Zheng, Jianxia; Elangovan, Saravanakumar; Valyaev, Dmitry A.; Brousses, Remy; Cesar, Vincent; Sortais, Jean-Baptiste; Darcel, Christophe; Lugan, Noel; Lavigne, Guy published the artcile< Hydrosilylation of Aldehydes and Ketones Catalyzed by Half-Sandwich Manganese(I) N-Heterocyclic Carbene Complexes>, Formula: C6H9NO, the main research area is aldehyde ketone hydrosilylation manganese heterocyclic carbene complex catalyst.
Easily available manganese(I) N-heterocyclic carbene (NHC) complexes, Cp(CO)2Mn(NHC), obtained in one step from industrially produced cymantrene, were evaluated as pre-catalysts in the hydrosilylation of carbonyl compounds under UV irradiation Complexes with NHC ligands incorporating at least one mesityl group led to the most active and selective catalytic systems. A variety of aldehydes (13 examples) and ketones (11 examples) were efficiently reduced under mild conditions [Cp(CO)2Mn(IMes) (1 mol%), Ph2SiH2 (1.5 equiv), hν (350 nm), toluene, 25°, 1-24 h] with good functional group tolerance.
Advanced Synthesis & Catalysis published new progress about Aldehydes Role: RCT (Reactant), RACT (Reactant or Reagent). 52160-51-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C6H9NO, Formula: C6H9NO.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts