Category: 597-52-4

Kikukawa, Yuji published the artcileA discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands, SDS of cas: 597-52-4, the publication is Chemical Communications (Cambridge, United Kingdom) (2013), 49(4), 376-378, database is CAplus and MEDLINE.

By the reaction of TBA₄H₄[γ-SiW₁₀O₃₆] (TBA = Bu₄N) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag₆]⁴⁺ cluster, TBA₈[Ag₆(γ-H₂SiW₁₀O₃₆)₂]·5H₂O (1), could be synthesized, and the mol. structure was determined 1 Could act as an efficient (pre)catalyst for the hydrolytic oxidation of structurally diverse silanes including aromatic, double bond-containing, and aliphatic ones which could be converted into the corresponding silanols in excellent yields.

Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Wang, Jing published the artcileMetal-free visible-light-mediated aerobic oxidation of silanes to silanols, Product Details of C6H16OSi, the publication is Science China: Chemistry (2018), 61(12), 1594-1599, database is CAplus.

Herein, the first metal-free visible-light-mediated aerobic oxidation of silanes to silanols using 2 mol% Rose Bengal as the catalyst, air (O₂) as the oxidant and water as the additive is reported. While this method produces various silanols in a simple, cost-effective, efficient (92%-99% yields) and scalable fashion, its reaction mechanism is very different than the reported ones associated with metal catalysis.

Science China: Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C9H8ClNO3S, Product Details of C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Ma, Lina published the artcileGold nanoparticles supported on the periodic mesoporous organosilica SBA-15 as an efficient and reusable catalyst for selective oxidation of silanes to silanols, Formula: C6H16OSi, the publication is RSC Advances (2014), 4(13), 6807-6810, database is CAplus.

Gold nanoparticles are confined and stabilized within the channels of SBA-15 through the poly(ionic liquid) brushes that are anchored onto the pore walls of SBA-15. The supported gold catalyst exhibited remarkably high catalytic activities for selective oxidation of silanes into silanols using water as an oxidant without the use of organic solvents.

RSC Advances published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Formula: C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Trzmiel, Simon P. O. published the artcileChromous siloxides of variable nuclearity and magnetism, COA of Formula: C6H16OSi, the publication is Dalton Transactions (2022), 51(13), 5072-5081, database is CAplus and MEDLINE.

Treatment of Cr[N(SiMe₃)₂]₂(THF)₂ with HOSiR₃ (R = Et, iPr) in THF afforded the bridged Cr^II siloxide complexes Cr₃(OSiEt₃)₂(μ-OSiEt₃)₄(THF)₂ and Cr₂(OSiiPr₃)₂(μ-OSiiPr₃)₂(THF)₂ in high yield. Exposure of these compounds to vacuum in aliphatic solvents led to the loss of coordinated THF and to the formation of the homoleptic chromous siloxides Cr₄(μ-OSiEt₃)₈ and Cr₃(OSiiPr₃)₂(μ-OSiiPr₃)₄, resp., in moderate to high yield. Use of TMEDA as a potentially bidentate donor mol. gave the monomeric cis-coordinated siloxide Cr(OSiiPr₃)₂(tmeda) (tmeda = N,N,N’,N’-tetramethylethane-1,2-diamine). Oxidation of Cr₂(OSiiPr₃)₂(μ-OSiiPr₃)₂(THF)₂ with CHI₃ and C₂Cl₆ produced the trigonal bipyramidal chromic compound Cr^III(OSiiPr)₃(THF)₂ and asym. coordinated Cr₂Cl₃(OSiiPr₃)₃(THF)₃, resp. Magnetic measurements (Evans and SQUID) hinted at (a) antiferromagnetic interactions between the Cr^II centers, (b) revealed higher effective magnetic moments (μ_eff) for cis-coordinated monomeric heteroleptic complexes compared to trans-coordinated ones, and (c) pointed out the highest (μ_eff) for the tetranuclear complex Cr₄(μ-OSiEt₃)₈ (6.26μB, SQUID, 300 K; Cr···Cr_adjacent average 2.535 Å).

Dalton Transactions published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C19H36BNO2Si, COA of Formula: C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Masada, Koichiro published the artcileReductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids, Related Products of alcohols-buliding-blocks, the publication is Organic Letters (2020), 22(13), 4922-4926, database is CAplus and MEDLINE.

Copper-mediated reductive coupling between CO₂ and an aldehyde to form α-hydroxycarboxylic acid was achieved using silylborane as a reductant. CO₂ cleanly inserted into a copper-carbon bond that was formed by the reaction between a silylcopper-NHC complex and an aldehyde. A series of reactions that regenerate the silylcopper complex were developed for the synthesis of an α-hydroxycarboxylic acid. After repeating each step iteratively for two cycles, 0.62 equiv of α-hydroxycarboxylic acid based on the copper complex was obtained.

Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Kikukawa, Yuji published the artcileA discrete octahedrally shaped [Ag₆]⁴⁺ cluster encapsulated within silicotungstate ligands, SDS of cas: 597-52-4, the publication is Chemical Communications (Cambridge, United Kingdom) (2013), 49(4), 376-378, database is CAplus and MEDLINE.

By the reaction of TBA₄H₄[γ-SiW₁₀O₃₆] (TBA = Bu₄N) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag₆]⁴⁺ cluster, TBA₈[Ag₆(γ-H₂SiW₁₀O₃₆)₂]·5H₂O (1), could be synthesized, and the mol. structure was determined 1 Could act as an efficient (pre)catalyst for the hydrolytic oxidation of structurally diverse silanes including aromatic, double bond-containing, and aliphatic ones which could be converted into the corresponding silanols in excellent yields.

Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Galloway, John M. published the artcileSynthesis and characterization of bifunctional surfaces with tunable functional group pairs, Name: Triethylsilanol, the publication is Surface Science (2016), 284-290, database is CAplus.

Grafting of pairs of functional groups onto a silica surface was demonstrated by tethering both terminals of an organochlorosilane precursor mol., Cl₂(CH₃)Si(CH₂)₄(CO)(OSi(i-Pr)₂)(CH₂)₂Si(CH₃)Cl₂, that possess a cleavable silyl ester bond, onto a silica surface. Hydrolytic cleavage of the silyl ester bond of the grafted mol. resulted in the generation of organized pairs of carboxylic acid and organosilanol groups. This organosilanol moiety was easily transformed into other functional groups through condensation reactions to form, together with the neighboring acid group, pairs such as carboxylic acid/secondary amine, carboxylic acid/pyridine, and carboxylic acid/phosphine. In the case of carboxylic acid/amine pairing, there was evidence of the formation of amide. A sample grafted with amine-carboxylic acid pairs was three times more active (per free amine) than a sample without such pairs for the nitroaldol condensation of 4-nitrobenzaldehyde and nitromethane.

Surface Science published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Name: Triethylsilanol.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Kazmierczak, Joanna published the artcileRu-Catalyzed Dehydrogenative Silylation of POSS-Silanols with Hydrosilanes: Its Introduction to One-Pot Synthesis, Category: alcohols-buliding-blocks, the publication is Inorganic Chemistry (2019), 58(2), 1201-1207, database is CAplus and MEDLINE.

A com. available and stable ruthenium dodecacarbonyl catalyst Ru₃(CO)₁₂ allows very efficient and convenient access to functionalized silsesquioxanes (SQs) containing siloxane moiety (Si-O-Si) via dehydrogenative coupling of POSS-silanols with hydrosilanes. With the aid of SiH-containing silsesquioxanes, an unprecedented one-pot procedure has been revealed, and the usefulness of this approach was demonstrated by the synthesis of various derivatives via O-silylation, as well as C:C and C:N hydrosilylation.

Inorganic Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Category: alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Shimizu, Ken-ichi published the artcileSurface Oxygen-Assisted Pd Nanoparticle Catalysis for Selective Oxidation of Silanes to Silanols, SDS of cas: 597-52-4, the publication is Chemistry – A European Journal (2012), 18(8), 2226-2229, S2226/1-S2226/12, database is CAplus and MEDLINE.

Oxygen-adsorbed Pd surfaces show higher reactivity for water dissociation than clean Pd surfaces. Thus, carbon-supported Pd nanoparticles with surface oxygen atoms show higher activity for hydrolytic oxidation of silanes than previously reported catalysts. The synthetic utility of this catalyst is quite high because the catalyst, readily prepared from com. Pd/C, is easily recovered and reused, and shows high activity in oxidation of various silanes. This is a surface-science driven strategy of catalyst design for green organic synthesis. E.g., hydration of Et₃SiH in presence of carbon-supported Pd nanoparticles covered with O gave >99% Et₃SiOH, with TON = 20,000.

Chemistry – A European Journal published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C4HN5, SDS of cas: 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Limnios, Dimitris published the artcileOrganocatalytic Oxidation of Organosilanes to Silanols, Related Products of alcohols-buliding-blocks, the publication is ACS Catalysis (2013), 3(10), 2239-2243, database is CAplus.

The oxidation of organosilanes to silanols constitutes an attractive transformation for both industry and academia. Bypassing the need for stoichiometric oxidants or precious metal catalytic complexes, the first organocatalytic oxidation of silanes has been accomplished. Catalytic amounts of 2,2,2-trifluoroacetophenone, in combination with the green oxidant H₂O₂, lead to excellent to quant. yields in a short reaction time. A variety of alkyl, aryl, alkenyl, and alkynyl substituents can be tolerated, providing an easy, cheap, efficient, and practical solution to a highly desirable transformation.

ACS Catalysis published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts