Category: 599-64-4

Wang, Qiao;Xu, Zetao;Cao, Yiting;Chen, Yuanqing;Du, Xing;Yang, Yang;Wang, Zhihong published 《Two-dimensional ultrathin perforated Co₃O₄ nanosheets enhanced PMS-Activated selective oxidation of organic micropollutants in environmental remediation》. The research results were published in《Chemical Engineering Journal (Amsterdam, Netherlands)》 in 2022.Computed Properties of C15H16O The article conveys some information:

Here a two-dimensional (2D) ultrathin perforated Co₃O₄ nanosheet is rationally designed by a wet-chem. synthesis to activate peroxymonosulfate (PMS) for efficient selective oxidation And the physicochem. properties of catalyst were investigated by series of techniques. The Co₃O₄ nanosheets achieved a 98.0% degradation efficiency of bisphenol A (BPA) within 30 min, showing a 4 times higher kinetic constant (0.112 min^-1) and 5 times lower Co²⁺ leakage (6.5 μg/L), than com. Co₃O₄ microspheres. The great enhancement in catalytic performance was ascribed to the large surface area and pore diameter in porous 2D structure, as well as the strong electrostatic attraction with PMS. Moreover, the influence of several parameters such as initial pH, temperatures, humic acids and inorganic anions in the system on the remaval of BPA were systematically studied. Since sulfate radicals (SO·^–₄) were proved to be the primary reactive oxygen species by EPR measurements and quenching experiments, the PMS/Co₃O₄ nanosheets exhibits a highly selective oxidation on aromatics with electron donating groups (i.e., -OH and -CH₃), while a relatively low value for organics with electron-withdrawing groups (e.g., -NO₂ and -COOH). A high ionization potential threshold was determined to be greater than 9.39 eV, corresponding to a high oxidation ability to react with the organics Finally, possible degradation pathways were proposed based on twenty intermediate products determined from mass spectrometry. The experimental procedure involved many compounds, such as 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) .

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.Computed Properties of C15H16O 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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Geng, Hui-Qing;Wu, Xiao-Feng published 《Copper-Catalyzed Alkoxycarbonylation of Alkyl Iodides for the Synthesis of Aliphatic Esters: Hydrogen Makes the Difference》 in 2021. The article was appeared in 《Organic Letters》. They have made some progress in their research.Formula: C15H16O The article mentions the following:

A copper-catalyzed alkoxycarbonylation transformation of unactivated alkyl iodides was developed. Various alkyl iodides were converted into the corresponding tert-Bu esters in good yields. NaOt-Bu acts as both a nucleophile and a base. Moreover, other types of aliphatic esters was also be obtained in moderated yields if extra alcs. are added. Both primary and secondary alkyl alcs. can react successfully.4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) were involved in the experimental procedure.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.Formula: C15H16O 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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Rank, Christian K.;Oezkaya, Buenyamin;Patureau, Frederic W. published 《HBF₄– and AgBF₄-Catalyzed ortho-Alkylation of Diarylamines and Phenols》. The research results were published in《Organic Letters》 in 2019.Application of 599-64-4 The article conveys some information:

A silver-tetrafluoroborate- or HBF₄-catalyzed ortho-alkylation reaction of phenols and diarylamines with styrenes has been explored. A broad substrate scope is presented as well as mechanistic experiments and discussion. And 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) was used in the research process.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.Application of 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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Zhu, Zhaodong;Gong, Yuxin;Tong, Weiqi;Xue, Weichao;Gong, Hegui published 《Ni-Catalyzed Cross-Electrophile Coupling of Aryl Triflates with Thiocarbonates via C-O/C-O Bond Cleavage》 in 2021. The article was appeared in 《Organic Letters》. They have made some progress in their research.COA of Formula: C15H16O The article mentions the following:

A synthesis of aryl thioesters RCOSR¹ (R = Ph, 4-MeO₂CC₆H₄, 4-BnOC₆H₄, etc.; R¹ = n-hexyl, cyclohexyl, cyclopentyl, etc.) via nickel-catalyzed reductive coupling of aryl triflates with thiocarbonates was reported. Both electron-rich and -deficient aryl C(sp²)-O electrophiles as well as a class of O-tBu S-alkyl thiocarbonates were compatible with the optimized reaction conditions as evidenced by 49 examples. The reaction also proceeded with good chemoselective cleavage of the C-O bond with regard to thioesters. This work broadened the scope of nickel-catalyzed reductive cross-electrophile coupling reactions. And 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) was used in the research process.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.COA of Formula: C15H16O 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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HPLC of Formula: 599-64-4《Effectively enhanced photodegradation of Bisphenol A by in-situ g-C₃N₄-Zn/Bi₂WO₆ heterojunctions and mechanism study》 was published in 2020. The authors were Ruan, Xian;Hu, Yongyou, and the article was included in《Chemosphere》. The author mentioned the following in the article:

In our work, a series of in-situ g-C₃N₄-Zn/Bi₂WO₆ heterojunctions were synthesized by a two-step solvothermal method followed with calcination process, using dicyanamide as the precursor for g-C₃N₄. C₃N₄-Zn/BWO heterojunctions were of gossypine shape, and both C₃N₄ and Zn were finely distributed into BWO nanosheets, forming a hierarchical structure. C₃N₄-Zn/BWO with 2.0 g of precursor addition and calcined at 520°C exhibited effectively enhanced photodegradation for typical organic contaminant BPA, degrading 93% within 120 min, and implied a maximum rate constant k of 0.0211 min^-1, indicating synergistic effect of C₃N₄ and Zn components in C₃N₄-Zn/BWO heterojunction. The enhancement of photocatalysis was due to quick carriers’ separations via Z-scheme system and enlarged sp. surface area of as-synthesized C₃N₄-Zn/BWO heterojunction. Main reactive oxidation species were detected to be h⁺ and ·O^–2, and nine intermediates were confirmed via anlysis of LC-MS/MS. This study provided an alternative strategy to design novel photocatalysts containing multicomponents for higher photocatalytic activity. The experimental procedure involved many compounds, such as 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) .

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.HPLC of Formula: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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Formula: C15H16O《Accelerated SuFEx Click Chemistry For Modular Synthesis》 was published in 2022. The authors were Smedley, Christopher J.;Homer, Joshua A.;Gialelis, Timothy L.;Barrow, Andrew S.;Koelln, Rebecca A.;Moses, John E., and the article was included in《Angewandte Chemie, International Edition》. The author mentioned the following in the article:

The development of accelerated SuFEx click chem. (ASCC), an improved SuFEx method for the efficient and catalytic coupling of aryl and alkyl alcs. with a range of SuFExable hubs was reported. Barton’s hindered guanidine base (2-tert-butyl-1,1,3,3-tetramethylguanidine; BTMG) was demonstrated as a superb SuFEx catalyst, when used in synergy with silicon additive hexamethyldisilazane (HMDS), yielded stable S-O bond linkages in a single step; often within minutes. The powerful combination of BTMG and HMDS reagents allowed for catalyst loadings as low as 1.0 mol % and in congruence with click-principles, provided a scalable method that is safe, efficient and practical for modular synthesis. ASSC expands the number of accessible SuFEx products and will find significant application in organic synthesis, medicinal chem., chem. biol., and materials science. And 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) was used in the research process.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.Formula: C15H16O 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

Reference:
Alcohol – Wikipedia,
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Liu, Xiaojie;Xu, Biping;Su, Weiping published 《Ni-Catalyzed Deoxygenative Borylation of Phenols Via O-Phenyl-uronium Activation》. The research results were published in《ACS Catalysis》 in 2022.HPLC of Formula: 599-64-4 The article conveys some information:

Herein, we report an efficient method for the Ni-catalyzed deoxygenative borylation of unprotected phenols and also demonstrate that this Ni-catalyzed phenolic C(sp²)-O transformation is applicable to the Suzuki-Miyaura-type and Heck-type cross-couplings of phenols. Investigations on the reaction intermediate have revealed that the achievement of general, mild deoxygenative cross-coupling reactions of phenols is ascribed to the conversion of phenols into the unusual O-phenyl-uroniums that feature active phenolic C(sp²)-O bonds. The Ni-complex intermediate resulting from an oxidative addition of a phenolic C(sp²)-O bond to monophosphine-supported Ni(0) catalyst was characterized and confirmed to be (PCy₃)₂Ni(Ar)(F) complex, offering exptl. evidence for the generally proposed C(sp²)-O oxidative addition step.4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) were involved in the experimental procedure.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.HPLC of Formula: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

Reference:
Alcohol – Wikipedia,
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HPLC of Formula: 599-64-4In 2021, Shi, Junbin;Wang, Yubin;Bu, Qingqing;Liu, Binyuan;Dai, Bin;Liu, Ning published 《Cr-Catalyzed Direct ortho-Aminomethylation of Phenols》. 《Journal of Organic Chemistry》published the findings. The article contains the following contents:

A Cr-catalyzed strategy for the regioselective formation of Csp²-Csp³ bonds through the direct and efficient ortho-aminomethylation of N,N-dimethylanilines with phenols is reported. The approach showed excellent site selectivity at the ortho-position of phenols and accommodated broad substrate scope and functional group compatibility for both N,N-dimethylanilines and phenols. Mechanistic studies revealed that the direct ortho-aminomethylation between N,N-dimethylanilines and phenols occurred via an ionic mechanism. To complete the study, the researchers used 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) .

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.HPLC of Formula: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

Reference:
Alcohol – Wikipedia,
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Wang, Xuan;Yu, Liangmin;Liu, Yujing;Jiang, Xiaohui published 《Synthesis and fouling resistance of capsaicin derivatives containing amide groups》 in 2020. The article was appeared in 《Science of the Total Environment》. They have made some progress in their research.SDS of cas: 599-64-4 The article mentions the following:

Capsaicin, which inhibits the attachment and growth of fouling organisms, is a bioactive substance that is generally recognized as a highly active environmental algaecide agent. Its derivatives are simple in structure and have been proven to have low toxicity and be environmentally friendly. Six capsaicin derivatives were synthesized via Friedel-Crafts alkylation and characterized using m.p. (MP) anal., IR spectroscopy, NMR (¹H NMR) spectroscopy and high-resolution mass spectrometry (HRMS). The inhibition effect and toxicity of these compounds towards Phaeodactylum tricornutum (P. tricornutum), Skeletonema costatum (S. costatum) and Chaetoceros curvisetus (C. curvisetus) were tested. The capsaicin derivatives all showed inhibitory effects. In particular, compound E with over 95% (3 mg·L^-1) inhibition and intermediate toxicity was superior to the other compounds, reflecting an environmentally friendly effect. This finding indicates that capsaicin derivatives possess the potential to become environmentally friendly algaecide agents. The fouling resistance of capsaicin derivatives incorporated into the coatings as antifouling agents was measured in the marine environment. The results showed that capsaicin derivatives possess excellent fouling resistance, with only a small amount of algae and muck attached to the tested panel at 90 days. The above results provide a scientific basis for the application of capsaicin derivatives as environmentally friendly antifouling agents. To complete the study, the researchers used 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) .

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.SDS of cas: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

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Alcohol – Wikipedia,
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SDS of cas: 599-64-4《In Vitro Screening of 21 Bisphenol A Replacement Alternatives: Compared with Bisphenol A, the Majority of Alternatives Are More Cytotoxic and Dysregulate More Genes in Avian Hepatocytes》 was published in 2021. The authors were Crump, Doug;Sharin, Tasnia;Chiu, Suzanne;O’Brien, Jason M., and the article was included in《Environmental Toxicology and Chemistry》. The author mentioned the following in the article:

An avian in vitro screening approach was used to determine the effects of 21 bisphenol A (BPA) alternatives. Cytotoxicity and dysregulation of genes associated with estrogen response and other toxicol. relevant pathways evoked by these alternatives were compared with BPA. Most of the BPA alternatives (15/21) were equally or more cytotoxic than BPA in chicken embryonic hepatocytes; variability in cell viability was associated with chem. structure and the log octanol-water partition coefficient (logP) values. A neg. linear relationship (r2 = 0.745; p = 0.49-07; n = 18) was observed between logP and the log median lethal concentration (logLC50) values. The least cytotoxic BPA alternatives elicited the greatest gene dysregulation and, overall, most of the alternatives altered more genes than BPA (measured with a custom polymerase chain reaction array). This overall approach shows promise for use as a screen for hazard-based prioritization of BPA replacement alternatives and to ideally identify those that may be less harmful and/or require addnl. toxicity testing.4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) were involved in the experimental procedure.

4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.SDS of cas: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts