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Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 13826-35-2, Name is (3-Phenoxyphenyl)methanol, molecular formula is C13H12O2, belongs to alcohols-buliding-blocks compound, is a common compound. In a patnet, author is Khmelinskii, Igor, once mentioned the new application about 13826-35-2, Application In Synthesis of (3-Phenoxyphenyl)methanol.

Energy transfer along Muller cell intermediate filaments isolated from porcine retina: I. Excitons produced by ADH1A dimers upon simultaneous hydrolysis of two ATP molecules

IR exciton propagation was explored in Muller cell (MC) intermediate filaments (IFs) filling a capillary matrix. These IFs have been isolated from porcine retina using different methods, while their properties were almost identical. Therefore, IFs isolated from the whole retinas were used presently. IR excitons were generated by IR radiation at 2 lm wavelength, or by enzymatic ATP hydrolysis, with the energy transferred to IFs. Excitons produced by ATP hydrolysis required simultaneous energy contribution of two ATP molecules, indicating simultaneous hydrolysis of two ATP molecules in the naturally dimeric human alcohol dehydrogenase enzyme (ADH1A). ATP hydrolysis was thus catalyzed by ADH1A center dot center dot center dot NAD+ enzymatic complexes absorbed at the IF extremities protruding out of the capillary matrix. The IR emission spectra of excitons were dependent on the exciton generation method. We believe this resulted from the exciton energy distribution varying in function of the generation method used. The latter seems reasonable, given the very long excited-state lifetimes, implying low nonradiative relaxation rates. The energy liberated by ATP hydrolysis has been measured directly in these experiments, for the first time. The results demonstrate that contrary to the predictions of equilibrium thermodynamics, the liberated energy is independent on the ATP/ADP concentration ratio, indicating that non-equilibrium reactions take place. Time-resolved experiments with excitons produced by pulsed IR radiation evaluated characteristic exciton propagation and emission times. For the first time, biexcitonic processes were observed in biological objects, whereby simultaneous hydrolysis of two ATP molecules bound to the same dimeric ADH1A molecule generated excitons carrying twice the energy liberated by hydrolysis of a single ATP molecule. The results reported indicate that ATP-liberated energy may be transmitted along natural polypeptide nanofibers in vivo, within and between live cells. These ideas could promote new understanding of the biophysics of life. Published by Elsevier B.V.

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Estimating person-to-person variability in VOC emissions from personal care products used during showering

An increasing fraction of volatile organic compounds (VOC) emissions come from the domestic use of solvents, contained within myriad commonplace consumer products. Emission rates are often poorly characterized and depend significantly on individual behavior and specific product formulation and usage. Time-concentration profiles of volatile organic compounds (VOCs) arising from the use of a representative selection of personal care products (PCPs) during showering are generated, and person-to-person variability in emissions calculated. A panel of 18 participants used a standardized set of products, dosages, and application times during showering in a controlled indoor bathroom setting. Proton transfer mass spectrometry was used to measure the in-room VOC evolution of limonene (representing the sum of monoterpenes), benzyl alcohol, and ethanol. The release of VOCs had reproducible patterns between users, but noticeable variations in absolute peak concentrations, despite identical amounts of material being used. The amounts of VOC emitted to air for one showering activity were as follows: limonene (1.77 mg +/- 42%), benzyl alcohol (1.07 mg +/- 41%), and ethanol (0.33 mg +/- 78%). Real-world emissions to air were between 1.3 and 11 times lower than bottom-up estimates based on dynamic headspace measurements of product emissions rates, likely a result of PCPs being washed away before VOC evaporation could occur.

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Chemistry is the science of change. But why do chemical reactions take place? Why do chemicals react with each other? The answer is in thermodynamics and kinetics, HPLC of Formula: C13H12O2, 13826-35-2, Name is (3-Phenoxyphenyl)methanol, SMILES is OCC1=CC(OC2=CC=CC=C2)=CC=C1, belongs to alcohols-buliding-blocks compound. In a document, author is Hajavazzade, Reza, introduce the new discover.

Synthesis and characterization of Mg1(-x)Ni(x)Al(2)O(4) and their photocatalytic behaviors towards Congo red under UV light irradiation

In this paper, MgAl2O4 nanoparticles were synthesized by the Sol-gel auto combustion method and were doped with different concentrations of Ni2+ (x= 0, 0.1, 0.05, and 0.03). By this method, a novel photocatalyst which had better decolorization percentages of Congo red(compared) to MgAl2O4 was produced. The MgAl2O4 samples were calcinated at 1000 degrees C. The samples obtained were characterized by X-ray diffraction (XRD), SEM, FT-IR, EDX, and ICP-AES. The photocatalytic activity of MgAl2O4 samples were evaluated by UV-Vis spectroscopy and diffuse reflectance spectra (DRS) to confirm the performance rate of the photocatalyst. Also, the photocatalytic properties were investigated in the presence of UV light, certain amounts of photocatalysts, and Congo red dye. The best- obtained results of the photocatalytic activity among the prepared samples were Mg0.9Ni0.1Al2O4 because this photocatalyst had a removal conversion of 99.3 % of the dye after 90 min, which was better than other photocatalysts in similar conditions. Mg0.9Ni0.1Al2O4 was used as a photocatalyst five successfully times without any changes or loss of its high photocatalytic activity for this process. In this project, we used Ni2+ to dope MgAl2O4 nanoparticles. The results decolorization percentages of Congo red showed that Mg0.9Ni0.1Al2O4 had better efficiency compared to MgAl2O4, (and other) photocatalysts.

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Chemistry is traditionally divided into organic and inorganic chemistry. The former is the study of compounds containing at least one carbon-hydrogen bonds. 13826-35-2, Name is (3-Phenoxyphenyl)methanol, molecular formula is C13H12O2, belongs to alcohols-buliding-blocks compound, is a common compound. In a patnet, author is Bharath, G., once mentioned the new application about 13826-35-2, Safety of (3-Phenoxyphenyl)methanol.

High-performance and stable Ru-Pd nanosphere catalyst supported on two-dimensional boron nitride nanosheets for the hydrogenation of furfural via water-mediated protonation

Bimetallic Ru-Pd catalysts are increasingly being investigated for applications in the upgrading of bio-oils to biofuels, owing to their high catalytic activities. Similarly, the recent development of Ru-Pd alloyed nanoparticle (NP) incorporated into hexagonal boron nitride (h-BN) catalysts that can be utilized for tuning the selectivity of desired products has also received considerable attention. In the present study, nanoclusters of Ru-0-Pd-0 that self-assemble into spherical-like Ru-Pd bimetallic catalytic sites were successfully grown on the surfaces of BN nanosheets (Ru-Pd/BN NCs) via microwave irradiation for 30 s. HR-TEM investigations revealed the formation of 25 nm sized Ru-Pd nanoparticles comprising <= 2 nm hexagonal closed-pack (hcp) Ru-Pd clusters with Ru crystallites on the BN nanosheets. Further, furfural was effectively converted into furfural alcohol at a lower temperature (150 degrees C) and valuable cyclopentanone was obtained at a higher temperature (>250 degrees C) over the RuPd/BN catalyst through the protonation of water molecules. Furthermore, various solvents namely 2-propanol, toluene, and cyclohexane were also used to achieve the production of furan and tetrahydrofuran over the Ru-Pd/BN catalyst via the decarbonylation of furfural under mild reaction conditions. Moreover, for real-time upgrading, furfural-rich bio-oil produced by the pyrolysis of date-tree biomass was processed over the Ru-Pd/BN catalyst to obtain a maximum of 97% furfural conversion with a 71% FFA yield at 150 degrees C. The stability and reusability of the catalyst were also determined. The results demonstrated that the Ru-Pd/BN catalyst is highly active and chemically stable, and is therefore suitable for industrial applications.

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Deciphering the succession patterns of bacterial community and their correlations with environmental factors and flavor compounds during the fermentation of Zhejiang rosy vinegar

Zhejiang Rosy Vinegar (ZRV) is a traditional condiment in Southeast China, produced using semi-solid-state fermentation techniques under an open environment, yet little is known about the functional microbiota involved in the flavor formation of ZRV. In this study, 43 kinds of volatile flavor substances were identified by HS-SPME/GC-MS, mainly including ethyl acetate (relative content at the end of fermentation: 1104.1 mg/L), phenylethyl alcohol (417.6 mg/L) and acetoin (605.2 mg/L). The most abundant organic acid was acetic acid (59.6 g/L), which kept rising during the fermentation, followed by lactic acid (7.0 g/L), which showed a continuously downward trend. Amplicon sequencing analysis revealed that the richness and diversity of bacterial community were the highest at the beginning and then maintained decreasing during the fermentation. The predominant bacteria were scattered in Acetobacter (average relative abundance: 63.7%) and Lactobacillus (19.8%). Both sequencing and culture-dependent analysis showed Lactobacillus dominated the early stage (day 10 to 30), and Acetobacter kept highly abundant from day 40 to the end. Spearman correlation analysis displayed that the potential major groups involved in the formation of flavor compounds were Acetobacter and Lactobacillus, which were also showed strong relationships with other bacteria through co-occurrence network analysis (edges attached to Acetobacter: 61.7%; Lactobacillus: 14.0%). Moreover, structural equation model showed that the contents of ethanol, titratable acid and reducing sugar were the major environmental factors playing essential roles in influencing the succession of bacterial community and their metabolism during the fermentation. Overall, these findings illuminated the dynamic profiles of bacterial community and flavor compounds and the potential functional microbes, which were expected to help us understand the formation of flavor substances in ZRV.

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Elevated Lithium Ion Regulation by a Natural Silk Modified Separator for High-Performance Lithium Metal Anode

Metallic lithium anode has long stood as the holy grail in the field of secondary batteries for its high theoretical specific capacity and low electrochemical potential. But its edge is blunted by the inherent uncontrolled lithium dendrite growth that can curtail the cycle life and raise safety concerns. In this work, a functional modification layer from a derivant of natural silk is developed to protect lithium anode via a facile automatic transfer route. Via offering abundant functional group sites, the Li-ion flux on the anode surface is made uniform efficiently. The silk fibroin-based modification layer also contributes to the in situ formation of a Li3N-rich solid electrolyte interphase film on the lithium anode. Consequently, a high-performance lithium metal anode with dendrite-free morphology and significantly enhanced cycle stability is achieved: when paired with LiFePO4 cathodes, the full cell achieves a long-term cycling stability of 3000 cycles at 5 C; when paired with sulfur cathodes (5 mg(sulfur) cm(-2)), a long lifespan for over 400 cycles at 1 C is achieved. This work offers a facile and practical approach for the interface modification of the high-performance lithium anode and as well as provides a new perspective for the application of biomass-based materials in advanced batteries.

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Chemistry is the experimental and theoretical study of materials on their properties at both the macroscopic and microscopic levels. 13826-35-2, Name is (3-Phenoxyphenyl)methanol, molecular formula is C13H12O2. In an article, author is Herle, Bart,once mentioned of 13826-35-2, Category: alcohols-buliding-blocks.

Total Synthesis of Mycinolide IV and Path-Scouting for Aldgamycin N

Proof-of-concept is provided that a large estate of 16-membered macrolide antibiotics can be reached by a unified approach. The key building block was formed on scale by an asymmetric vinylogous Mukaiyama aldol reaction; its alkene terminus was then converted either into the corresponding methyl ketone by Wacker oxidation or into a chain-extended aldehyde by catalyst-controlled branch-selective asymmetric hydroformylation. These transformations ultimately opened access to two structurally distinct series of macrolide targets. Notable late-stage maneuvers comprise a rare example of a ruthenium-catalyzed redox isomerization of an 1,3-enyne-5-ol into a 1,3-diene-5-one derivative, as well as the elaboration of a tertiary propargylic alcohol into an acyloin by trans-hydrostannation/Chan-Lam-type coupling. Moreover, this case study illustrates the underutilized possibility of forging complex macrolactone rings by transesterification under essentially neutral conditions.

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The important role of C13H12O2

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Let¡¯s face it, organic chemistry can seem difficult to learn. Especially from a beginner¡¯s point of view. Like 13826-35-2, Name is (3-Phenoxyphenyl)methanol. In a document, author is Kojcinovic, Aleksa, introducing its new discovery. HPLC of Formula: C13H12O2.

Furfural hydrogenation, hydrodeoxygenation and etherification over MoO2 and MoO3: A combined experimental and theoretical study

Valorization of lignocellulosic biomass, particularly catalytic hydrotreatment of hemicellulose-based furfural (FUR), has been studied for the production of value-added chemicals. A three-phase batch reactor has been used for hydrotreatment in isopropanol over various commercially available unsupported MoOx catalysts, at various temperatures (170-230 degrees C), pressures (0-80 bar H-2), catalyst loadings (0-2 wt%), and reactant concentrations (5-20 wt%). No significant difference in catalytic activity or selectivity has been observed among the three different MoO3 and one MoO2 catalysts, while NiMo/Al2O3, Mo2C and WO3 were much less active. Data-points collected have been used to propose a detailed reaction pathway network for a micro-kinetic model, which also took into consideration the thermodynamics, and adsorption, desorption, and surface reaction kinetics. The alcoholysis of FUR yielded valuable isopropyl levulinate (IPL) as the major product under all tested reaction conditions, while other value-added compounds (furfuryl alcohol, isopropyl furfuryl ether, furfuryl acetone, angelica lactone) were observed in smaller quantities. It was found that neither the presence nor the absence of the gaseous H-2 pressure contributes to the global reaction rate, or selectivity, since the solvent acts as a sufficient hydrogen donor. Additionally, density functional theory (DFT) calculations provided further insight into the active planes present by the implementation of the Wulff construction. Furthermore, the reaction mechanism was explained based on reaction energies, which were in silico determined and compared for several surfaces. The results were consistent with the characterization and activity-testing results. The furfural ring-opening reaction, yielding valuable IPL in the absence of gaseous H-2, over a cheap bulk MoOx is reported for the first time.

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The Absolute Best Science Experiment for (3-Phenoxyphenyl)methanol

Note that a catalyst decreases the activation energy for both the forward and the reverse reactions and hence accelerates both the forward and the reverse reactions. you can also check out more blogs about 13826-35-2. Category: alcohols-buliding-blocks.

Children learn through play, and they learn more than adults might expect. Science experiments are a great way to spark their curiosity, Category: alcohols-buliding-blocks13826-35-2, Name is (3-Phenoxyphenyl)methanol, SMILES is OCC1=CC(OC2=CC=CC=C2)=CC=C1, belongs to alcohols-buliding-blocks compound. In a article, author is Hinostroza Ballon, Alvaro Jaime, introduce new discover of the category.

Parenting practices and neighborhoods in adolescents: a comparative study at the level of psychosocial risk

The present study is carried out with the purpose of describing and comparing the results between 85 adolescents who reside in an area considered to be of high psychosocial risk in the city of Callao (Peru) with a group of 82 adolescents with similar sociodemographic characteristics who reside in an area not considered to be of high psychosocial risk of the same jurisdiction. The methodology is descriptive – comparative and has a non-experimental, cross-sectional design. In this case, the Escala de Afecto and the Escala de Normas y Exigencias and the Escala de Violencia en el Barrio were used. The results allow us to establish that adolescents in a zone of high psychosocial risk express, from their perception, that their parents prioritize affection, interest and communication, and they attribute this practice especially to the materna object. Similarly, they also refer, that their parents resort to dialog when they must monitor or demand compliance with their limits; however, compared to the control group, they evaluate their parents more authoritatively.

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Synthetic Route of 13826-35-2, The transformation of simple hydrocarbons into more complex and valuable products via catalytic C¨CH bond functionalisation has revolutionised modern synthetic chemistry. 13826-35-2, Name is (3-Phenoxyphenyl)methanol, SMILES is OCC1=CC(OC2=CC=CC=C2)=CC=C1, belongs to alcohols-buliding-blocks compound. In a article, author is Jimenez-Murcia, Susana, introduce new discover of the category.

Gambling disorder seeking treatment patients and tobacco use in relation to clinical profiles

Objectives: Tobacco smoking and gambling disorder (GD) often co-occur. However, few studies have assessed the extent to which cigarette smoking may serve to classify and/or better define GD behaviour profiles. Methods: Among a large sample of n = 3,652 consecutive treatment-seeking patients with GD (91% men). Smokers were compared to non-smokers across different sociodemographic, clinical, psychopathological and personality variables. The effect sizes for the means and the proportion differences between the groups were estimated. An evaluation of the smoking changes over the last 15 years was also performed. Results: From the total sample, 62.4% of gamblers reported tobacco use. A decreasing linear trend in tobacco use was observed within the studied period, women having a more irregular pattern. The use of tobacco was linked to the use of alcohol and other illegal drugs. Gamblers who smoke, as compared to those who don’t, presented lower education levels, lower social position indexes and active employment. They were younger, with an earlier age of onset, shorter duration of the gambling behavior, higher GD severity, more psychological symptoms, higher scores in novelty seeking and lower scores in reward dependence, self-directedness and self-transcendence. Conclusions: Gamblers seeking treatment who smoke display particular social, clinical, psychological, temperamental and character features different from non-smoking gamblers, suggesting that the presence or absence of comorbid smoking condition in GD should always be considered when developing an optimal treatment, as gamblers who smoke might need treatment strategies different from non-smoking gamblers.

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