Category: 143-10-2

On May 1, 2020, Welearegay, Tesfalem Geremariam; Duran-Acevedo, Cristhian Manuel; Jaimes-Mogollon, Aylen Lisset; Pugliese, Giovanni; Ionescu, Florina; Perez-Ortiz, Omar Geovanny; Gualdron-Guerrero, Oscar Eduardo; Cindemir, Umut; Oesterlund, Lars; Ionescu, Radu published an article.Application In Synthesis of 1-Decanethiol The title of the article was Exhaled air analysis as a potential fast method for early diagnosis of dengue disease. And the article contained the following:

Dengue is a neglected tropical disease caused by arbovirus. Every year 390 million persons are infected with dengue, of which 96 million manifest clin. around the world, mainly in the Latin America, South-East Asia and Western Pacific. The disease manifests itself as a flu-like infection that generally is difficult to recognize from a normal flu or other viral infections. The mortality rate is around 20% for the severe form of dengue, which readily could be decreased to below 1% with early, reliable diagnostic tools. Today there exist however no diagnostic tests for the early and rapid diagnosis of this disease. In this study, we report for the first time the possibility of identification of possible biomarkers associated with dengue disease in the exhaled air, and of the development of a breath test for fast, non-invasive and easy diagnosis of this disease. Further, we demonstrate a new deployable sensor technol. based on a chemoresistive metal-ligand nanoassembly tailored for the identified possible biomarkers of dengue disease, which achieved 100% accuracy for dengue diagnosis on our study group and can be used in both specialist and non-specialist settings. Nevertheless, as the present study was performed on a limited number of patients because of the difficulty to recruit a high number of patients because dengue is a neglected disease, future validation tests on a higher cohort are necessary for corroborating the results obtained in the present study. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol

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On August 23, 2022, Tsvetanova, Martina; Syromyatnikov, Alexey G.; van der Meer, Thomas; van Houselt, Arie; Zandvliet, Harold J. W.; Klavsyuk, Andrey L.; Sotthewes, Kai published an article.Electric Literature of 143-10-2 The title of the article was Self-assembled decanethiolate monolayers on Au(001): Expanding family of known phases. And the article contained the following:

We have studied decanethiolate self-assembled monolayers on the Au(001) surface. Planar and striped phases, as well as disordered regions, have formed after exposing the Au surface to a decanethiol solution The planar phases that we observe have a hexagonal symmetry and have not been previously reported for thiols on the Au(001) surface and have lower coverage compared to that of the other known thiol planar phases such as the square α phase. The striped phases that we observe are similar to the previously reported β phase but still feature unit cells that cannot be modeled as the archetype, and the coverage is also somewhat lower. The disordered decanethiolate regions are more dynamic compared to the ordered phases, confirmed with I(t) spectroscopy. This suggests that in these regions the coverage is too low in order to form ordered decanethiolate phases. Our findings contribute to the growing family of possible decanethiol formations on the Au(001) surface, for which still less is known compared to the extensive overview present for the Au(111) surface. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Electric Literature of 143-10-2

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On June 1, 2020, Mukherjee, Manjistha; Dey, Abhishek published an article.Recommanded Product: 143-10-2 The title of the article was Catalytic C-H Bond Oxidation Using Dioxygen by Analogues of Heme Superoxide. And the article contained the following:

Heme active sites are capable of oxidizing organic substrates by four electrons using mol. oxygen (heme dioxygenases), where a dioxygen (O2) adduct of heme (FeIII-O2•-) acts as the primary oxidant, in contrast to monooxygenases, where high-valent species are involved. This chem., although lucrative, is difficult to access using homogeneous synthetic systems. Over the past few years using a combination of self-assembly and in situ resonance Raman spectroscopy, the distribution of different reactive intermediates formed during the electrochem. reduction of oxygen has been elucidated. An FeIII-O2•- species, which is the reactive species of dioxygenase, is an intermediate in heterogeneous electrochem. O2 reduction by iron porphyrins and its population, under electrochem. conditions, may be controlled by controlling the applied potential. Iron porphyrins having different axial ligands are constructed on a self-assembled monolayer of thiols on an electrode, and these constructs can activate O2 and efficiently catalyze the dioxygenation of 3-methylindole and oxidation of a series of organic compounds having C-H bond energies between 80 and 90 kcal mol-1 at potentials where FeIII-O2•- species are formed on the electrode. Isotope effects suggest that hydrogen-atom transfer from the substrate is likely to be the rate-determining step. Axial thiolate ligands are found to be more efficient than axial imidazoles or phenolates with turnover numbers above 60000 and turnover frequencies over 60 s-1. These results highlight a new reaction engineering approach to harness O2 as a green oxidant for efficient chem. oxidation Four-electron oxidation of a substrate by oxygen catalyzed by iron porphyrins. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Recommanded Product: 143-10-2

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On December 8, 2020, Markovic, Aleksandra; Buschbeck, Leon; Brand, Izabella; Dosche, Carsten; Christoffers, Jens; Wittstock, Gunther published an article.Formula: C10H22S The title of the article was Electrochemical Activation of Self-Assembled Monolayers for the Binding of Effectors. And the article contained the following:

A self-assembled monolayer (SAM) on Au was prepared from a diaminoterephthalate (DAT) derivative as functional mol. and 1-decanthiol as a backfiller. The DAT derivative is N-protected by a tert-butyloxycarbonyl (Boc) group and is anchored to the Au surface via a liponic acid as a stable anchor group. The terminal DAT moiety exhibits interesting effector properties such as fluorescence and electrochem. activity. Irreversible oxidation of the monolayer at 0.4 V (Hg|Hg2SO4) in 0.1M HClO4 triggers deprotection of the DAT group and subsequent chem. reactions, during which 10% of the DAT groups of the original SAM are transformed to a new surface-bound, quasi-reversible redox couple with a formal potential of 0.0 V (Hg|Hg2SO4) and a standard rate constant of 8 s-1 in 0.1M HClO4. Immersion of the mixed SAM in 0.1M HClO4 at open circuit potential or oxidation in 0.1M H2SO4 did not produce this surface-bound redox couple. The monolayers were thoroughly characterized by XPS and polarization modulation IR reflection absorption spectroscopy (PM IRRAS) after the different preparation steps indicating only minor changes in the overall composition of the monolayer, in particular, the preservation of the heteroatoms. The new redox couple is likely a diimine, in agreement with its ability to bind nucleophiles such as anilines by conjugate addition that could be followed by multicycle voltammetry and XPS. The DAT effector group is especially interesting because it can also report the binding reaction by changed electrochem. and fluorescence signals. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Formula: C10H22S

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da Camara, Bryce; Dietz, Philip C.; Chalek, Kevin R.; Mueller, Leonard J.; Hooley, Richard J. published an article in 2020, the title of the article was Selective, cofactor-mediated catalytic oxidation of alkanethiols in a self-assembled cage host.Electric Literature of 143-10-2 And the article contains the following content:

A spacious Fe(II)-iminopyridine self-assembled cage complex can catalyze the oxidative dimerization of alkanethiols, with air as stoichiometric oxidant. The reaction is aided by selective mol. recognition of the reactants, and the active catalyst is derived from the Fe(II) centers that provide the structural vertices of the host. The host is even capable of size-selective oxidation and can discriminate between alkanethiols of identical reactivity, based solely on size. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Electric Literature of 143-10-2

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On July 31, 2020, Bonegardt, Dmitry; Klyamer, Darya; Koksoy, Baybars; Durmus, Mahmut; Basova, Tamara published an article.Application In Synthesis of 1-Decanethiol The title of the article was Hybrid materials of carbon nanotubes with fluoroalkyl- and alkyl-substituted zinc phthalocyanines. And the article contained the following:

In this work, hybrid materials of single-walled carbon nanotubes (SWCNT) noncovalently functionalized with fluoroalkyl- (SWCNT/ZnPc-CF) and alkyl- (SWCNT/ZnPc-CH) substituted zinc(II) phthalocyanines were prepared The effect of fluorination of the substituents in phthalocyanine macrocycle on the functionalization degree of carbon nanotubes and sensor response to ammonia was investigated. It was shown that the type of substituents in the phthalocyanine macrocycle showed noticeable effect both on the degree of functionalization of carbon nanotubes and on the sensing performance of the investigated hybrids. The amount of phthalocyanine mols. adsorbed on SWCNT walls was shown to be 1.5 times higher in the SWCNT/ZnPc-CH hybrid. The SWCNT/ZnPc-CF layer exhibited 2 times less chemiresistive sensor response to ammonia than SWCNT/ZnPc-CH, while its sensor response was more stable at 70% relative humidity. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol

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On June 4, 2021, Wang, Sheng; Yu, Jiahao; Ye, Haiqiao; Chi, Mingbo; Yang, Heng; Wang, Haihui; Cao, Fan; Li, Wenqiang; Kong, Lingmei; Wang, Lin; Chen, Rui; Yang, Xuyong published an article.Reference of 1-Decanethiol The title of the article was Low-Threshold Amplified Spontaneous Emission in Blue Quantum Dots Enabled by Effectively Suppressing Auger Recombination. And the article contained the following:

The amplified spontaneous emissions in blue quantum dots (QDs) are still constrained by their high thresholds due to the challenge in engineering alloyed core-shell interface in the QDs with a wide bandgap to suppress Auger recombination. Compared with their red and green counterparts, the larger reactivity difference between the alloyed shell precursors makes it hard to regulate the composition and structure of the shell, and the smaller potential barrier between the core and the alloyed shell in blue QDs renders charge carriers tunneling into surface defects easier. Here, we employ a Lewis soft base ligand, 1-decanethiol, to balance the mismatched reactivity between Zn and Cd precursors for crafting a thick gradient alloyed shell with gradually increased potential barrier, which can not only restrict the charge carriers tunneling but also smooth the confinement potential. As a result, the resulting blue QDs show a long Auger lifetime of 1.3 ns, and a low threshold of 6.9 μJ cm-2 excited by a femtosecond laser, which is the record value among all reported blue-emitting nanocrystals and comparable to those of state-of-the-art red and green QDs. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Reference of 1-Decanethiol

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On April 30, 2022, Yu, Yi; Jiang, Yimin; Wu, Shaofen; Shi, Zhaojiang; Wu, Jinnan; Yuan, Yaofeng; Ye, Keyin published an article.Application In Synthesis of 1-Decanethiol The title of the article was Electrochemistry enabled selective vicinal fluorosulfenylation and fluorosulfoxidation of alkenes. And the article contained the following:

Both sulfur and fluorine play important roles in organic synthesis, the life science, and materials science. The direct incorporation of these elements into organic scaffolds with precise control of the oxidation states of sulfur moieties is of great significance. Herein, we report the highly selective electrochem. vicinal fluorosulfenylation and fluorosulfoxidn. reactions of alkenes, which were enabled by the unique ability of electrochem. to dial in the potentials on demand. Preliminary mechanistic investigations revealed that the fluorosulfenylation reaction proceeded through a radical-polar crossover mechanism involving a key episulfonium ion intermediate. Subsequent electrochem. oxidation of fluorosulfides to fluorosulfoxides were readily achieved under a higher applied potential with the adventitious H2O in the reaction mixture The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application In Synthesis of 1-Decanethiol

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Yang, Xiuxiu; Li, Haiyu; Zhao, Xiaofang; Liao, Wei; Zhang, Claire Xi; Yang, Zhongqiang published an article in 2020, the title of the article was A novel, label-free liquid crystal biosensor for Parkinson′s disease related alpha-synuclein.Application of 143-10-2 And the article contains the following content:

A liquid crystal biosensor based on DNA aptamer for sensitive detection of Parkinson′s Disease (PD) related alpha-synuclein was developed. This LC biosensor is constructed using a simple and label free method, and it not only enables early PD diagnosis, but also provides a general platform for detection based on DNA aptamer. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Application of 143-10-2

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Liu, Jiaming; Liu, Rongjuan; Yang, Zhijie; Wei, Jingjing published an article in 2022, the title of the article was Folding of two-dimensional nanoparticle superlattices enabled by emulsion-confined supramolecular co-assembly.Synthetic Route of 143-10-2 And the article contains the following content:

Folding of two-dimensional nanoparticle superlattices is achieved through templated assembly on as-formed supramol. nanosheets, which undergo a folding process within the emulsion droplets during the evaporation of the inner phase liquid Building the folded nanoparticle superlattices opens a new gateway to reshape the properties of inorganic solids. The experimental process involved the reaction of 1-Decanethiol(cas: 143-10-2).Synthetic Route of 143-10-2

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