Wang, Xin; Guo, Zhi; Da, Xiang; Xie, Xingyi published an article in 2022. The article was titled 《Antimicrobial polyurethane foams blown by CO2 adducts from polyethylenimines grafted with alkyl quaternary ammonium groups》, and you may find the article in Journal of Applied Polymer Science.Quality Control of 3-Bromopropan-1-ol The information in the text is summarized as follows:
Based on previous endeavors on antimicrobial polyurethane (PU) foams and CO2-releasing environment-friendly blowing agents, we explored a series of modified polyethylenimine (PEI)-CO2 adducts, serving as both blowing and antimicrobial agents for PUs. For this purpose, a quaternary ammonium chain with a C12 alkyl (C12+), either alone or together with neutral (C8 and C12) alkyls, was grafted onto branched PEI (Mn = 25,000 Da) backbones prior to saturation with CO2. The resultant four CO2 adducts, 5C12+5C8-, 5C12+5C12-, 10C12+- and 15C12+-PEI-CO2 (where the number indicates grafting rate in percentage of each side chain), all can well disperse into PU foaming mixtures, generating flexible PU foams with antimicrobial activity. 15C12+-PEI-CO2 displays the best dispersibility and highest foaming efficiency, while 10C12+-PEI-CO2 is the most antimicrobial toward both Gram pos. and neg. bacteria. The relatively high grafting rate in 15C12+-PEI-CO2 drives the formation of micelle-like particles in the foaming system; the outermost hydrophobic chains can somewhat prevent the internal quaternary ammoniums from accessing to the neg. charged cell membrane of bacteria, causing a reduction in antimicrobial efficacy compared with that of 10C12+-PEI-CO2. The developed PEI-CO2 adducts might replace the traditional ozone depletion and/or global warming blowing agents, and would show prolonged antimicrobial activity over rapidly leachable small mol. antimicrobial agents. In the experiment, the researchers used 3-Bromopropan-1-ol(cas: 627-18-9Quality Control of 3-Bromopropan-1-ol)
3-Bromopropan-1-ol(cas: 627-18-9) was used in the synthesis of fluorescent halide-sensitive quinolinium dyes and molten salt-polymers. Furthermore, it was used in the synthesis of chiral, quaternary prolines via cyclization of quaternary amino acids.Quality Control of 3-Bromopropan-1-ol
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