Category: 34374-88-4

Application In Synthesis of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehydeIn 2020 ,《Sulphonate functionalized covalent organic framework-based magnetic sorbent for effective solid phase extraction and determination of fluoroquinolones》 was published in Journal of Chromatography A. The article was written by Wen, Aying; Li, Guoliang; Wu, Di; Yu, Yanxin; Yang, Yan; Hu, Na; Wang, Honglun; Chen, Jian; Wu, Yongning. The article contains the following contents:

Most of the reported covalent organic frameworks (COFs) are hydrophobic, limiting their adsorption application in sample pretreatment field. In this work, sulfonate functionalized magnetic covalent organic frameworks (COFs) composites were first synthesized by loading gold nanoparticles on Fe3O4@COF(TpBD) surface and then functionalized by sodium 3-mercaptopropanesulfonate immobilization via Au-S bonding formation (denoted as Fe3O4@COF(TpBD)@Au-MPS nanocomposites), which were further utilized as adsorbents for magnetic solid-phase extraction (MSPE) of fluoroquinolones. Compared with Fe3O4@COF(TpBD), the composites exhibited higher affinity to fluoroquinolones. Under optimized conditions, the developed MSPE method coupled with HPLC-MS/MS showed good linearity (R2 ≥0.9989) and yielded low limits of detection (0.1-1.0μg kg-1) for fluoroquinolones. Moreover, the proposed method was successfully applied to extract fluoroquinolones from spiked meats (pork, chicken and bovine). The satisfactory recoveries were in the range of 82-110.2% with the relative standard deviations (RSDs) lower than 7.7%. These results indicated that the Fe3O4@COF(TpBD)@Au-MPS is a promising magnetic adsorbent for trace fluoroquinolones determination in meat samples. This work not only provided a facile strategy for COF functionalization, but also developed an efficient method for detecting fluoroquinolones in foodstuffs. In the experimental materials used by the author, we found 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Application In Synthesis of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Phloroglucinol derivatives are a major class of secondary metabolites. Phloroglucinol compounds can be classified into monomeric, dimeric, trimeric and higher phloroglucinols, and phlorotannins.Application In Synthesis of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde

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Alcohol – Wikipedia,
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In 2019,ACS Applied Nano Materials included an article by Cui, Wei-Rong; Zhang, Cheng-Rong; Jiang, Wei; Liang, Ru-Ping; Qiu, Jian-Ding. HPLC of Formula: 34374-88-4. The article was titled 《Covalent Organic Framework Nanosheets for Fluorescence Sensing via Metal Coordination》. The information in the text is summarized as follows:

Covalent organic framework nanosheets (COF NSs) provide well-ordered π-π structures that can be used to develop luminescent materials. However, most COF NSs have problems of weak luminescence and low fluorescence quantum yield. In this work, the authors prepared covalent organic framework nanosheets (Bpy-NSs) with good water dispersibility, nitrogen-rich functional groups, and regular pore structure. The authors explored the coordination of Bpy-NSs with Al3+ to eliminate the fluorescence quenching process caused by photoinduced electron transfer (PET). Thus, the fluorescence “”turn-on”” signal linearly increases with Al3+ concentration, achieving a 15.7-fold improved in fluorescence, and the absolute fluorescence quantum yield increased from 0.15 to 1.74%. Furthermore, this is the first COF fluorescence sensor that can be used for high sensitivity and selectivity detection of Al3+ in the aqueous phase. The authors anticipate that the expansion of metal ions coordination strategy in the aqueous phase will not only significantly enhance the fluorescence of COF NSs but also extend the functional range of COF NSs. The experimental process involved the reaction of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4HPLC of Formula: 34374-88-4)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.HPLC of Formula: 34374-88-4For acyl phloroglucinols, it is considered the largest category of compounds among phloroglucinols of natural characteristics.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Journal of Membrane Science included an article by Shi, Xiansong; Xiao, Ankang; Zhang, Chenxu; Wang, Yong. Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde. The article was titled 《Growing covalent organic frameworks on porous substrates for molecule-sieving membranes with pores tunable from ultra- to nanofiltration》. The information in the text is summarized as follows:

Crystalline imine-based covalent organic frameworks (COFs) have attracted great interest as next-generation water treatment materials owning to their numerous merits. The construction of COF layers with tunable pore sizes ranging from meso- to micropores, which can significantly broaden the membrane selectivity from ultra- (UF) to nanofiltration (NF), has remained unexplored. Herein, we demonstrate the controllable solvothermal synthesis of COF layers with adjustable pore sizes on anodic aluminum oxide (AAO) substrates. With rising synthesis duration the modulation on pore sizes of AAO supports can be achieved till the formation of continuous COF layers, leading to a gradually enhanced selectivity. Importantly, the synthesized microporous COFs shrink the pore sizes of AAO substrates and provide addnl. nanochannels for water transporting, eventuating in a ∼2-9 times higher permeance than other reported UF membranes with comparable rejections. Once forming continuous COF layers, more rigid selectivities based on COF inherent nanochannels (∼1.83 nm) can be realized with capacities of removing dyes from water or organic solvent. This work provides a facile methodol. to construct COF-based membranes with broadly tunable separation performance, recommending the membranes for removing targeted mols. including proteins, nanoparticles, and dyes. In the experiment, the researchers used 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.Reference of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehydeFor acyl phloroglucinols, it is considered the largest category of compounds among phloroglucinols of natural characteristics.

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Fabrication of Hydrazone-Linked Covalent Organic Frameworks Using Alkyl Amine as Building Block for High Adsorption Capacity of Metal Ions》 were Li, Ya; Wang, Chang; Ma, Shujuan; Zhang, Haiyang; Ou, Junjie; Wei, Yinmao; Ye, Mingliang. And the article was published in ACS Applied Materials & Interfaces in 2019. Electric Literature of C9H6O6 The author mentioned the following in the article:

There are several researches on the preparation and application of hydrazone-linked covalent organic frameworks (COFs), and all of them generally necessitate rigid aromatic amines. Herein, we report a strategy for design and synthesis of COF with flexible alkyl amine as a building block and intramol. hydrogen bonding as a knot in the network. The proof-of-concept design was demonstrated by exploring 1,3,5-triformylphloroglucinol and oxalyldihydrazide (ODH) as precursors to synthesize a novel COF material (TpODH), in which different organic building units are combined through hydrazone bonds to form two-dimensional porous frameworks. It should be pointed that irreversible enol-to-keto tautomerism and intramol. N-H···O=C hydrogen bonding of TpODH would enhance the crystallinity and chem. stability, leading to large sp. surface area of 835 m2 g-1. However, another COF synthesized with 1,3,5-triformylbenzene and ODH exhibited less crystallinity and low special surface area (94 m2 g-1). Representatively, the resulting TpODH afforded Cu(II) and Hg(II) capacities of 324 and 1692 mg g-1, resp., which exceeded that of most COFs previously reported. Moreover, the Fourier-transform IR and XPS spectra analyses were taken to demonstrate the adsorption mechanism. These results suggested that the materials could be applied to the removal of metallic ions in the future. In the experiment, the researchers used many compounds, for example, 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Electric Literature of C9H6O6)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Regarding monomeric phloroglucinols, this group encompasses acryl phloroglucinols, phloroglucinol-terpene adducts, phloroglucinol glycosides, halogenated phloroglucinols, prenylated phloroglucinols, and cyclicroup polyketides.Electric Literature of C9H6O6

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Ionic liquid as a green solvent for ionothermal synthesis of 2D keto-enamine-linked covalent organic frameworks》 were Dong, Bin; Wang, Wen-Jing; Pan, Wei; Kang, Guo-Jun. And the article was published in Materials Chemistry and Physics in 2019. COA of Formula: C9H6O6 The author mentioned the following in the article:

Covalent organic frameworks (COFs) are usually synthesized under solvothermal conditions in a mixture of high-boiling organic solvents in a sealed system. By using a room temperature ionic liquid (IL) as a solvent, we presented the preparation of two-dimensional (2D) keto-enamine-linked COFs in an open container at ambient pressure. The as-synthesized 2D keto-enamine-linked COFs have ordered open channels and so the IL can be completely removed from the pores to provide the sole formation of crystalline 2D COFs. Not only the imidazolium-based IL acted as both solvent and catalyst, it was also recycled for further use without activity loss. The experimental part of the paper was very detailed, including the reaction process of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4COA of Formula: C9H6O6)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Regarding monomeric phloroglucinols, this group encompasses acryl phloroglucinols, phloroglucinol-terpene adducts, phloroglucinol glycosides, halogenated phloroglucinols, prenylated phloroglucinols, and cyclicroup polyketides.COA of Formula: C9H6O6

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Magnetic covalent organic framework as platform for high-performance extraction of Cr(VI) and bisphenol A from aqueous solution》 was published in Journal of Hazardous Materials in 2020. These research results belong to Zhong, Xin; Lu, Zhipeng; Liang, Wen; Hu, Baowei. Name: 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde The article mentions the following:

The magnetic covalent organic framework with β-ketoenamine linkage (Fe3O4@COF(TpPa-1)) was fabricated by the hydrothermal method. The obtained Fe3O4@TpPa-1 integrated four advantages, namely easy preparation, high stability, excellent adsorption performance (485.2 m2/g) and good recoverability (19.5 emu/g), which enabled it an ideal sorbent for wastewater treatment. Fe3O4@TpPa-1 exhibited excellent adsorption capacities for Cr (VI) (245.45 mg/g) and bisphenol A (1220.97 mg/g). The adsorption kinetics and isotherms were in alignment to the pseudo-second-order and Langmuir model, resp. After five times cycles, the adsorption capacity of Fe3O4@TpPa-1 still retained at a high level. According to Materials Studio simulation and XPS anal., the adsorption mechanism was attributed to the presence of the homogeneously distributed imine and carbonyl functional groups in the framework of TpPa-1, allowing them to serve as platforms for anchoring heavy metals and organic pollutants. Besides, the hydrophobic skeleton structures of TpPa-1 endowed them good adsorption performance towards organic pollutants via hydrogen -bonding (NH…O…HO) and π-π interaction. Therefore, the recyclable Fe3O4@TpPa-1 showed a broad application prospects in environmental remediation. The results came from multiple reactions, including the reaction of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Name: 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.Name: 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehydeFor acyl phloroglucinols, it is considered the largest category of compounds among phloroglucinols of natural characteristics.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The author of 《Ion Rejection in Covalent Organic Frameworks: Revealing the Overlooked Effect of In-Pore Transport》 were Xu, Fang; Wei, Mingjie; Zhang, Xin; Wang, Yong. And the article was published in ACS Applied Materials & Interfaces in 2019. Product Details of 34374-88-4 The author mentioned the following in the article:

Covalent organic frameworks (COFs), possessing highly ordered and intrinsic nanopores with high d. and tunable sizes, are expected to find important applications in ion separation and desalination. The design of COF membranes with outstanding permselectivity requires understanding the ion rejection behaviors of COF multilayers. However, the ion rejection mechanism of COF multilayers remains to be elucidated because it may significantly differ from that of conventional polyamide membranes. Herein, we use nonequilibrium mol. dynamics simulations to investigate the ion transport through multilayers of TpHZ, which is a stable, imine-linked COF. Surprisingly, we find that the rejection to NaCl is determined by its rejection to Na+ rather than to Cl-, although hydrated Cl- is bigger than hydrated Na+. Inside the channels of the TpHZ multilayers, Na+ ions transport evidently slower than water mols., implying that the in-pore transport effect instead of the commonly thought pore-entrance sieving effect governs ion rejection. The in-pore transport effect of Na+ is mainly due to the hydration of Na+ with pore wall and stronger capability of the hydrated Na+ ions to form hydrogen bonds with pore wall, both of which are primarily originated from the polarity of the COF. This work reveals the significant role of in-pore transport in ion rejection, which is overlooked in commonly used polyamide desalination membranes, and develops a universal equation capable of describing ion rejections of all membranes, especially those that contain structures of nanopores or nanochannels by considering both the effects of pore-entrance sieving and in-pore transport. The results came from multiple reactions, including the reaction of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Product Details of 34374-88-4)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Regarding monomeric phloroglucinols, this group encompasses acryl phloroglucinols, phloroglucinol-terpene adducts, phloroglucinol glycosides, halogenated phloroglucinols, prenylated phloroglucinols, and cyclicroup polyketides.Product Details of 34374-88-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,ACS Applied Materials & Interfaces included an article by Wu, Yang; Yan, Dongwan; Zhang, Zhongyue; Matsushita, Michio M.; Awaga, Kunio. Electric Literature of C9H6O6. The article was titled 《Electron Highways into Nanochannels of Covalent Organic Frameworks for High Electrical Conductivity and Energy Storage》. The information in the text is summarized as follows:

To enhance the electron transfer within the covalent organic frameworks (COFs), we obtained a nanocomposite of conductive poly(3,4-ethylenedioxythiophene) (PEDOT) and redox-active AQ-COF by performing a facile in situ solid-state polymerization inside the nanochannels of COFs. The PEDOT chains functioned like electron highways within the nanochannels, resulting in a PEDOT@AQ-COF nanocomposite with an excellent elec. conductivity of 1.1 S cm-1 and a remarkably improved performance in faradaic energy storage. The all-organic PEDOT@AQ-COF electrode showed specific capacitance as high as 1663 F g-1 (at 1 A g-1), ultrafast charge/discharge rate performance (998 F g-1 at 500 A g-1), and excellent stability for 10 000 cycles. This research demonstrates a promising strategy for increasing the conductivity of COF-based materials and broadening their applications. The experimental process involved the reaction of 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Electric Literature of C9H6O6)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives.Electric Literature of C9H6O6For acyl phloroglucinols, it is considered the largest category of compounds among phloroglucinols of natural characteristics.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Application of 34374-88-4In 2020 ,《Thiol-functionalized magnetic covalent organic frameworks by cutting strategy for efficient removal of Hg2+ from water》 was published in Journal of Hazardous Materials. The article was written by Huang, Lijin; Shen, Rujia; Liu, Ruiqi; Shuai, Qin. The article contains the following contents:

Covalent organic frameworks (COFs) have attracted tremendous attention due to their excellent performance in wastewater remediation, but their practical application still suffers from various challenges. The development of highly-efficient magnetic COFs along with fast adsorption kinetic and high adsorption capacity is very promising. To achieve the purpose, thiol-functionalized magnetic covalent organic frameworks (M-COF-SH) with abundant accessible chelating sites were designed and synthesized by utilizing disulfide derivative as building blocks and subsequently cutting off the disulfide linkage. After the cutting process, the crystallinity, porosity, superparamagnetism of pristine M-COF are well maintained, and the resultant M-COF-SH turned out to be an effective and selective platform for Hg2+ capture from water. Impressively, the resulting composite exhibited a maximum adsorption capacity of Hg2+ as high as 383 mg g-1. In addition, it also displays a rapid kinetic, where the adsorption equilibrium can be achieved within 10 min. More importantly, there is no significant loss of its adsorption performance even after recycling 5 times. This work not only offers a reliable platform for wastewater remediation but also provides a conceptual guide to prepare functionalized M-COF composites which cannot be obtained through conventional approaches. In addition to this study using 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde, there are many other studies that have used 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Application of 34374-88-4) was used in this study.

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Phloroglucinol derivatives are a major class of secondary metabolites. Phloroglucinol compounds can be classified into monomeric, dimeric, trimeric and higher phloroglucinols, and phlorotannins.Application of 34374-88-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《Ball milling synthesis of covalent organic framework as a highly active photocatalyst for degradation of organic contaminants》 was written by Lv, Hongzhou; Zhao, Xiaoli; Niu, Hongyun; He, Sijing; Tang, Zhi; Wu, Fengchang; Giesy, John P.. Application of 34374-88-4This research focused ontriformylphloroglucinol melamine covalent organic framework photocatalyst wastewater treatment; Ball milling; Covalent organic framework; Mechanochemical fabrication; Photocatalysis; TpMA. The article conveys some information:

Facile, environmentally-friendly fabrication of high-yield and stable covalent organic framework (COF) materials was a limitation to their large-scale production and application. Ball milling was used to synthesize COF by mechanochem. reaction between 1,3,5-triformylphloroglucinol (Tp) and melamine (MA) at ambient temperature Different routes (liquid-free, solvent-assisted and catalyst-assisted) and proportions of liquids (solvents or catalyst) were studied. Two morphologies were obtained when various amounts of liquid were added during grinding. The 2 forms were interwoven thread-shaped and exfoliative thin ribbon-like structures. Further, visible-light photocatalytic (λ > 400 nm) performance and mechanism of the 2 structures of COFs were studied. The exfoliative ribbon-like structures exhibited greater rates of photodegradation of phenol and retained 87.6% of initial photodegradation after being used 4 times. Addition of liquid catalyst not only improved crystallinity of the COF materials, but also enhanced rates of photocatalytic reactions. Photocatalytic activity of the exfoliative structure of TpMA synthesized by ball milling was comparable with that of the photocatalyst prepared using the solvothermal method, while time to prepare the catalyst was shortened by 36-fold and the amount of solvent used was reduced by 8-fold at room temperature Mechanochem. synthesis is a promising potential tool for large-scale production of COFs, which will make greater use of COFs for degradation of pollutants. After reading the article, we found that the author used 2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4Application of 34374-88-4)

2,4,6-Trihydroxybenzene-1,3,5-tricarbaldehyde(cas: 34374-88-4) is a member of phloroglucinol derivatives. Phloroglucinol derivatives are a major class of secondary metabolites. Phloroglucinol compounds can be classified into monomeric, dimeric, trimeric and higher phloroglucinols, and phlorotannins.Application of 34374-88-4

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts