides the reductant for concomitant hydrogenolysis of C-O bonds in β aryl ethers. Decarbonylation of primary alcs. also occurred, and this process resulted in significant amounts of aromatic products containing substituents bearing one fewer carbon atom than the original linkages in lignin. The fragmentations of synthetic lignin and several organosolv lignins derived from Miscanthus giganteus and pine tree were conducted. Because the lignins contain alkenes that accept the hydrogen, two procedures involving reduction of the alkenes prior to C-O bond cleavage were developed. The first procedure involves reduction of the alkenes, followed by catalytic cleavage of C-O bonds after saturation of the C-C bonds; a second involves cleavage of lignin samples in the presence of 1 atm of hydrogen to saturate the alkenes before cleavage in situ. These protocols convert solid lignin to monomeric phenolic compounds with 20 mol % catalyst or to an oil (with 5 mol % Pd/C loading) having favorable viscosity parameters upon blending with a renewable organic solvent.

ACS Catalysis published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Name: 2-Phenoxy-1-phenylpropane-1,3-diol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Luo, Huihui published the artcileCobalt Nanoparticles-Catalyzed Widely Applicable Successive C-C Bond Cleavage in Alcohols to Access Esters, Recommanded Product: 2-Phenoxy-1-phenylpropane-1,3-diol, the publication is Angewandte Chemie, International Edition (2020), 59(43), 19268-19274, database is CAplus and MEDLINE.

Selective cleavage and functionalization of C-C bonds have important applications in organic synthesis and biomass use. However, functionalization of C-C bonds by controlled cleavage remains difficult and challenging because they are inert. Herein, the authors describe an unprecedented efficient protocol for the breaking of successive C-C bonds in alcs. to form esters with one or multiple carbon atoms less using heterogeneous cobalt nanoparticles as catalyst with dioxygen as the oxidant. A wide range of alcs. including inactive long-chain alkyl aryl alcs. undergo smoothly successive cleavage of adjacent -(C-C)_n– bonds to afford the corresponding esters. The catalyst was used for seven times without any decrease in activity. Characterization and control experiments disclose that cobalt nanoparticles are responsible for the successive cleavage of C-C bonds to achieve excellent catalytic activity, while the presence of Co-N_x has just the opposite effect. Preliminary mechanistic studies reveal that a tandem sequence reaction is involved in this process.

Angewandte Chemie, International Edition published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Recommanded Product: 2-Phenoxy-1-phenylpropane-1,3-diol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Luo, Huihui published the artcileNitrogen-Doped Carbon-Modified Cobalt-Nanoparticle-Catalyzed Oxidative Cleavage of Lignin β-O-4 Model Compounds under Mild Conditions, Quality Control of 70110-65-5, the publication is ACS Sustainable Chemistry & Engineering (2018), 6(11), 14188-14196, database is CAplus.

A noble-metal-free Co-based catalyst, derived from pyrolysis of natural vitamin B₁₂ on activated carbon, is developed for the first time for one-pot oxidative cleavage of lignin linkages to phenols and aromatic esters with mol. oxygen as the oxidant under mild reaction conditions. High yields of phenol were obtained, and no oxidative coupling of phenol was produced based on the present cobalt catalyst. Compared to the previous report, the present catalyst can achieve the oxidative cleavage of β-O-4 ketones even at room temperature using a dioxygen balloon. The heterogeneous catalyst shows robust recyclability and can be conveniently recovered and reused up to eight times without an appreciable loss of catalytic activity. Moreover, this catalyst system can realize the bond cleavage of organosolv lignin. The evidence of depolymerization was given by two-dimensional heteronuclear single quantum coherence NMR and gel permeation chromatog. Characterization of the catalyst by inductively coupled plasma, N₂ adsorption-desorption, Raman spectroscopy, SEM, transmission electron microscopy (TEM), high-resolution TEM, high-angle angular dark-field scanning TEM, energy-dispersive X-ray spectroscopy, XPS, and control experiments provide a fundamental understanding of the catalytic materials and the reaction pathway. Co₃O₄ in situ supported on a N-doped carbon matrix by the way of high-temperature pyrolysis might be a catalytically active species. Two reaction intermediates are detected and confirmed by gas chromatograph-mass spectrometry.

ACS Sustainable Chemistry & Engineering published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Quality Control of 70110-65-5.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Zhu, Qilei published the artcileCatalytic C(β)-O Bond Cleavage of Lignin in a One-Step Reaction Enabled by a Spin-Center Shift, Related Products of alcohols-buliding-blocks, the publication is ACS Catalysis (2021), 11(22), 14181-14187, database is CAplus.

A challenge to the utilization of lignin as a feedstock for aromatic fine chems. lies in selective cleavage of copious β-O-4 linkages. A photocatalytic strategy for the selective cleavage of the C(β)-O bonds of model substrates and natural lignin extracts is achieved by a redox-neutral, catalytic cycle that does not require stoichiometric reagents. Mechanistic studies reveal the generation of a thiyl radical, which is derived from a cystine-derived H-atom transfer catalyst, initiates a spin-center shift (SCS) that leads to C(β)-O bond cleavage. The SCS reactivity is reminiscent of the C(β)-O bond cleavage chem. that occurs in the active site of ribonucleotide reductase.

ACS Catalysis published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C20H28B2O4S2, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Luo, Zhicheng published the artcileTransition metal-like carbocatalyst, COA of Formula: C15H16O3, the publication is Nature Communications (2020), 11(1), 4091, database is CAplus and MEDLINE.

Catalytic cleavage of strong bonds including hydrogen-hydrogen, carbon-oxygen, and carbon-hydrogen bonds is a highly desired yet challenging fundamental transformation for the production of chems. and fuels. Transition metal-containing catalysts are employed, although accompanied with poor selectivity in hydrotreatment. Here we report metal-free nitrogen-assembly carbons (NACs) with closely-placed graphitic nitrogen as active sites, achieving dihydrogen dissociation and subsequent transformation of oxygenates. NACs exhibit high selectivity towards alkylarenes for hydrogenolysis of aryl ethers as model bio-oxygenates without over-hydrogeneration of arenes. Activities originate from cooperating graphitic nitrogen dopants induced by the diamine precursors, as demonstrated in mechanistic and computational studies. We further show that the NAC catalyst is versatile for dehydrogenation of ethylbenzene and tetrahydroquinoline as well as for hydrogenation of common unsaturated functionalities, including ketone, alkene, alkyne, and nitro groups. The discovery of nitrogen assembly as active sites can open up broad opportunities for rational design of new metal-free catalysts for challenging chem. reactions.

Nature Communications published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, COA of Formula: C15H16O3.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Freudenberg, Karl published the artcileSynthetic experiments connected with lignin, Application In Synthesis of 70110-65-5, the publication is Annalen der Chemie, Justus Liebigs (1953), 40-53, database is CAplus.

The following model substances are in part related to the dimers obtained by F. in experiments with coniferyl alc. (C.A. 47, 12296g), which are considered “secondary building stones” in lignin formation. Veratraldehyde condensed with CH₂(CO₂H)₂ gave quant. yields of 3,4-(MeO)₂C₆H₃CH:CHCO₂H, whose Et ester (obtained in 94% yield) with Br in CHCl₃ in artificial light yielded the dibromide, m. 110°; this was refluxed 7-8 hrs. with 3 moles KOH in alc., cooled, filtered, neutralized gradually (at about 0°) with concentrated HCl, refiltered, and concentrated in vacuo. Any salts that had been filtered, combined with those separating on concentration, were dissolved in H₂O and acidified with 20% H₂SO₄, giving 20-30% 3,4-(MeO)₂C₆H₃CCCO ₂H (I), m. 156° (Fulton and Robinson, J. Chem. Soc. 1903, 1463). Carefully purified 4,3-Me(MeO)C₆H₃OH (13.8 g.) and 50 cc. MeOH containing 2.3 g. Na, evaporated in vacuo, heated 5 hrs. at 100° with 22 g. I Me ester, 50 cc. PhMe, and 13.8 g. creosol, allowed to stand 12 hrs. at room temperature, extracted with Et₂O, shaken repeatedly with aqueous H₂SO₄, and the excess creosol extracted from the Et₂O with aqueous NaOH, followed by washing, drying, evaporation, and fractionation, gave 17 g. Me β-(3-methoxy-4-methylphenoxy)-3,4-dimethoxycinnamate (II), prisms, m. 107-8°. At -70 to -80°, 5 g. crude II in 100 cc. dry Et₂O with 0.3 g. LiAlH₄ in 26 cc. Et₂O gave a precipitate which, when decomposed with H₂SO₄, yielded a mixture of creosol, dimethoxycinnamyl alc. (III), and α-(2-methoxy-4-methylphenoxy)-3,4-dimethoxycinnamyl alcohol (IV). III and IV could not be separated by distillation, or by adsorption in C₆H₆ on Al₂O₃ but the separation was effected on a paper chromatogram with C₆H₆ (R_f of III and IV being 0 and 0.9, resp.). IV was noncrystalline, but gave a red, crystalline p-PhN₂C₆H₄CO derivative, m. 118-19°; and a crystalline phenyl-urethan, m. 134-5°. The phenylurethan of III m. 107-8°. PhOCH₂CO₂Me (22 g.) and 14 g. BzH reacted vigorously with 3 g. Na wire and 40 cc. dry Et₂O. After 12 hrs. 8.2 g. glacial AcOH, 60 cc. H₂O, and 20 cc. Et₂O were added successively, giving 38% PhCH(OH)CH(OPh)CO₂Na (V), the Et₂O and alc. washings from which, when concentrated and esterified, yielded 48% PhCH:C(OPh)CO₂Me (VI), b₁₁ 210°, m. 60-1°. The free acid from V, oil (not characterized) gave the Me ester (VII), m. 61° (from petr. ether); Ac derivative of VII, m. 69-70°; S-benzylthiuronium salt (corresponding to V), m. 188°. VI in Et₂O, under N at -70° with LiAlH₄, gradually warmed to -20° with aqueous H₂SO₄ gave PhCH:C(OPh)CH₂OH, viscous oil; phenyl urethan, m. 104°. VII, similarly reduced (at -20°) gave PhCH(OH)CH(OPh)CH₂OH, b₁ 197°, m. 74-5°. Using Giacosa’s technique [J. prakt. Chem. 19, 396(1879)] but with longer initial heating, creosol, ClCH₂CO₂H, and NaOH gave 67% 4,2-Me(MeO)C₆H₃OCH₂CO₂H, m. 115°; Me ester (VIII), b₁₁ 167°; amide, m. 134-5°. Veratraldehyde (15.8 g.), 20 g. VIII, and 2.2 g. powd. Na under Et₂O, first cooled, then heated several hrs. on a steam bath and acidified with AcOH, gave 3,4-(MeO)₂C₆H₃CH:CRCO₂Me (IX) [R in this and other compounds = 4,2-Me(MeO)C₆H₃O], which, reduced with LiAlH₄ at -70° yielded the alc., C₁₉H₂₂O₅ (isolated by treating the intermediate salt, under Et₂O, with Dry Ice), oil, setting to a resin; 3,5-dinitrobenzoale, yellow needles, m. 158-9° (from BuOH). When 15.8 g. veratraldehyde, 20 g. VIII, 2.2 g. Na, and 50 cc. Et₂O were kept at about 0° and then acidified with aqueous AcOH, the product was a mixture, b_0.01 225°, of IX and 3,4-(MeO)₂C₆H₃(OH)CHRCO₂Me, m. 137° (from aqueous MeOH). To 8 g. Na (powdered under 100 cc. absolute PhMe) were added successively 25 g. abs EtOH and 50 g. vanillin, and the resulting Na derivative was filtered, triturated with and suspended in PhMe, well-cooled, and treated with freshly distilled ClCH₂OMe; this kept at least 6 hrs. at room temperature, washed with 2% NaOH, and fractionated gave 41 g. methoxymethylvanillin (X), b_1.5 145-7°, m. 39-40°. Freshly prepared X (9.8 g.) fused with 10.5 g. VIII, the product cooled, treated with 1.15 g. Na wire and 40 cc. Et₂O, allowed to stand overnight, 3.1 g. AcOH in 40 cc. H₂O added, and the mixture extracted with Et₂O gave 9 g. 4,3-(MeOCH₂O)(MeO)C₆H₃CH(OH)CHRCO₂Me, b_0.05 175-7°. With 30 g. 14-day-old X (or with fresh X containing small amounts of vanillin), the reaction was sluggish and required heating for completion, giving as the principal product 3,4-MeO(MeOCH₂O)C₆H₃CH: CRCO₂Me (XI), m. 112-13° (from aqueous MeOH). With a drop of H₂SO₄, AcOH, and Ac₂O, 2 g. XI at 0° gave, after 1.5 hrs., 1.3 g. 3,4-MeO(AcO)C₆H₃CH:CRCO₂Me (XII), m. 80° (from aqueous EtOH); when cooling was omitted, but the reaction continued for 8 hrs., the yield of XII was 87%. XII reduced with LiAlH₄ under N at -20°, followed by a fully described extensive purification, including chromatographic fractionation on powd. cellulose, gave 3,4-MeO(HO)C₆H₃CH:CRCH₂OH (XIII), b_0.0001 140° (bath temperature), prisms, m. 90-1° (from CH₂Cl₂-petr. ether). Hydrogenated in MeOH with 5% Pd-BaSO₄, XII gave the dihydro derivative, C₂₁H₂₄C₇, b_0.01 197°, which, reduced with LiAlH₄, yielded the dihydro derivative of XIII, C₁₈H₂₂O₅, b_0.01 150°. Vanillin (10 g.), 6.25 g. CH₂ClCO₂H, 8.5 g. KOH, and 30 cc. H₂O heated 4 hrs. at 100° and acidified with aqueous HCl gave quantitatively 2,4-MeO(OHC)C₆H₃OCH₂CO₂H, m. 188-9° [Elkan, Ber. 19, 3045(1886)], 8 g. of which with 10 g. CH₂(CO₂H)₂ in 50 cc. pyridine containing small amounts of piperidine heated 2 hrs. at 100° yielded quantitatively 3,4-MeO(HO₂CCH₂O)C₆H₃CH:CHCO₂H, m. 234° (also formed in 73% yield from ferulic acid, CH₂ClCO₂H and NaOH); di-Me ester (XIV), m. 104-5°. Veratraldehyde, (3 g.), 5 g. XIV, 0.41 g. Na powder, 20 cc. Et₂O, and several drops absolute MeOH, heated several hrs. and acidified with aqueous AcOH, gave 2 g. Me α-[2-methoxy-4-(β-carbomethoxyvinyl)phenoxy]-3,4-dimethoxycinnamate, b_0.01 260°, m. 129°. XIV and X refluxed with Na in Et₂O gave, after acidification and fractionation of the Et₂O extract, 31% Me O-methoxymethyl-α-[2-methoxy-4-(β-carbomethoxyvinyl)phenoxy]ferulate (XV), b_0.01 275°, m. 100-1° (from MeOH). By replacing the MeOCH₂ group in XV by Ac, the O-Ac analog (XVI), C₂₄H₂₄O₉, b_0.0001 180° (bath temperature), m. 117-18°, was formed. XVI (18 g.) in Et₂O reduced by stepwise addition of LiAlH₄ at room temperature, followed by adding moist Et₂O, Na₂S₂O₄, and Dry Ice to the aqueous phase, and fractionation in high vacuum of the Et₂O extract, gave about 100 mg. resinous. 3,4-MeO[3,4-MeO(HO)C₆H₃CH:C(CH₂OH)O] C₆H₃CH:CHCH₂OH (XVII). The tetrahydro derivative of XVI, sirup, b_0.001 160° (bath temperature); the tetrahydro derivative of XVII, colorless sirup, b_0.001 150° (bath temperature). Inasmuch as both acetone-lignin and the dehydrogenation polymers of coniferyl alc. yielded 1.5-2% HCHO when distilled with H₂SO₄, a similar treatment was applied to a number of the synthetic compounds listed above. None of these gave more than faint traces of HCHO, with the single exception of PhCH(OH)CH(OPh)CH₂OH, which yielded 1.3% HCHO. From this and previous studies (C.A. 42, 882a). F. and M. have indicated what types of structure, in O-containing derivatives of PhPr, are capable of giving rise to HCHO. 19 references.

Annalen der Chemie, Justus Liebigs published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Application In Synthesis of 70110-65-5.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Li, Tengfei published the artcilePhotoelectrochemical Decomposition of Lignin Model Compound on a BiVO₄ Photoanode, Formula: C15H16O3, the publication is ChemSusChem (2020), 13(14), 3622-3626, database is CAplus and MEDLINE.

The photoelectrochem. decomposition of lignin model compounds at a BiVO₄ photoanode is demonstrated with simulated sunlight and an applied bias of 2.0 V. These prototypical lignin model compounds are photoelectrochem. converted into the corresponding aryl aldehyde and phenol derivatives in a single step with conversion of up to ≈64% over 20 h. Control experiments suggest that vanadium sites are electrocatalytically active, which precludes the need for a redox mediator in solution This feature of the system is corroborated by a layer of V₂O₅ deposited on BiVO₄ serving to boost the conversion by 10%. Our methodol. capitalizes on the reactive power of sunlight to drive reactions that have only been studied previously by electrochem. or catalytic methods. The use of a BiVO₄ photoanode to drive lignin model decomposition therefore provides a new platform to extract valuable aromatic chem. feedstocks using solar energy, electricity and biomass as the only inputs.

ChemSusChem published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Formula: C15H16O3.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Zhou, Xiaoyuan published the artcileLignol Cleavage by Pd/C Under Mild Conditions and Without Hydrogen: A Role for Benzylic CH Activation?, COA of Formula: C15H16O3, the publication is ChemSusChem (2014), 7(6), 1623-1626, database is CAplus and MEDLINE.

The cleavage of CO bonds in lignin model compounds without hydrogen was developed using the com. available Pd/C. Hydrogen donor solvents are helpful for this reaction through transfer hydrogenation, but not necessary. A redox neutral process that utilizes the internal hydrogen source for the cleavage is also possible. An initial mechanistic study indicates that the β-benzylic-H atom in the substrate plays a critical role and that the present system undergoes a process different from previous reports.

ChemSusChem published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C24H20Ge, COA of Formula: C15H16O3.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Cui, Tingting published the artcileAtomically Dispersed Pt-N₃C₁ Sites Enabling Efficient and Selective Electrocatalytic C-C Bond Cleavage in Lignin Models under Ambient Conditions, Product Details of C15H16O3, the publication is Journal of the American Chemical Society (2021), 143(25), 9429-9439, database is CAplus and MEDLINE.

Selective cleavage of C-C linkages is the key and a challenge for lignin degradation to harvest value-added aromatic compounds To this end, electrocatalytic oxidation presents a promising technique by virtue of mild reaction conditions and strong sustainability. However, the existing electrocatalysts (traditional bulk metal and metal oxides) for C-C bond oxidative cleavage suffer from poor selectivity and low product yields. We show for the first time that atomically dispersed Pt-N₃C₁ sites planted on nitrogen-doped carbon nanotubes (Pt₁/N-CNTs), constructed via a stepwise polymerization-carbonization-electrostatic adsorption strategy, are highly active and selective toward C_α-C_β bond cleavage in β-O-4 model compounds under ambient conditions. Pt₁/N-CNTs exhibits 99% substrate conversion with 81% yield of benzaldehyde, which is exceptional and unprecedented compared with previously reported electrocatalysts. Moreover, Pt₁/N-CNTs using only 0.41 weight % Pt achieved a much higher benzaldehyde yield than those of the state-of-the-art bulk Pt electrode (100 weight % Pt) and com. Pt/C catalyst (20 weight % Pt). Systematic exptl. investigation together with d. functional theory (DFT) calculation suggests that the superior performance of Pt₁/N-CNTs arises from the atomically dispersed Pt-N₃C₁ sites facilitating the formation of a key C_β radical intermediate, further inducing a radical/radical cross-coupling path to break the C_α-C_β bond. This work opens up opportunities in lignin valorization via a green and sustainable electrochem. route with ultralow noble metal usage.

Journal of the American Chemical Society published new progress about 70110-65-5. 70110-65-5 belongs to alcohols-buliding-blocks, auxiliary class Benzene,Alcohol,Ether,Benzene Compounds, name is 2-Phenoxy-1-phenylpropane-1,3-diol, and the molecular formula is C15H16O3, Product Details of C15H16O3.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts