Category: 63012-03-3

The author of 《Grignard Reactions in Cyclopentyl Methyl Ether》 were Kobayashi, Shoji; Shibukawa, Keisuke; Miyaguchi, Yuta; Masuyama, Araki. And the article was published in Asian Journal of Organic Chemistry in 2016. Computed Properties of C13H11ClO The author mentioned the following in the article:

A systematic study of Grignard reactions using cyclopentyl Me ether (CPME) as a reaction solvent was studied. Diisobutylaluminum hydride was found to be the most appropriate activator of magnesium and a number of Grignard reagents could be prepared as homogeneous or heterogeneous solutions in CPME. The CPME used in the Grignard reaction was efficiently recycled without affecting the reaction yield of the second experiment GC-MS anal. of the recovered solvent revealed that CPME was stable under the Grignard conditions. Some of the Grignard reagents in CPME were stable for at least several months and therefore these solutions could replace existing com. reagents. Tramadol hydrochloride, an analgesic that is used worldwide, and tamoxifen, an anti-estrogenic drug for estrogen-receptor-pos. breast cancer were synthesized using Grignard reactions in CPME. In the experiment, the researchers used many compounds, for example, (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Computed Properties of C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Computed Properties of C13H11ClO

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Wang, Jiao; Fan, Xiuju; Feng, Xiao; Li, Yueming published an article on February 28 ,1993. The article was titled 《Studies on enantioselective effect of chiral titanate reagents on the synthesis of substituted benzhydrols》, and you may find the article in Chemical Research in Chinese Universities.Recommanded Product: 63012-03-3 The information in the text is summarized as follows:

Chiral titanate reagents were prepared for use in the asym. synthesis of substituted benzhydrols from Grignard reagents and aldehydes. The solvents, reaction temperature, and exchange of reactants by crossing experiments were investigated. Favored attack of the nucleophile upon the prochiral face of the aromatic aldehyde is proposed, the absolute configurations of the resulting benzhydrols are suggested, and a preliminary reaction mechanism is described. Thus, PhMgBr reacted with 3-ClC6H4CHO in Et2O in the presence of the (+)-tartarate-titanate I to give (-)-(R)-PhCH(OH)C6H4Cl-3 in 34% enantiomeric excess, in contrast, similar reaction of 3-ClC6H4MgBr with PhCHO in the presence of (+)-I gave (+)-(S)-PhCH(OH)C6H4Cl-3 in 73% enantiomeric excess. In addition to this study using (3-Chlorophenyl)(phenyl)methanol, there are many other studies that have used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Recommanded Product: 63012-03-3) was used in this study.

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Recommanded Product: 63012-03-3 Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

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《Zinc triflate catalyzed synthesis of thioethers》 was written by Baddam, Sudhakar Reddy; Neelam, Uday Kumar; Manne, Naga Raju; Adulla, Panasa Reddy; Bandichhor, Rakeshwar. Related Products of 63012-03-3 And the article was included in Chemistry & Biology Interface on April 30 ,2014. The article conveys some information:

Zinc triflate-catalyzed aralkylation of thiols using various substituted benzylic alcs. was developed for the synthesis of thioether (sulfide) derivatives This procedure presents a greener approach for the synthesis of sulfides. The experimental process involved the reaction of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Related Products of 63012-03-3)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.Related Products of 63012-03-3

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《Efficient Thiolation of Alcohols Catalyzed by Long Chained Acid-Functionalized Ionic Liquids under Mild Conditions》 was published in European Journal of Organic Chemistry in 2019. These research results belong to Miao, Chengxia; Zhuang, Hongfeng; Wen, Yating; Han, Feng; Yang, Qing-Feng; Yang, Lei; Li, Zhen; Xia, Chungu. Recommanded Product: 63012-03-3 The article mentions the following:

Thioethers as important building blocks have been usually found in organic synthesis. Herein, a series of long chained acid-functionalized ionic liquids derived from pyrrolidine were applied for the thiolation of alcs. to synthesize different compounds containing thioether structures. This kind of ionic liquids exhibited higher efficiency than general ionic liquids based on imidazole, providing up to 99 % yield with [BsCtP][OTf] as the catalyst at room temperature for 0.25 h. The results indicated that the activities of the ionic liquids have relationship with the side chain length of ionic liquids based on pyrrolidine, anions and cations. The catalytic system had wide substrate scope and was applicable for the reaction of aromatic primary and secondary alcs. and thiols including aliphatic and aromatic thiols, benzothiazole-2-thiols and benzooxazole-2-thiols. Besides, there was no obvious change in activity of the catalyst after six runs. Thus, the catalytic system exhibited good recyclability. Addnl., carbocations should be the key intermediate and several functionalized groups of the ionic liquids have synergetic effect for the thiolation. In the experiment, the researchers used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Recommanded Product: 63012-03-3)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.Recommanded Product: 63012-03-3

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《Promoter free allylation of trichloroacetimidates with allyltributylstannanes under thermal conditions to access the common 1,1′-diarylbutyl pharmacophore》 was published in Organic & Biomolecular Chemistry in 2018. These research results belong to Mahajani, Nivedita S.; Chisholm, John D.. COA of Formula: C13H11ClO The article mentions the following:

4,4-Diaryl-1-butenes such as Ph2CHCH2CH:CH2 and selected 4-aryl-1-butenes were prepared by allylation of diarylmethyl and electron-rich benzylic trichloroacetimidates such as Ph2CHOC(:NH)CCl3 with allyltributylstannane and allylic stannanes in MeNO2 without the addition of other promoters or catalysts. In the experimental materials used by the author, we found (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3COA of Formula: C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.COA of Formula: C13H11ClO

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《Sol-gel derived LaFeO3/SiO2 nanocomposite: synthesis, characterization and its application as a new, green and recoverable heterogeneous catalyst for the efficient acetylation of amines, alcohols and phenols》 was written by Farhadi, Saeed; Jahanara, Kosar; Sepahdar, Asma. Application of 63012-03-3 And the article was included in Journal of the Iranian Chemical Society on August 31 ,2014. The article conveys some information:

LaFeO3/SiO2 nanocomposite was synthesized by the sol-gel process from metal nitrates and tetra-Et orthosilicate (TEOS) as the SiO2 source. The nanocomposite product was characterized by XRD, FT-IR, SEM, and surface area measurements and was used as a heterogeneous catalyst for the efficient acetylation of amines, alcs., and phenols to the corresponding acetates using acetic anhydride under solvent-free conditions. Among the various substrates, acetylation of amines was preceded rapidly, so that an amine group could be selectively acetylated in the presence of alc. or phenolic hydroxyl groups by the appropriate choice of reaction time. The catalyst can also be reused several times without the loss of activity. In addition, the catalytic activity of the LaFeO3/SiO2 nanocomposite was higher than that of the pure LaFeO3 nanoparticles. The method is high yielding, clean, cost effective, compatible with the substrates having other functional groups and very suitable for the practical organic synthesis.(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Application of 63012-03-3) was used in this study.

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group.Application of 63012-03-3 Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Hirano, Masao; Kuroda, Hisanori; Morimoto, Takashi published their research in Bulletin of the Chemical Society of Japan on August 15 ,1990. The article was titled 《Oxidation of aromatic alcohols with chromium(VI) trioxide in the presence of wet-aluminum oxide in aprotic solvent》.Computed Properties of C13H11ClO The article contains the following contents:

The title oxidation resulted in a selective formation of the corresponding carbonyl compounds in excellent yields under mild conditions. The experimental process involved the reaction of (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Computed Properties of C13H11ClO)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy-containing compounds engage in intermolecular hydrogen bonding increasing the electrostatic attraction between molecules and thus to higher boiling and melting points than found for compounds that lack this functional group. Organic compounds, which are often poorly soluble in water, become water-soluble when they contain two or more hydroxy groups, as illustrated by sugars and amino acid.Computed Properties of C13H11ClO

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Alcohol – Wikipedia,
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Hirano, Masao; Morimoto, Takashi published their research in Bulletin of the Chemical Society of Japan on December 31 ,1989. The article was titled 《Oxidation of aromatic secondary alcohols with cobalt(III) acetate in the presence of sodium bromide》.Product Details of 63012-03-3 The article contains the following contents:

Oxidation of aromatic secondary alcs., RC6H4CH(OH)R1 (e.g., R = H, 2-, 3-, 4-Me, 2-, 3-, 4-Br, 2-, 3-, 4-Cl; R1 = Me, Ph) with Co(OAc)3 in presence of NaBr in AcOH gave ketones RC6H4COR1 in 83-97% yields. After reading the article, we found that the author used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Product Details of 63012-03-3)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The creation of a peptide bond to link two amino acids to make a protein removes the −OH from the carboxy group of one amino acid.Product Details of 63012-03-3

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Alcohol – Wikipedia,
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In 1994,Bulletin de la Societe Chimique de France included an article by Berkous, Rabia; Dupas, Georges; Bourguignon, Jean; Queguiner, Guy. Recommanded Product: (3-Chlorophenyl)(phenyl)methanol. The article was titled 《Behavior and extension of the scope of NADH models to the reduction of non-activated ketones by a stable indolo NADH model compound in the presence of Lewis acids》. The information in the text is summarized as follows:

The reduction of non-activated ketones, e.g., acetophenone, by a very stable NADH model in the presence of Lewis acids (AlX3, Et2AlCl) is reported. During the reaction, a side equilibrated aldol condensation occurs. Due to the reversibility of this reaction, the overall yield in alc. is not notably diminished. The scope of NADH models has been extended for the first time to non-activated ketones, such as dialkyl, aryl alkyl and diaryl ketones. In the experimental materials used by the author, we found (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Recommanded Product: (3-Chlorophenyl)(phenyl)methanol)

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains. The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.Recommanded Product: (3-Chlorophenyl)(phenyl)methanol

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Alcohol – Wikipedia,
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The author of 《Synthesis, antibacterial and antifungal activities of bifonazole derivatives》 were El Hage, Salome; Lajoie, Barbora; Feuillolay, Catherine; Roques, Christine; Baziard, Genevieve. And the article was published in Archiv der Pharmazie (Weinheim, Germany) in 2011. Product Details of 63012-03-3 The author mentioned the following in the article:

Two series of chlorinated benzhydryl imidazole and triazole derivatives were synthesized and tested in vitro against representative strains of potent pathogenic bacteria (Staphylococcus aureus CIP 4.83, Enterococcus hirae CIP 5855, Pseudomonas aeruginosa CIP 82118, Escherichia coli CIP 53126) and fungi (Aspergillus niger IP 1431.83, Candida albicans IP 48.72, Candida krusei IP 208.52, Trichophyton rubrum IP 1657.86). Most of these compounds were devoid of any antimicrobial activity, but several of them inhibited T. rubrum with MIC values in the range 0.125-32 μg/mL, similar or superior to those of bifonazole and clotrimazole, used as standard controls. The replacement of the imidazole ring by a triazole moiety in these compounds led to derivatives with less antifungal activity. A preliminary SAR was undertaken on the effect of the number and the position of chlorine atoms on the distribution of neg. charge on the surface of some compounds on antifungal activity. In addition to this study using (3-Chlorophenyl)(phenyl)methanol, there are many other studies that have used (3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3Product Details of 63012-03-3) was used in this study.

(3-Chlorophenyl)(phenyl)methanol(cas: 63012-03-3) belongs to hydroxy-containing compounds. Hydroxy groups participate in the dehydration reactions that link simple biological molecules into long chains.Product Details of 63012-03-3 The joining of a fatty acid to glycerol to form a triacylglycerol removes the −OH from the carboxy end of the fatty acid.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts