Category: 12080-32-9

Puttock, Emma V.; Sturala, Jiri; Kistemaker, Jos C. M.; Williams, J. A. Gareth published an article about the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9,SMILESS:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-] ).Reference of Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:12080-32-9) through the article.

Five Pt(II) complexes are described in which the metal ion is bound to anionic N N N-coordinating ligands. The central, deprotonated N atom is derived from an imide Ar-C(:O)-NH-C(:O)-Ar {PtL1-2Cl; Ar = pyridine or pyrimidine}, an amide py-C(:O)-NH-CH2-py {PtL3Cl}, or a hydrazide py-C(:O)-NH-N:CH-py {PtL4Cl}. The imide complexes PtL1-2Cl show no significant emission in solution but are modestly bright green/yellow phosphors in the solid state. PtL3Cl is weakly phosphorescent. PtL4Cl is formed as a mixture of isomers, bound through either the amido or imino nitrogen, the latter converting to the former upon absorption of light. Remarkably, the imino form displays fluorescence in solution, λ0,0=535 nm, whereas the amido shows phosphorescence, λ0,0=624 nm, τ=440 ns. It is highly unusual for two isomeric compounds to display emission from states of different spin multiplicity. The amido-bound PtL4Cl can act as a bidentate O N-coordinating ligand, demonstrated by the formation of bimetallic complexes with iridium(III) or ruthenium(II).

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Reference of Dichloro(1,5-cyclooctadiene)platinum(II), illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Category: alcohols-buliding-blocks. The mechanism of aromatic electrophilic substitution of aromatic heterocycles is consistent with that of benzene. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Sterically Encumbered 4,5-Bis(diphenylphosphino)acenaphthene Ligand and Its Ni(II), Pd(II), Pt(II), and Cu(I) Complexes. Author is Tosolini, Massimo; Avo, Joao; Parola, Antonio Jorge; Balducci, Gabriele; Tecilla, Paolo.

A new sterically encumbered sym. substituted 4,5-bis(diphenylphosphino)acenaphthene ligand (L) has been prepared The ligand readily forms distorted square-planar complexes with group 10 metal ions [Ni(II), Pd(II), Pt(II)] and a dimeric tetrahedral complex with Cu(I). The x-ray structures of the ligand and of the complexes show a notably short distance between the two phosphorus atoms, well below than twice the van der Waals radius of P, due to the steric requirements of the rigid acenaphthene backbone. Moreover, in the complexes a stabilizing π-π interaction between two Ph rings belonging to the two P atoms is present. The [LCuCl]2 complex is weakly fluorescent both in solution and in the solid state with higher quantum yield as a solid where it exhibits thermally-activated delayed fluorescence and phosphorescence. [LPdCl2] and [LCuCl]2 behave as chloride transporters across a liposomal phospholipid membrane with the Pd(II) complex displaying a very high activity.

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Category: alcohols-buliding-blocks, illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Recommanded Product: 12080-32-9. The fused heterocycle is formed by combining a benzene ring with a single heterocycle, or two or more single heterocycles. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Mesoionic 1,2,3-Triazolo[1,5-a]pyridine-3-ylidenes in Phosphorescent Platinum(II) Complexes. Author is Soellner, Johannes; Strassner, Thomas.

Mesoionic carbene ligands based on 1,2,3-triazole platforms can be used in cyclometalated platinum(II) complexes to achieve an efficient phosphorescence even at room temperature In this report, 1,2,3-triazolo[1,5-a]pyridine-3-ylidenes are employed in such mols. along with β-diketonates with varying steric demand. For full structural characterization, NMR spectroscopy and XRD experiments were employed. The photophys. properties were studied in solid poly(Me methacrylate) (PMMA) matrixes, as well as dichloromethane solutions In PMMA, the synthesized complexes show quantum yields of 47-54% with emission bands in the yellow region of the visible spectrum. Cyclic voltammetry measurements along with DFT calculations helped to assign the nature of the observed emissions.

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Recommanded Product: 12080-32-9, illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

SDS of cas: 12080-32-9. So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Water’s Role in Polymorphic Platinum(II) Complexes.

Solvent plays a vital role in the recrystallization process and resulting crystallinity of materials. This role is of such importance that it can control the stability and utility of materials. In this work, the inclusion of a solvent in the crystalline lattice, specifically water, drastically affects the overall stability of two platinum polymorphs. [Pt(tpy)Cl]BF4 (tpy = 2,2′;6’2”-terpyridine) crystallizes in three forms, red (1R) and blue (1B) polymorphs and a yellow nonsolvated form (2). 1R is the more stable of the two polymorphs, whereas 1B loses crystallinity upon dehydration at ambient conditions resulting in the formation of 2. Close examination of the solid-state extended structures of the two polymorphs reveals that 1R has a lattice arrangement that is more conducive to stronger intermol. interactions compared to 1B, thereby promoting greater stability. In addition, these two polymorphs exhibit unique vapochromic responses when exposed to various solvents.

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))SDS of cas: 12080-32-9, illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sayadi, Mohsen; Sabounchei, Seyyed Javad; Sedghi, Asieh; Bayat, Mehdi; Hosseinzadeh, Leila; Gable, Robert W. published an article about the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9,SMILESS:C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-] ).Reference of Dichloro(1,5-cyclooctadiene)platinum(II). Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:12080-32-9) through the article.

The new phosphonium salt, the C,C-chelating phosphorus ylide ligand, (MeOC6H5C(O)CH:PPh2(CH2)2PPh2:CHC(O)C6H5OMe), and its Pd(II) and Pt(II) complexes were synthesized and the cytotoxic activity of the synthesized complexes against three human cancer cell lines, including HeLa (Human cervix cancer cell line), KB (human oral cancer cell line) and U87 MG (human glioblastoma cell line) were evaluated using an MTT assay. The new compounds were identified and characterized using multinuclear (1H, 13C and 31P) NMR, IR spectroscopy, elemental anal., and through UV absorption and fluorescence emission spectra. Also, the crystal structure of the phosphorus ylide ligand was determined by single-crystal x-ray diffraction anal. According to the obtained results from the MTT assay, the Pd(II) and Pt(II) complexes demonstrated a higher cytotoxic activity against KB human oral cancer cells in comparison with other cell lines, rendering these compounds into suitable candidates for further anti-oral cancer studies. Furthermore, a theor. study on structure and nature of the M-C bonding between the Y ligand (ylide) and MCl2 fragment in the [YMCl2] (M = Pd, Pt and Y = (MeOC6H5C(O)CH:PPh2(CH2)2PPh2:CHC(O)C6H5OMe)) complexes are reported via NBO and energy-decomposition anal. (EDA).

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Reference of Dichloro(1,5-cyclooctadiene)platinum(II), illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Name: Dichloro(1,5-cyclooctadiene)platinum(II). So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about C-C* Platinum(II) Complexes with Electron-Withdrawing Groups and Beneficial Auxiliary Ligands: Efficient Blue Phosphorescent Emission.

Cyclometalated arylimidazolylidene platinum complexes with diketonate and dipyrazolylborate auxiliary ligands were prepared and examined for photoluminescence and photophys. properties. The combination of strong electron-withdrawing groups in cyclometalated N-heterocyclic carbene ligands (C-C*) with known beneficial auxiliary ligands in phosphorescent platinum(II) complexes leads to efficient light-to-deep-blue emission with quantum yields of up to 92%. All compounds were characterized and investigated regarding their photophys., electrochem., and thermal properties, and three complexes could addnl. be characterized by solid-state structures. D. functional theory calculations (PBE0/6-311G* with dispersion correction) are reported.

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Name: Dichloro(1,5-cyclooctadiene)platinum(II), illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Dichloro(1,5-cyclooctadiene)platinum(II)(SMILESS: C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-],cas:12080-32-9) is researched.SDS of cas: 1798-99-8. The article 《Understanding Doping Effects on Electronic Structures of Gold Superatoms: A Case Study of Diphosphine-Protected M@Au12 (M = Au, Pt, Ir)》 in relation to this compound, is published in Inorganic Chemistry. Let’s take a look at the latest research on this compound (cas:12080-32-9).

Dopants into ligand-protected Au superatoms have been hitherto limited to group X-XII elements (Pt, Pd, Ag, Cu, Hg, and Cd). To expand the scope of the dopants to the group IX elements, the authors synthesized unprecedented [IrAu12(dppe)5Cl2]+ [IrAu12; dppe = 1,2-bis(diphenylphosphino)ethane] and [PtAu12(dppe)5Cl2]2+ (PtAu12) and compared their electronic structures with that of [Au13(dppe)5Cl2]3+ (Au13). Single-crystal x-ray diffractometry, 31P{1H} NMR, and Ir L3-edge extended X-ray absorption fine structure anal. of IrAu12 revealed that the single Ir atom is located at the center of the icosahedral IrAu12 core. Electrochem. anal. demonstrated that the energy levels of the highest occupied MOs are upshifted in the order of Au13 < PtAu12 < IrAu12. This trend was qual. explained in such a manner that the jellium core potential at the central position becomes shallower by replacing Au+ with Pt0 and further with Ir-. IrAu12 underwent reversible redox reactions between the charge states of 1+ and 2+. The gradual increase of the energy gap between the HOMO and LUMO in the order of Au13 < PtAu12 < IrAu12 was observed by electrochem. measurement and optical spectroscopy. This study provides a simple guiding principle to tune the electronic structures of heterometal-doped superatoms. The orbital energies of [IrAu12(dppe)5Cl2]+ (IrAu12) and [PtAu12(dppe)5Cl2]2+ (PtAu12) were compared with those of [Au13(dppe)5Cl2]3+ (Au13) by electrochem. anal. The superat. orbitals were shifted up in the order of IrAu12 > PtAu12 > Au13. The result was explained by the upshift of the bottom of the effective potential due to different formal charge states of the dopants. Whereas Au was incorporated as Au+, Ir and Pt were incorporated as Ir- and Pt0, resp.

In addition to the literature in the link below, there is a lot of literature about this compound(Dichloro(1,5-cyclooctadiene)platinum(II))Related Products of 12080-32-9, illustrating the importance and wide applicability of this compound(12080-32-9).

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Heterocyclic compounds can be divided into two categories: alicyclic heterocycles and aromatic heterocycles. Compounds whose heterocycles in the molecular skeleton cannot reflect aromaticity are called alicyclic heterocyclic compounds. Compound: 12080-32-9, is researched, Molecular C8H12Cl2Pt, about Dynamics of the efficient cyclometalation of the undercoordinated organoplatinum complex [Pt(COD)(neoPh)]+ (neoPh = 2-methyl-2-phenylpropyl), the main research direction is platinum metallacycle cyclooctadiene complex preparation CH activation neophyl ligand; crystal structure platinum metallacycle cyclooctadiene complex; mol structure platinum metallacycle cyclooctadiene complex; cyclometalation mechanism platinum neophyl cyclooctadiene complex potential energy surface.Product Details of 12080-32-9.

Reaction of the organoplatinum complex [Pt(COD)(neoPh)Cl] (neoPh = (2-methyl-2-phenylpropyl)) with Ag(PF6) leads to the undercoordinated cationic complex [Pt(COD)(neoPh)]+ which rapidly and quant. rearranges to the complex [Pt(COD)(κ2-neoPh)] through intramol. cyclometalation. Detailed NMR spectroscopy and single crystal XRD reveal a doubly metalated neoPh ligand. In line with exptl. observations, ab initio mol. dynamics simulations confirm that the cyclometalation reaction is exothermic and has a relatively low free energy barrier. In addition, the simulations provide detailed insight into the reaction mechanism, showing that an intermediate species exists in which the newly formed Pt-C bond coexists with a covalent Pt-H bond involving the leaving proton. The latter is found to eventually transfer onto an acetone solvent mol.

There are many compounds similar to this compound(12080-32-9)Product Details of 12080-32-9. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II). The reaction of aromatic heterocyclic molecules with protons is called protonation. Aromatic heterocycles are more basic than benzene due to the participation of heteroatoms. Compound: Dichloro(1,5-cyclooctadiene)platinum(II), is researched, Molecular C8H12Cl2Pt, CAS is 12080-32-9, about Encapsulation of FePt and FePt3 alloys inside carbon-foam materials. Author is Boi, Filippo S.; Wang, Jiayu; He, Yi; Wen, Jiqiu; Wang, Shanling; Zhang, Xi; Yu, Tian; Shi, Lin; Ma, Qiuyan; Lan, Mu; Lei, Li; Xiang, Gang.

We demonstrate an advanced chem. vapor deposition (CVD) approach in which the addition of Pt-containing hydrocarbons to ferrocene allows the nucleation of a novel carbon-foam material completely filled with elemental Fe and Pt crystal-phases. These phases are then found to alloy into tetragonal FePt and cubic FePt3 in specific annealing conditions. A dependence of the FePt nucleation on the Ar/H2 flow rate is reported. In addition, high pressure (5 GPa) experiments are found to favor the formation of a single FePt3 encapsulated phase together with the nucleation of C-O rich carbon layers in the foam surface.

There are many compounds similar to this compound(12080-32-9)Recommanded Product: Dichloro(1,5-cyclooctadiene)platinum(II). if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In general, if the atoms that make up the ring contain heteroatoms, such rings become heterocycles, and organic compounds containing heterocycles are called heterocyclic compounds. An article called Synthesis and structure of thienyl Fischer carbene complexes of PtII for application in alkyne hydrosilylation, published in 2021, which mentions a compound: 12080-32-9, Name is Dichloro(1,5-cyclooctadiene)platinum(II), Molecular C8H12Cl2Pt, Application of 12080-32-9.

Transmetalation of Group 6 thienylene Fischer carbene complexes to Pt(II) precursors yielded new examples of neutral Pt(II) bisethoxycarbene complexes with either 2-thienyl (T) or 5-thieno[2,3-b]thienylene (TT) carbene substituents. The use of analogous aminocarbene group 6 precursors proceeded to give isomeric Pt(II) product mixtures where the resultant bisaminocarbene ligands displayed different orientations due to restricted rotation around the Pt-aminocarbene bond caused by the sterically demanding TT substituents. The well-defined Pt(II) ethoxycarbene complexes were screened as catalyst precursors in the benchmark hydrosilylation reaction employing phenylacetylene and triethylsilane substrates. Marked selectivity for the β-E isomer (E)-triethyl(styryl)silane was observed, and the (pre)catalysts proved recyclable, active in solvent-free reactions, and displaying a high alkyne functional group tolerance.

There are many compounds similar to this compound(12080-32-9)Application of 12080-32-9. if you want to know more, you can check out my other articles. I hope it will help you，maybe you’ll find some useful information.

Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts