Teodorovic, Aleksandar V. published the artcileStabilization of long-chain intermediates in solution. Tridecyl radicals and cations, Quality Control of 58783-82-7, the main research area is tetradecanoic acid decarboxylation product formation tridecyl radical rearrangement.
Tetradecanoic acid was decarboxylated by means of lead(IV) acetate (LTA) under thermal (81 °C) and photolytic (r.t.) conditions in benzene solution The mixture of products, obtained in thermal reaction, consists of esters (acetoxyalkanes and carboxylates), tridecenes, tridecane and phenyltridecane. Addnl., tetradecane and hexacosane, under photolytic conditions, were formed. The classes of products and their distribution might be explained by presence of intermediate 1-tridecyl radical which can undergo intramol. (result in formation of rearranged carbon centered radicals) and intermol. stabilization pathways. Exptl. obtained results were used as input data for computational Monte Carlo simulation study of the reaction. On the basis of these results, radical rearrangements, as well as hydride shifts in tridecyl system are discussed.
Journal of Molecular Structure published new progress about Deamination. 58783-82-7 belongs to class alcohols-buliding-blocks, name is 5-Tridecanol, and the molecular formula is C13H28O, Quality Control of 58783-82-7.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts