Category: 60462-27-3

Cyclooctatetraenes through Valence Isomerization of Cubanes: Scope and Limitations was written by Houston, Sevan D.; Xing, Hui; Bernhardt, Paul V.; Vanden Berg, Timothy J.; Tsanaktsidis, John; Savage, G. Paul; Williams, Craig M.. And the article was included in Chemistry – A European Journal in 2019.COA of Formula: C10H12O2 The following contents are mentioned in the article:

The scope and limitations of Eaton’s rhodium(I)-catalyzed valence isomerization of cubane to cyclooctatetraene (COT) were studied in the context of functional group tolerability, multiple substitution modes and the ability of cubane-alcs. to undergo one-pot tandem Ley-Griffith Wittig reactions in the absence of a transition metal catalyst. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3COA of Formula: C10H12O2).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.COA of Formula: C10H12O2

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Proton magnetic resonance spectra of cubane derivatives. I. Syntheses and spectra of mono- and 1,4-disubstituted cubanes was written by Edward, John T.; Farrell, Patrick G.; Langford, Gordon E.. And the article was included in Journal of the American Chemical Society in 1976.Name: Cubane-1,4-diyldimethanol The following contents are mentioned in the article:

The syntheses of a number of monosubstituted and 1,4-disubstituted cubanes are described, together with the measurement and anal. of their 100-MHz 1H NMR spectra. A simple additivity rule is described whereby chem. shifts in CDCl3 can be predicted to within ±0.02 ppm. Both chem. shifts and coupling constants are shown to vary with substituent electronegativity. The derived correlations allow quick and effective identification of cubane derivatives from their 1H NMR spectra, and also aid in the interpretation of the more complex spectra of less sym. cage mols. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Name: Cubane-1,4-diyldimethanol).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Name: Cubane-1,4-diyldimethanol

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Proton magnetic resonance spectra of cubane derivatives. II. Aromatic solvent-induced shifts was written by Edward, John T.; Farrell, Patrick G.; Langford, Gordon E.. And the article was included in Journal of the American Chemical Society in 1976.Application of 60462-27-3 The following contents are mentioned in the article:

Aromatic solvent-induced shifts (ASIS) were measured for a number of substituted cubanes in benzene and pyridine and an additivity rule was derived which allows accurate prediction of these shifts. Protons remote from the substituent show the largest ASIS and these are shown to correlate with substituent electronegativity. Models are discussed for the nature and stereochem. of the solute-solvent interaction. The observed additive shifts arise from independent, transient 1:1 associations of solvent mols. with the electron-deficient sites of all local dipoles in the solute. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Application of 60462-27-3).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Application of 60462-27-3

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Ring enlargement reactions of homocubyl-4- and cubyl-1,4-dicarbinols was written by Higuchi, Hiroyuki. And the article was included in Advances in Strained and Interesting Organic Molecules in 1999.Computed Properties of C10H12O2 The following contents are mentioned in the article:

A review. Carbinols of cubane and homocubane derivatives were prepared by Grignard reactions in good yields. These carbinols underwent smooth C-C bond cleavage under Wagner-Meerwein conditions to give mixtures of ring enlargement products along with unexpected products, in various ratios depending on the reaction conditions. 1,4-Bishomocubane, previously believed to be much less stable than 1,3-bishomocubane both exptl. and theor., was obtained as one of major products from the electronically modified homocubyl-and cubyldicarbinols. It is indicated that the ring enlargement reactions of the present carbinols proceeds along the reaction paths in a borderline area between kinetically and thermodynamically controlled pathways. A review with 34 references This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Computed Properties of C10H12O2).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Computed Properties of C10H12O2

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Efficient preparation of apically substituted diamondoid derivatives was written by Kahl, Paul; Tkachenko, Boryslav A.; Novikovsky, Anatoliy A.; Becker, Jonathan; Dahl, Jeremy E. P.; Carlson, Robert M. K.; Fokin, Andrey A.; Schreiner, Peter R.. And the article was included in Synthesis in 2014.HPLC of Formula: 60462-27-3 The following contents are mentioned in the article:

The authors present an effective three-step chromatog.-free sequence for the preparation of apical monohydroxy derivatives of diamantane, triamantane and [121]tetramantane from the corresponding bis-apical diols utilizing tert-butyldimethylsilyl chloride as the silylation agent. The procedure was successfully applied to the protection of several other aliphatic and aromatic diols. Addnl., 9-amino-4-diamantanecarboxylic acid, which has significant potential in medicinal and material sciences, was prepared by a Ritter reaction of 4,9-dihydroxydiamantane in trifluoroacetic acid. The synthesis of the target compounds was achieved using octahydro-3,5,1,7-[1,2,3,4]butanetetraylnaphthalene-3,7-diol (4,9-diamantanediol), decahydro-4,5,12-metheno-2,9,7-[1,2,3]propanetriylanthracene-2,7(1H,3H)-diol (9,15-triamantanediol) and tetradecahydro-1,5,7,11-ethanediylidene-3,5:9,11-dimethanochrysene-3,9-diol (6,13-tetramantanediol) as starting materials. The tilte compounds thus formed included octahydro-3,5,1,7-[1,2,3,4]butanetetraylnaphthalen-3(2H)-ol, dodecahydro-4,5,12-metheno-2,9,7-[1,2,3]propanetriylanthracen-2(1H)-ol, tetradecahydro-1,5,7,11-ethanediylidene-3,5:9,11-dimethanochrysen-3(4H)-ol. Other diols included bicyclo[2.2.2]octane-1,4-diol, Pentacyclo[4.2.0.02,5.03,8.04,7]octane-1,4-dimethanol (cubane derivative), 1,10-decanediol, 1,8-octanediol, 1,4-benzenediol, 2,6-naphthalenediol, [1,1′-binaphthalene]-2,2′-diol. 7-(Amino)octahydro-3,5,1,7-[1,2,3,4]butanetetraylnaphthalene-3(2H)-carboxylic acid [i.e., (amino)diamantanecarboxylic acid] was prepared This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3HPLC of Formula: 60462-27-3).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.HPLC of Formula: 60462-27-3

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Polynorbornene-Based Double-Stranded Ladderphanes with Cubane, Cuneane, Tricyclooctadiene, and Cyclooctatetraene Linkers was written by Yeh, Nai-Hua; Chen, Chih-Wei; Lee, Shern-Long; Wu, Hung-Jen; Chen, Chun-hsien; Luh, Tien-Yau. And the article was included in Macromolecules (Washington, DC, United States) on March 27,2012.Recommanded Product: Cubane-1,4-diyldimethanol The following contents are mentioned in the article:

Double-stranded ladderphanes 2, 3, and 5 having cubane, cuneane, and cyclooctatetraene linkers are synthesized by ring-opening metathesis polymerization (ROMP) of the corresponding bisnorbornene monomers 10, 11, and 13, resp. Attempts to polymerize the corresponding tricyclooctadiene-linked bisnorbornene 12 are not successful, starting monomer being recovered. Polymer with this tricyclic diene linker 4 is obtained from the rhodium-catalyzed isomerization of 2. The scanning tunneling microscopic (STM) image of 2 shows an ordered pattern on the graphite surface by self-assembly. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Recommanded Product: Cubane-1,4-diyldimethanol).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Recommanded Product: Cubane-1,4-diyldimethanol

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Cubane derivatives 10. Synthesis and molecular structures of nitroxymethylcubanes was written by Romanova, L. B.; Barinova, L. S.; Zakharov, V. V.; Eremenko, L. T.; Aleksandrov, G. G.; Eremenko, I. L.. And the article was included in Russian Chemical Bulletin on May 31,2010.Recommanded Product: Cubane-1,4-diyldimethanol The following contents are mentioned in the article:

The reactions of hydroxymethylcubanes with nitric acid result in the resp. nitroxymethylcubanes. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Recommanded Product: Cubane-1,4-diyldimethanol).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Recommanded Product: Cubane-1,4-diyldimethanol

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

Cubane Arrives on the Cucurbituril Scene was written by Jelinkova, Kristyna; Surmova, Heda; Matelova, Alena; Rouchal, Michal; Pruckova, Zdenka; Dastychova, Lenka; Necas, Marek; Vicha, Robert. And the article was included in Organic Letters on May 19,2017.Quality Control of Cubane-1,4-diyldimethanol The following contents are mentioned in the article:

Cubane, an intriguing chem. curiosity first studied in the early 1960s, has become a valuable structural motif and has recently been involved in the structures of a great number of prospective compounds The first dicationic supramol. guest 5 is prepared and derived from a 1,4-disubstituted cubane moiety, and its binding behavior toward cucurbit[n]urils (CBn) and cyclodextrins (CD) is studied. The bisimidazolium salt 5 forms 1:1 inclusion complexes with CB7, CB8, and β-CD with the resp. association constants (6.7 ± 0.5) × 1011 M-1, (1.5 ± 0.2) × 109 M-1, and <102 M-1 in water. The solid-state structures of the 5@CB7 and 5@CB8 complexes are also reported. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Quality Control of Cubane-1,4-diyldimethanol).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Quality Control of Cubane-1,4-diyldimethanol

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

New method for preparation of aluminum hydride solutions was written by Zakharov, V. V.; Bugaeva, G. P.; Naumenko, I. G.; Nechiporenko, G. N.; Petinov, V. I.. And the article was included in Zhurnal Prikladnoi Khimii (Sankt-Peterburg) on June 30,1999.SDS of cas: 60462-27-3 The following contents are mentioned in the article:

Stable solutions of AlH3 were obtained by precipitation of AlH3 (synthesized from Al and H2) from an ether or amine solvent onto a surface cooled by liquid N2, thawing, and separating the AlH3 solution from Al and other solid products. The AlH3 prepared in this way reduced 1,4-cubanedicarboxylic acid to 1,4-cubanedimethanol in 85% yield. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3SDS of cas: 60462-27-3).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.SDS of cas: 60462-27-3

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3

3.* Synthesis and molecular structure of 1,4-bis(hydroxymethyl)cubane was written by Zakharov, V. V.; Bugaeva, G. P.; Ivanova, M. E.; Romanova, L. B.; Eremenko, L. T.; Nefedov, S. E.; Eremenko, I. L.. And the article was included in Russian Chemical Bulletin (Translation of Izvestiya Akademii Nauk, Seriya Khimicheskaya) on July 31,1998.Related Products of 60462-27-3 The following contents are mentioned in the article:

An efficient procedure for the preparation of 1,4-bis(hydroxymethyl)cubane by reduction of 1,4-cubanedicarboxylic acid or its di-Me ester with aluminum hydride was developed. The mol. structure of 1,4-bis(hydroxymethyl)cubane was established by X-ray diffraction anal. This study involved multiple reactions and reactants, such as Cubane-1,4-diyldimethanol (cas: 60462-27-3Related Products of 60462-27-3).

Cubane-1,4-diyldimethanol (cas: 60462-27-3) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Related Products of 60462-27-3

60462-27-3;Cubane-1,4-diyldimethanol;The future of 60462-27-3;New trend of C10H12O2;function of 60462-27-3