Category: 50966-69-3

Polshettiwar, Vivek published the artcileNano-organocatalyst: magnetically retrievable ferrite-anchored glutathione for microwave-assisted Paal-Knorr reaction, aza-Michael addition, and pyrazole synthesis, Name: 3-(1H-Pyrrol-1-yl)propan-1-ol, the main research area is Paal Knorr aza Michael pyrazole synthesis microwave glutathione nanocatalyst.

Postsynthetic surface modification of magnetic nanoparticles by glutathione imparts desirable chem. functionality and enables the generation of catalytic sites on the surfaces of ensuing organocatalysts. In this article, we discuss the developments, unique activity, and high selectivity of nano-organocatalysts for microwave-assisted Paal-Knorr reaction, aza-Michael addition, and pyrazole synthesis. Their insoluble character coupled with paramagnetic nature enables easy separation of these nano-catalysts from the reaction mixture using external magnet, which eliminates the requirement of catalyst filtration.

Tetrahedron published new progress about Amino acid esters Role: SPN (Synthetic Preparation), PREP (Preparation). 50966-69-3 belongs to class alcohols-buliding-blocks, name is 3-(1H-Pyrrol-1-yl)propan-1-ol, and the molecular formula is C7H11NO, Name: 3-(1H-Pyrrol-1-yl)propan-1-ol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Schiffner, Julia A. published the artcileEnantioselective Fujiwara-Moritani Indole and Pyrrole Annulations Catalyzed by Chiral Palladium(II)-NicOx Complexes, SDS of cas: 50966-69-3, the main research area is pyridinecarboxylate oxazolinyl preparation chiral ligand Fujiwara Moritani annulation; indole pyrrole alkenyl preparation asym intramol Fujiwara Moritani cyclization.

The catalytic asym. Fujiwara-Moritani ring closures of several indole- and pyrrole-based cyclization precursors, e.g. I (R1 = H, R12 = benzo; X = CH2, CH2CH2; R2 = Me, Ph), are reported. These unprecedented oxidative palladium(II)-catalyzed annulations allow for the formation of a stereogenic quaternary carbon atom, and decent levels of enantiocontrol are seen in 5-exo-trig cyclizations (54% ee for an indole and 76% ee for a pyrrole) while 6-exo-trig ring closures afford essentially racemic material. Novel oxazoline ligands with a nicotine platform (NicOx) are pivotal for good catalytic turnover as conventional PyOx ligands failed to produce acceptable chem. yields. The preparation of these NicOx ligands II (R3 = i-Pr, t-Bu, PhCH2; R4 = Me, Et, F3CCH2) as well as the syntheses of the cyclization precursors, e.g. I, are described in detail.

European Journal of Organic Chemistry published new progress about Cyclization catalysts, stereoselective. 50966-69-3 belongs to class alcohols-buliding-blocks, name is 3-(1H-Pyrrol-1-yl)propan-1-ol, and the molecular formula is C7H11NO, SDS of cas: 50966-69-3.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ono, Tetsuya published the artcileElectrocatalytic Oxidation of Carbohydrates Mediated by Nitroxyl Radical-Modified Electrodes in Aqueous Solution, Application of 3-(1H-Pyrrol-1-yl)propan-1-ol, the main research area is electrocatalysis oxidation carbohydrate mediated nitroxyl radical modified electrode.

The electrocatalytic activity of a 2,2,6,6-tetramethylpipridine-N-oxyl (TEMPO)-modified electrode toward the oxidation of carbohydrates in phosphate buffer solution was studied under neutral aqueous solution conditions at 25°. The modified electrode was prepared on the surface of a glassy C electrode by the electrochem. polymerization of a TEMPO precursor containing a pyrrole side chain. Cyclic voltammetric studies showed that the anodic peak current increased with the concentration of carbohydrates in a dose-dependent manner.

Electroanalysis published new progress about Chemically modified electrodes. 50966-69-3 belongs to class alcohols-buliding-blocks, name is 3-(1H-Pyrrol-1-yl)propan-1-ol, and the molecular formula is C7H11NO, Application of 3-(1H-Pyrrol-1-yl)propan-1-ol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts