Category: 597-52-4

Cao, Xiamin’s team published research in International Journal of Food Properties in 17 | CAS: 597-52-4

International Journal of Food Properties published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Application In Synthesis of 597-52-4.

Cao, Xiamin published the artcileEffects of High Hydrostatic Pressure Combined with Blanching on Microorganisms and Quality Attributes of Cloudy and Clear Strawberry Juices, Application In Synthesis of 597-52-4, the publication is International Journal of Food Properties (2014), 17(9), 1900-1920, database is CAplus.

Effects of high hydrostatic pressure combined with blanching on microorganisms and quality attributes of strawberry juices were investigated. High hydrostatic pressure at 600 MPa/4 min/ambient temperature inactivated total aerobic bacteria, coliform bacteria, yeasts, and molds in juices, ensuring their microbiol. safety. Under this condition, the cloudiness of cloudy juices increased by 54.49% and its viscosity decreased by 12.40%. Ascorbic acid decreased by 7.82% in cloudy juices and 12.60% in clear juices. The content of total volatile flavor compounds increased by 13.21% in cloudy juices and decreased by 6.92% in clear juices. No significant changes in anthocyanins, total phenols, and antioxidant capacity were found with high hydrostatic pressure treatment.

International Journal of Food Properties published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Application In Synthesis of 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Li, Zhiwen’s team published research in Catalysis Science & Technology in 4 | CAS: 597-52-4

Catalysis Science & Technology published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Li, Zhiwen published the artcileNanoporous palladium-catalyzed silicon-based one-pot cross-coupling reaction of aryl iodides with organosilanes, SDS of cas: 597-52-4, the publication is Catalysis Science & Technology (2014), 4(6), 1734-1737, database is CAplus.

One-pot cross-coupling of aryl iodides with organosilanes was realized in excellent yield by utilizing dealloyed nanoporous palladium as a sustainable and heterogeneous catalyst. The reaction was completed under mild conditions and the catalyst was reused several times without evident loss of its catalytic activity.

Catalysis Science & Technology published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Chainet, Fabien’s team published research in Journal of Chromatography A in 1264 | CAS: 597-52-4

Journal of Chromatography A published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Application In Synthesis of 597-52-4.

Chainet, Fabien published the artcileDevelopment of heart-cutting multidimensional gas chromatography coupled to time of flight mass spectrometry for silicon speciation at trace levels in gasoline samples, Application In Synthesis of 597-52-4, the publication is Journal of Chromatography A (2012), 80-86, database is CAplus and MEDLINE.

To improve the understanding of hydrotreatment (HDT) catalyst poisoning by silicon species, these mols. must be characterized in petroleum products using powerful anal. systems. Heart-cutting gas chromatog. coupled to time of flight mass spectrometry (GC-GC/TOFMS) method equipped with a Deans switch (DS) system was developed for the direct characterization of target silicon compounds at trace level (μg/kg) in gasoline samples. This method was performed to identify silicon compounds never characterized before. After the selection of the 2nd dimension column using GC-GC-FID, GC-GC/TOFMS was performed. The calibration curves obtained by the GC-GC/TOFMS method were linear up to 1000 μg kg-1. Limits of detection (LOD) were ranging from 5 to 33 μg/kg in spiked gasoline. The method provided sufficient selectivity and sensitivity to characterize known silicon compounds thanks to their specific ions and their retention times. The anal. of a naphtha sample by GC-GC/TOFMS showed cyclic siloxanes (Dn) as major compounds of PDMS thermal degradation with the occurrence of linear siloxanes, especially hexamethyldisiloxane (L2), which was never characterized in petroleum products but already known as severe poison for catalyst.

Journal of Chromatography A published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Application In Synthesis of 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Luo, Nianhua’s team published research in Organometallics in 39 | CAS: 597-52-4

Organometallics published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Synthetic Route of 597-52-4.

Luo, Nianhua published the artcileHighly Selective Hydroxylation and Alkoxylation of Silanes: One-Pot Silane Oxidation and Reduction of Aldehydes/Ketones, Synthetic Route of 597-52-4, the publication is Organometallics (2020), 39(1), 165-171, database is CAplus.

An efficient chemoselective iridium-catalyzed method for the hydroxylation and alkoxylation of organosilanes to generate hydrogen gas and silanols or silyl ethers was developed. A variety of sterically hindered silanes with alkyl, aryl, and ether groups were tolerated. Furthermore, this atom-economical catalytic protocol can be used for the synthesis of silanediols and silanetriols. A one-pot silane oxidation and chemoselective reduction of aldehydes/ketones was also realized.

Organometallics published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Synthetic Route of 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Wang, Jing’s team published research in Science China: Chemistry in 61 | CAS: 597-52-4

Science China: Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C9H8ClNO3S, Product Details of C6H16OSi.

Wang, Jing published the artcileMetal-free visible-light-mediated aerobic oxidation of silanes to silanols, Product Details of C6H16OSi, the publication is Science China: Chemistry (2018), 61(12), 1594-1599, database is CAplus.

Herein, the first metal-free visible-light-mediated aerobic oxidation of silanes to silanols using 2 mol% Rose Bengal as the catalyst, air (O2) as the oxidant and water as the additive is reported. While this method produces various silanols in a simple, cost-effective, efficient (92%-99% yields) and scalable fashion, its reaction mechanism is very different than the reported ones associated with metal catalysis.

Science China: Chemistry published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C9H8ClNO3S, Product Details of C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Ma, Lina’s team published research in RSC Advances in 4 | CAS: 597-52-4

RSC Advances published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Formula: C6H16OSi.

Ma, Lina published the artcileGold nanoparticles supported on the periodic mesoporous organosilica SBA-15 as an efficient and reusable catalyst for selective oxidation of silanes to silanols, Formula: C6H16OSi, the publication is RSC Advances (2014), 4(13), 6807-6810, database is CAplus.

Gold nanoparticles are confined and stabilized within the channels of SBA-15 through the poly(ionic liquid) brushes that are anchored onto the pore walls of SBA-15. The supported gold catalyst exhibited remarkably high catalytic activities for selective oxidation of silanes into silanols using water as an oxidant without the use of organic solvents.

RSC Advances published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Formula: C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Trzmiel, Simon P. O.’s team published research in Dalton Transactions in 51 | CAS: 597-52-4

Dalton Transactions published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C19H36BNO2Si, COA of Formula: C6H16OSi.

Trzmiel, Simon P. O. published the artcileChromous siloxides of variable nuclearity and magnetism, COA of Formula: C6H16OSi, the publication is Dalton Transactions (2022), 51(13), 5072-5081, database is CAplus and MEDLINE.

Treatment of Cr[N(SiMe3)2]2(THF)2 with HOSiR3 (R = Et, iPr) in THF afforded the bridged CrII siloxide complexes Cr3(OSiEt3)2(μ-OSiEt3)4(THF)2 and Cr2(OSiiPr3)2(μ-OSiiPr3)2(THF)2 in high yield. Exposure of these compounds to vacuum in aliphatic solvents led to the loss of coordinated THF and to the formation of the homoleptic chromous siloxides Cr4(μ-OSiEt3)8 and Cr3(OSiiPr3)2(μ-OSiiPr3)4, resp., in moderate to high yield. Use of TMEDA as a potentially bidentate donor mol. gave the monomeric cis-coordinated siloxide Cr(OSiiPr3)2(tmeda) (tmeda = N,N,N’,N’-tetramethylethane-1,2-diamine). Oxidation of Cr2(OSiiPr3)2(μ-OSiiPr3)2(THF)2 with CHI3 and C2Cl6 produced the trigonal bipyramidal chromic compound CrIII(OSiiPr)3(THF)2 and asym. coordinated Cr2Cl3(OSiiPr3)3(THF)3, resp. Magnetic measurements (Evans and SQUID) hinted at (a) antiferromagnetic interactions between the CrII centers, (b) revealed higher effective magnetic moments (μeff) for cis-coordinated monomeric heteroleptic complexes compared to trans-coordinated ones, and (c) pointed out the highest (μeff) for the tetranuclear complex Cr4(μ-OSiEt3)8 (6.26μB, SQUID, 300 K; Cr···Cradjacent average 2.535 Å).

Dalton Transactions published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C19H36BNO2Si, COA of Formula: C6H16OSi.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Masada, Koichiro’s team published research in Organic Letters in 22 | CAS: 597-52-4

Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Masada, Koichiro published the artcileReductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids, Related Products of alcohols-buliding-blocks, the publication is Organic Letters (2020), 22(13), 4922-4926, database is CAplus and MEDLINE.

Copper-mediated reductive coupling between CO2 and an aldehyde to form α-hydroxycarboxylic acid was achieved using silylborane as a reductant. CO2 cleanly inserted into a copper-carbon bond that was formed by the reaction between a silylcopper-NHC complex and an aldehyde. A series of reactions that regenerate the silylcopper complex were developed for the synthesis of an α-hydroxycarboxylic acid. After repeating each step iteratively for two cycles, 0.62 equiv of α-hydroxycarboxylic acid based on the copper complex was obtained.

Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Kikukawa, Yuji’s team published research in Chemical Communications (Cambridge, United Kingdom) in 49 | CAS: 597-52-4

Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Kikukawa, Yuji published the artcileA discrete octahedrally shaped [Ag6]4+ cluster encapsulated within silicotungstate ligands, SDS of cas: 597-52-4, the publication is Chemical Communications (Cambridge, United Kingdom) (2013), 49(4), 376-378, database is CAplus and MEDLINE.

By the reaction of TBA4H4[γ-SiW10O36] (TBA = Bu4N) with AgOAc (OAc = acetate) using dimethylphenylsilane as a reductant in acetone, a unique polyoxometalate containing a discrete octahedrally shaped [Ag6]4+ cluster, TBA8[Ag6(γ-H2SiW10O36)2]·5H2O (1), could be synthesized, and the mol. structure was determined 1 Could act as an efficient (pre)catalyst for the hydrolytic oxidation of structurally diverse silanes including aromatic, double bond-containing, and aliphatic ones which could be converted into the corresponding silanols in excellent yields.

Chemical Communications (Cambridge, United Kingdom) published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, SDS of cas: 597-52-4.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts

Masada, Koichiro’s team published research in Organic Letters in 22 | CAS: 597-52-4

Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Masada, Koichiro published the artcileReductive Coupling of Carbon Dioxide and an Aldehyde Mediated by a Copper(I) Complex toward the Synthesis of α-Hydroxycarboxylic Acids, Related Products of alcohols-buliding-blocks, the publication is Organic Letters (2020), 22(13), 4922-4926, database is CAplus and MEDLINE.

Copper-mediated reductive coupling between CO2 and an aldehyde to form α-hydroxycarboxylic acid was achieved using silylborane as a reductant. CO2 cleanly inserted into a copper-carbon bond that was formed by the reaction between a silylcopper-NHC complex and an aldehyde. A series of reactions that regenerate the silylcopper complex were developed for the synthesis of an α-hydroxycarboxylic acid. After repeating each step iteratively for two cycles, 0.62 equiv of α-hydroxycarboxylic acid based on the copper complex was obtained.

Organic Letters published new progress about 597-52-4. 597-52-4 belongs to alcohols-buliding-blocks, auxiliary class Aliphatic Chain, name is Triethylsilanol, and the molecular formula is C6H16OSi, Related Products of alcohols-buliding-blocks.

Referemce:
https://en.wikipedia.org/wiki/Alcohol,
Alcohols – Chemistry LibreTexts