Category: 2425-77-6

Schmode, Philip;Hochgesang, Adrian;Goel, Mahima;Meichsner, Florian;Mohanraj, John;Fried, Martina;Thelakkat, Mukundan published 《A Solution-Processable Pristine PEDOT Exhibiting Excellent Conductivity, Charge Carrier Mobility, and Thermal Stability in the Doped State》 in 2021. The article was appeared in 《Macromolecular Chemistry and Physics》. They have made some progress in their research.COA of Formula: C16H34O The article mentions the following:

PEDOT:PSS [poly(3,4-ethylenedioxythiophene) polystyrene sulfonate] is a widely used insoluble conducting polymer, which is therefore processed from dispersions. In this work, PEDOT homopolymers (PEDOT-C₆C₈ 1 and 2) highly soluble in common solvents like toluene, THF, and chloroform are synthesized with a high control of mol. weight and low dispersity using Kumada catalyst transfer polymerization of a newly synthesized EDOT monomer carrying a branched alkyl substituent. Pristine PEDOT-C₆C₈ allows the use in accumulation mode transistors with a high charge carrier mobility of 5 x 10^-4 cm² V^-1 s^-1. Moreover, these polymers can be doped in a controlled fashion, reaching conductivities of 10^-3 S cm^-1 at 10 mol% of a dopant, Spiro-MeOTAD(TFSI)₂. The doped state is remarkably stable, retaining 80% of the initial value after annealing under nitrogen at 100 °C and being exposed to ambient atm. for up to 12 h. During doping, the hole injection barrier decreases and reaches an impressively low value of 130 meV at only 2.5 mol% dopant loading without loss in carrier mobility; as monitored using UV photoelectron- and impedance spectroscopy. This new design concept leading to highly soluble polymers with well-controlled mol. weights provides solution-processable PEDOT dopable in a well-controlled fashion. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.COA of Formula: C16H34O This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

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Recommanded Product: 2425-77-6《Exploration on varying patterns of morphological features and quality of armeniacae semen amarum in rancid process based on colorimeter, electronic nose, and GC/MS coupled with human panel》 was published in 2022. The authors were Shao, Yuanyang;Chen, Huirong;Lin, Hongxin;Feng, Huishang;Gong, Jianting;Cao, Guangzhao;Hong, Weifeng;Yao, Yuebao;Zou, Huiqin;Yan, Yonghong, and the article was included in《Frontiers in Pharmacology》. The author mentioned the following in the article:

In recent years, the domestic and international trade volumes of Chinese medicinal materials (CMMs) keep increasing. By the end of 2019, the total amount of exported CMMs reached as high as US $1.137 billion, while imported was US $2.155 billion. A stable and controllable quality system of CMMs apparently becomes the most important issue, which needs multifaceted collaboration from harvesting CMMs at a proper season to storing CMMs at a proper temperature However, due to imperfect storage conditions, different kinds of deteriorations are prone to occur, for instance, get moldy or rancid, which not only causes a huge waste of CMM resources but also poses a great threat to clin. medication safety and public health. The key issue is to quickly and accurately distinguish deteriorated CMM samples so as to avoid consuming low-quality or even harmful CMMs. However, some attention has been paid to study the changing quality of deteriorated CMMs and a suitable method for identifying them. In this study, as a medicine and food material which easily becomes rancid, armeniacae semen amarum (ASA) was chosen as a research objective, and exptl. ASA samples of different rancidness degrees were collected. Then, various kinds of anal. methods and technologies were applied to explore the changing rules of ASA quality and figure out the key indicators for the quality evaluation of ASA in the rancid process, including the human panel, colorimeter, electronic nose, and GC/MS. This study aims to analyze the correlation between the external morphol. features and the inner chem. compounds, to find out the specific components from ”quant. change” to ”qual. change” in the process of ”getting rancid,” and to discover the dynamic changes in the aforementioned key indicators at different stages of rancidness. The results showed since ASA samples began to get rancid with the extension of storage time, morphol. features, namely, surface color and smell, changed significantly, and the degree of rancidness further deepened at the same time. Based on macroscopic identification accomplished via the human panel, ASA samples with varying degrees of rancidness were divided into four groups. The result of colorimeter anal. was in agreement with that of the human panel, as well as the determination of the amygdalin content and peroxide value. Moreover, there were obvious differences in the amygdalin content and peroxide value among ASA samples with different rancidness degrees. With a higher degree of rancidness, the content of amygdalin decreased, while the peroxide value increased significantly. The rancidness degree of ASA has a neg. correlation with the amygdalin content and a pos. correlation with the peroxide value. The newly discovered nonanal and 2-bromopropiophenone in rancid ASA samples may be the key components of ”rancidity smell,” and these two components would be the exclusive components that trigger ”quant. change” to ”qual. change” in the process of rancidness of ASA. This study sheds light on studying the internal mechanism of ”rancidness” of CMMs and provides an important basis for the effective storage and safe medication of easy-to-get rancid herbs, and it also plays an important foundation for the establishment of a stable and controllable quality system for CMMs. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.Recommanded Product: 2425-77-6 This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

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Teshima, Yoshikazu;Saito, Masahiko;Mikie, Tsubasa;Komeyama, Kimihiro;Osaka, Itaru published 《Bithiazole Dicarboxylate Ester: An Easily Accessible Electron-Deficient Building Unit for π-Conjugated Polymers Enabling Electron Transport》 in 2021. The article was appeared in 《Macromolecules (Washington, DC, United States)》. They have made some progress in their research.Synthetic Route of C16H34O The article mentions the following:

Thiazole has been less focused, compared to thiophene, as the building unit for π-conjugated polymers that are used in organic electronic devices despite its electron deficiency and ability to coplanarize the polymer backbone, which are crucial for design of such π-conjugated polymers. Here, we show that bithiazole dicarboxylate ester (BETz), which is quite easily synthesized, is a promising building unit for π-conjugated polymers. Copolymers based on BETz, having unsubstituted bithiophene and bithiazole as counits, indeed form highly crystalline structures in thin films, which is beneficial for semiconducting properties. Of particular interest is that the BETz-based polymers are found to show electron-transport property even though the LUMO energy levels are not very low, as they show ambipolar and unipolar n-channel behaviors depending on the counit in organic transistor devices. We believe that BETz allows us to design a wide variety of π-conjugated polymers that provide fascinating functions in organic electronic devices. To complete the study, the researchers used 2-Hexyl-1-decanol (cas: 2425-77-6) .

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.Synthetic Route of C16H34O This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

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Formula: C16H34O《Strategic side-chain engineering approach for optimizing thermoelectric properties of isoindigo-based conjugated polymers》 was published in 2020. The authors were Yoon, Sang Eun;Shin, So Jeong;Lee, Sang Yeon;Jeon, Gyeong G.;Kang, Hyunwoo;Seo, Hyungtak;Zheng, Jian;Kim, Jong H., and the article was included in《ACS Applied Polymer Materials》. The author mentioned the following in the article:

Strategic side-chain engineering has led to an increase in the power factor of isoindigo-based conjugated polymers (CPs) by an order of magnitude. We investigated the effect of side chains on the elec. properties of doped isoindigo-based CPs and gained insight into structure-elec. property-thermoelec. transport intercorrelation for optimization of thermoelec. CPs. For this study, we designed and synthesized four isoindigo-based polymers having different types of alkyl chains. The size of the alkyl chains significantly affected the crystallinity of the films, which subsequently resulted in different charge carrier mobilities and diffusion efficiencies of the mol. dopant. Amorphous polymers with bulkier alkyl chains promoted efficient dopant diffusion while their carrier mobility was relatively lower than that of crystalline CPs. Systematic characterizations on the structural, elec., and thermoelec. properties of the CP films showed a trade-off effect for these side-chain structures for optimization of the thermoelec. effect, and with the optimized structure, we obtained a significantly improved power factor up to 37.8μW·m^-1·K^-2. This study suggests that exercising fine control of crystallinity through side-chain modification of the fixed polymer backbone can be a simple but very effective approach to maximizing organic thermoelec. effects of CPs. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.Formula: C16H34O This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

Reference:
Alcohol – Wikipedia,
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Li, Z. W.;Wang, J. H. published 《Analysis of volatile aroma compounds from five types of Fenghuang Dancong tea using headspace-solid phase microextraction combined with GC-MS and GC-olfactometry》 in 2021. The article was appeared in 《International Food Research Journal》. They have made some progress in their research.Application of 2425-77-6 The article mentions the following:

The present work describes the relationship between volatile aroma components and flavors of Fenghuang Dancong tea. Volatile aroma components of five types of Fenghuang Dancong tea namely Baxian, Milanxiang, Yulanxiang, Guihuaxiang, and Yinhuaxiang were extracted by headspace solid-phase microextraction (HS-SPME), then analyzed by gas chromatog.- mass spectrometry (GC-MS) technique and gas chromatog. olfactometry (GC-O) techniques. The GC-MS results showed that a total of 116 volatile components were detected, among which 21 (including alcs., esters, olefins, aldehydes, ketones, and alkanes) were commonly detected in all types of tea. Based on GC-O anal., 26 active ingredients that mainly contribute to grassy, sweet, floral, fruity, woody, and honey aromas were detected. Among these ingredients, four compounds including linalool oxide I, linalool, nerol, and neroli, which give floral, sweet, and honey aromas were abundant (with high aroma intensity) in all five types of tea. This suggests that these compounds are the main components contributing to the unique aroma of Fenghuang Dancong tea. The experimental procedure involved many compounds, such as 2-Hexyl-1-decanol (cas: 2425-77-6) .

2-Hexyl-1-decanol(cas: 2425-77-6) may be employed as an organic solvent to study the extraction of non-polar acidic drugs from human plasma by parallel artificial liquid membrane extraction (PALME). Application of 2425-77-6

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Wang, Yali;Yang, Lu;Zhang, Ke;Chen, Xiaoxiang;Wang, Hangyu;Cheng, Ping;Wang, Jinhui published 《Untargeted metabolomics analysis of different grape varieties and different parts of wine grape using gas chromatography and mass spectrometry technique》. The research results were published in《Journal of Biobased Materials and Bioenergy》 in 2021.Recommanded Product: 2425-77-6 The article conveys some information:

Natural active compounds are an important key to the development and utilization of functional foods and medicine. In this study, the chem. diversity and varietal differences of wine grape were studied by using the untargeted metabolomics method based on gas chromatog.-mass spectrometry (GC-MS), and the secondary metabolites of different cultivars and different parts were analyzed. A GC-MS-based metabolomic approach and chemometrics tools was used to identify potential active compounds in Vitis vinifera. The results showed that the content of active compounds in red wine varieties was higher than that in white wine varieties, and the content of active ingredients in grape seeds was significantly higher than that in fruits. In conclusion, this study analyzed the metabolite composition and differentiation of different wine grape fruits in Turpan as a whole, and is expected to lay a foundation for the study of wine grape and to provide a theor. basis for development and utilization of the Dietary supplement and medicine on them. The experimental procedure involved many compounds, such as 2-Hexyl-1-decanol (cas: 2425-77-6) .

2-Hexyl-1-decanol(cas: 2425-77-6) is a fatty acid that is found in the essential oils of plants and has been shown to have fungicidal properties.Recommanded Product: 2425-77-6 It has also been shown to inhibit the growth of Candida glabrata when used as a cationic surfactant.

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Seshasayee, Mahadevan Subramanya;Savage, Phillip E. published 《Oil from plastic via hydrothermal liquefaction: Production and characterization》 in 2020. The article was appeared in 《Applied Energy》. They have made some progress in their research.Application In Synthesis of 2-Hexyl-1-decanol The article mentions the following:

We determined the effect of batch holding time (0.5 h, 1 h) and temperature (350-450°C) on the yield, composition, and quality of oil formed from the hydrothermal treatment of polypropylene (PP), polystyrene (PS), polycarbonate (PC), and polyethylene terephthalate (PET). The highest oil yields for each material ranged from just 16 wt% for PET to 86 wt% for polystyrene. The depolymerization of plastics to produce oil occurs fastest in the supercritical water regime (T > 400°C). The higher heating value (HHV) of the oil from PP and PS (44-45 MJ/kg) is comparable to that of gasoline (HHV ∼ 43.4 MJ/kg). The oil from PC and PET had lower heating values but further treatment to remove oxygen atoms would increase the energy d. Increasing the hydrothermal reaction severity (longer times, higher supercritical temperatures) reduces oil yields but increases heating values. Increasing temperature causes more aromatization in the oil from PP and PS and promotes dehydration reactions during hydrothermal treatment of PET and PC. The oil from PC contained bisphenol-A as a major product. Obtaining such monomers from hydrothermal treatment would provide a revenue stream in addition to oil and thereby improve the process economics. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) is a fatty acid that is found in the essential oils of plants and has been shown to have fungicidal properties.Application In Synthesis of 2-Hexyl-1-decanol It has also been shown to inhibit the growth of Candida glabrata when used as a cationic surfactant.

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Alcohol – Wikipedia,
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Abednatanzi, Sara;Gohari Derakhshandeh, Parviz;Tack, Pieter;Muniz-Miranda, Francesco;Liu, Ying-Ya;Everaert, Jonas;Meledina, Maria;Vanden Bussche, Flore;Vincze, Laszlo;Stevens, Christian V.;Van Speybroeck, Veronique;Vrielinck, Henk;Callens, Freddy;Leus, Karen;Van Der Voort, Pascal published 《Elucidating the promotional effect of a covalent triazine framework in aerobic oxidation》 in 2020. The article was appeared in 《Applied Catalysis, B: Environmental》. They have made some progress in their research.Recommanded Product: 2425-77-6 The article mentions the following:

Synergistic catalysis holds great promise to enhance the catalytic performance of heterogeneous catalysts suffering from sluggish reaction kinetics. Much effort has been dedicated to the development of bimetallic systems in which the two promoter elements display synergistic benefits compared to monometallic counterparts. However, the use of bimetallic catalysts inescapably raises the cost of preparation and environmental issues. This study discovers a synergistic effect when using a bipyridine covalent triazine framework (bipy-CTF) as support for an Ir^III complex in the aerobic oxidation reaction. The detailed mechanistic study provides insights into the function of the bipy-CTF in this synergistic catalysis. The EPR and in-situ XANES analyses confirm the applicability of bipy-CTF to activate oxygen and alc., resulting in an enhancement of the performance of the Ir^III complex to exceed the activity of the homogeneous counterpart. This is an unprecedented report on promoting the activity of a heterogeneous catalyst through its solid support.2-Hexyl-1-decanol (cas: 2425-77-6) were involved in the experimental procedure.

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.Recommanded Product: 2425-77-6 This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Paradiz Dominguez, Maximilian;Demirkurt, Beguem;Grzelka, Marion;Bonn, Daniel;Galmiche, Laurent;Audebert, Pierre;Brouwer, Albert M. published 《Fluorescent Liquid Tetrazines》 in 2021. The article was appeared in 《Molecules》. They have made some progress in their research.Synthetic Route of C16H34O The article mentions the following:

Tetrazines with branched alkoxy substituents are liquids at ambient temperature that despite the high chromophore d. retain the bright orange fluorescence that is characteristic of this exceptional fluorophore. Here, we study the photophys. properties of a series of alkoxy-tetrazines in solution and as neat liquids We also correlate the size of the alkoxy substituents with the viscosity of the liquids We show using time-resolved spectroscopy that intersystem crossing is an important decay pathway competing with fluorescence, and that its rate is higher for 3,6-dialkoxy derivatives than for 3-chloro-6-alkoxytetrazines, explaining the higher fluorescence quantum yields for the latter. Quantum chem. calculations suggest that the difference in rate is due to the activation energy required to distort the tetrazine core such that the nπ*S₁ and the higher-lying ππ*T₂ states cross, at which point the spin-orbit coupling exceeding 10 cm^-1 allows for efficient intersystem crossing to occur. Femtosecond time-resolved anisotropy studies in solution allow us to measure a pos. relationship between the alkoxy chain lengths and their rotational correlation times, and studies in the neat liquids show a fast decay of the anisotropy consistent with fast exciton migration in the neat liquid films. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) has been shown to inhibit the growth of b16 mouse melanoma cells, suggesting it may be useful for treating skin cancer.Synthetic Route of C16H34O This fatty acid also has transport properties and can form hydrogen bonds with other molecules.

Reference:
Alcohol – Wikipedia,
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Reference of 2-Hexyl-1-decanolIn 2020, Temerdashev, Z. A.;Milevskaya, V. V.;Ryabokon’, L. P.;Latin, N. N.;Kiseleva, N. V.;Nagalevskii, M. V. published 《Identification and Determination of the Components of Garden Sage (Salvia officinalis L.) Essential Oil, Isolated by Different Extraction Methods》. 《Journal of Analytical Chemistry》published the findings. The article contains the following contents:

We studied the component composition of the essential oil of garden sage (Salvia officinalis L.), obtained by various extraction methods. Essential oils were obtained by hydrodistillation and subcritical CO2 extraction, supercritical fluid extraction, and subcritical extraction with solid-phase and liquid-liquid preconcentration The components were identified by comparing the recorded mass spectra with the spectra of individual compounds and the data of the NIST07 and WILEY8 data bases. For all extraction methods, the major essential oil components were 1,8-cineole, camphor, α-thujone, β-thujone, borneol, 4-terpineol, β-caryophyllene, β-caryophyllene oxide, and viridiflorol. The concentration of analytes in the extracts varied depending on the extraction method. In total, 104 components were identified in the extracts, of which 30 were extracted by hydrodistillation, 32 by subcritical CO2 extraction, 14 by supercritical fluid extraction, 46 and 62 by subcritical extraction with solid-phase and liquid-liquid extraction into the organic phase. An increase in the number of components in more stringent extraction methods as compared to hydrodistillation showed that, in the extracts, a deeper decomposition of macrocomponents might take place, except for camphor. And 2-Hexyl-1-decanol (cas: 2425-77-6) was used in the research process.

2-Hexyl-1-decanol(cas: 2425-77-6) is a branched alcohol. It is one of the constituent of the essential oil, extracted from the roots of Adiantum flabellulatum. Reference of 2-Hexyl-1-decanol

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