Category: 111-87-5

Li, Shu-Ying published the artcileTri-Stable Structural Switching in 2D Molecular Assembly at the Liquid/Solid Interface Triggered by External Electric Field, Computed Properties of 111-87-5, the main research area is liquid solid interface 2D mol assembly elec field; electric field; scanning tunneling microscopy; self-assembly; structural transition; switchable nanostructures.

A tri-stable structural switching between different polymorphisms is presented in the 2D mol. assembly of a 5-(benzyloxy)isophthalic acid derivative (BIC-C12) at the liquid/solid interface. The assembled structure of BIC-C12 is sensitive to the applied voltage between the STM tip and the sample surface. A compact lamellar structure is exclusively observed at pos. sample bias, while a porous honeycomb structure or a quadrangular structure is preferred at neg. sample bias. Selective switching between the lamellar structure and the honeycomb structure or the quadrangular structure is realized by controlling the polarity and magnitude of the sample bias. The transition between the honeycomb structure and the quadrangular structure is, however, absent in the assembly. This tri-stable structural switching is closely related to the mol. concentration in the liquid phase. This result provides insights into the effect of external elec. field on mol. assembly and benefits the design and construction of switchable mol. architectures on surfaces.

ACS Nano published new progress about Adsorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Computed Properties of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Premadasa, Uvinduni I. published the artcileUnderstanding Self-Assembly and the Stabilization of Liquid/Liquid Interfaces: The Importance of Ligand Tail Branching and Oil-Phase Solvation, Category: alcohols-buliding-blocks, the main research area is dioctyl phosphoric acid liquid interface oil phase solvation; Air-liquid interface; Interfacial analysis; Interfacial tension; Liquid-liquid interface; Molecular ordering; Nonlinear spectroscopy; Oil phase interactions; Solvent extraction; Sum frequency generation; Vibrational spectroscopy.

Organophosphorus-based ligands represent a versatile set of solvent extraction reagents whose chem. makeup plays an important role in extraction mechanism. We hypothesize that the branching of the extractant hydrophobic tail and its oil-phase solvation affect the liquid/liquid interfacial structure. Understanding the structure mediated adsorption and interfacial ordering becomes key in designing ligands with enhanced selectivity and efficiency for targeted extractions We employed vibrational sum frequency generation spectroscopy and interfacial tension measurements to extract thermodn. adsorption energies, map interfacial ordering, and rationalize disparate behaviors of model di-(2-ethylhexyl) phosphoric acid and dioctyl phosphoric acid ligands at the hexadecane water interface. With increased surface loading, ligands with branched hydrophobic tails formed stable interfaces at much lower concentrations than those observed for ligands with linear alkyl tails. The lack of an oil phase and associated solvation results in markedly different interfacial properties, and thus measurements made at air/liquid surfaces cannot be assumed to correlate with the processes occurring at buried liquid/liquid interfaces. We attribute these differences in the surface mediated self-assembly to key variations in hydrophobic interactions and tail solvation taking place in the oil phase demonstrating that interactions in both the polar and nonpolar phases are essential to understand self-assembly and function.

Journal of Colloid and Interface Science published new progress about Adsorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Category: alcohols-buliding-blocks.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Zusman, Ofri B. published the artcileDissolved organic matter adsorption from surface waters by granular composites versus granular activated carbon columns: An applicable approach, Quality Control of 111-87-5, the main research area is dissolved organic matter granular activated carbon adsorption water treatment; Dissolved organic matter; Filtration; Granules; Polymer-clay composite; Surface water.

Many new sorbents have been introduced as an alternative for granular activated carbon (GAC), the most common sorbent for dissolved organic matter (DOM) removal. In the current study, we developed an applicable granular composite based on a flocculant commonly employed for drinking water treatment adsorbed to montmorillonite. DOM adsorption from surface waters, Lake Kinneret and Suwannee River, with low and high specific UV absorption (SUVA), resp., by composite and GAC columns, was studied. Adsorption of DOM from Suwannee River was significantly higher by the composite column, in comparison to the GAC column. In-situ regeneration of the columns with a brine solution was extremely efficient and inefficient for the composite and GAC columns, resp. Adsorption, of both waters, post-regeneration by the composite column was not compromised, while GAC effectiveness decreased. The opposite trend in DOM adsorption from Suwannee River and Lake Kinneret was explained by the different affinities of the sorbents towards various DOM mols. Distinguishing between different DOM components adsorbed by GAC and the composite was supported by 13C NMR and direct pyrolysis-GC-MS measurements. Furthermore, since DOM removal by GAC and by the composite, increases, and decreases with temperature, resp., the integrated column, mitigates the changes in removal, stabilizing the adsorption performance. Such an integrated filter may minimize addnl. seasonal and water quality fluctuations.

Water Research published new progress about Adsorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Quality Control of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Bertanza, Giorgio published the artcileRemoval of perfluoroalkyl substances in drinking water treatment plant, Category: alcohols-buliding-blocks, the main research area is perfluoroalkyl polyfluoroalkyl drinking water treatment plant groundwater pollution control; Activated carbon; Adsorption capacity; Breakthrough; Groundwater; PFAS.

Drinking water contamination by perfluoroalkyl and polyfluoroalkyl substances (PFASs) is an issue of relatively recent concern. The literature indicates that anion exchange resins and granular activated carbon (GAC) are suitable technologies for removing these compounds While several laboratory-scale and pilot-scale experiments have been conducted to study activated carbon adsorption/desorption mechanisms of a number of PFASs, little data on full-scale plants are available. This work examines a real case of groundwater contamination by PFASs in an area of approx. 200 km2. The performance of the main drinking water treatment plant in the area (flowrate = 30,000 m3/d; 100,000 people served), which is equipped with GAC filters, was analyzed. Approx. 17,000 anal. data points from a working period of five years were processed. Perfluorobutyric acid (PFBA) was the first compound to attain breakthrough, followed by perfluoropentanoic acid, perfluorohexanoic acid, perfluorobutanesulfonic acid, and perfluorooctanoic acid (PFOA). The adsorption capacity and treated bed volumes at complete breakthrough (saturation) were calculated, and ranged from 1.71 g/t and 7100 (PFBA) to 24.6 g/t and 50,900 (PFOA), with the total organic carbon concentration in the groundwater ranging from <0.1 to 0.5 mg/L. The overall adsorption capacity was approx. 40 g of total PFASs/t. The breakthrough behavior of PFASs was correlated with the C-F chain length, the type of hydrophilic head (either carboxyl or sulfonic), and the n-octanol/water partition coefficients logP and logD. The results corroborate the findings of previously published bench-scale and pilot-scale experiments Science of the Total Environment published new progress about Adsorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Category: alcohols-buliding-blocks.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Lone, Irfan H. published the artcileQuenching assisted reverse micellar synthesis and electrical properties of high surface area BiFeO3 nanoparticles, COA of Formula: C8H18O, the main research area is bismuth iron oxide nanoparticle quenching elec property.

Multiferroic compounds are prime important materials for future electronic and magnetic devices and overcome the fundamental limits of conventional materials. In present work, we reported the preparation of purely one phase of nano-sized BiFeO3 compound by microemulsion micellar method for the first time by employing rapid quenching of sample at 500°C, that is the main driving force to get the pure phase of BiFeO3 nanoparticles at low temperature method. The nanoparticles that we obtained were almost uniform with sphere shaped and these prepare nanoparticles possess high surface. The increase in permittivity in the form of dielec. constants were reported that depends on temperature and frequency that supports the ferroelec. nature and was further confirmed by the ferroelec. loops even at the room temperature has been found in theses prepared nanoparticles.

Journal of Nanoscience and Nanotechnology published new progress about Adsorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, COA of Formula: C8H18O.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Qian, Jiasheng published the artcileOne-Step Nanoextraction and Ultrafast Microanalysis Based on Nanodroplet Formation in an Evaporating Ternary Liquid Microfilm, Name: n-Octanol, the main research area is ternary liquid microfilm nanodroplet formation nanoextn microanalysis.

Preconcentration is key for detection from an extremely low concentration solution, but requires separation steps from a large volume of samples using extracting solvents. Here, a simple approach is presented for ultrafast and sensitive microanal. from a tiny volume of aqueous solutions In this approach, liquid-liquid nanoextn. in an evaporating thin liquid film on a spinning substrate is coupled with quant. anal. in one step. The approach is exemplified using a liquid mixture comprising a target compound to be analyzed in water, mixed with extractant oil and co-solvent ethanol. With rapid evaporation of ethanol, nanodroplets of oil form spontaneously in the film. The compounds are highly concentrated by liquid evaporation and meanwhile extracted to nanodroplets. A detection limit of nanomolar to picomolar is demonstrated for fluorescent model compounds in only â‰?μL of solution with the entire process taking â‰?0 s. The combination of nanoextn. and IR microscopy also enables simultaneous chem. identification. The dynamics of thin film evaporation are revealed using fast imaging. The principle behind this approach is general, providing a powerful technique for fast and sensitive chem. anal. of a vast library of compounds for environment monitoring, national security, early diagnosis, and many other applications.

Advanced Materials Technologies (Weinheim, Germany) published new progress about Absorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Name: n-Octanol.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Karami, Thomas K. published the artcileEyes on Lipinski′s Rule of Five: A New “”Rule of Thumb”” for Physicochemical Design Space of Ophthalmic Drugs, Formula: C8H18O, the main research area is ophthalmic drug delivery physicochem design space solubility; ocular permeability thermodn property; formulation; ocular permeability; ophthalmic drug delivery; physicochemical design space; solubility.

The study objective was to investigate mol. thermodn. properties of approved ophthalmic drugs and derive a framework outlining physicochem. design space for product development. Unlike the methodol. used to obtain mol. descriptors for assessment of drug-like properties by Lipinski′s Rule of 5 (Ro5), this work presents a retrospective approach based on in silico anal. of mol. thermodn. properties beyond Ro5 parameters (ie, free energy of distribution/partitioning in octanol/water, dynamic polar surface area, distribution coefficient, and solubility at physiol. pH) by using 145 marketed ophthalmic drugs. The study′s focus was to delineate inherent mol. parameters explicitly important for ocular permeability and absorption from topical eye drops. A comprehensive parameter distribution anal. on ophthalmic drugsâ€?mol. properties was performed. Frequencies in distribution analyses provided groundwork for physicochem. parameter limits of mol. thermodn. properties having impact on corneal permeability and topical ophthalmic drug delivery. These parameters included free energy of partitioning (ΔGo/w) calculated based on thermodn. free energy equation, distribution coefficient at physiol. pH (clog DpH7.4), topol. polar surface area (TPSA), and aqueous solubility (Sint, SpH7.4) with boundaries of clog DpH7.4 â‰?4.0, TPSA â‰?250 Å2, ΔGo/w â‰?20 kJ/mol (4.8 kcal/mol), and solubility (Sint and SpH7.4) â‰?1 μM, resp. The theor. free energy of partitioning model streamlined calculation of changes in the free energy of partitioning, Δ(ΔGo/w), as a measure of incremental improvements in corneal permeability for congeneric series. The above parameter limits are proposed as “”rules of thumb”” for topical ophthalmic drugs to assess risks in developability.

Journal of Ocular Pharmacology and Therapeutics published new progress about Absorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Formula: C8H18O.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Khatouri, M. published the artcileEffect of hydrophobically modified PEO polymers (PEO-dodecyl) on oil/water microemulsion properties: in vitro and in silico investigations, Synthetic Route of 111-87-5, the main research area is hydrophobically modified PEO polymer oil water microemulsion property.

Microemulsions are excellent systems for transdermal delivery of multifunctional drugs because they have the potential to improve drug absorption/permeation and handling limitations. Biocompatible polymers are used as a coating of microemulsions to avoid the interactions that can occur between the microemulsions and the skin. Thus, they protect and lubricate these transporter nanovesicles. In this paper, we studied decane/water microemulsions covered with hydrophobically modified PEO polymer (PEO-m). To reveal the effect of hydrophobically modified PEO (PEO-m) polymer on the shape, the micro-arrangement and the dynamics of the microemulsions, we used an integrated strategy combining Mol. Dynamics simulation (MD), Small-Angle Neutron Scattering experiments (SANS), and the Ornstein-Zernike integral equations with the Hypernetted Chain (HNC) closure relation. We determined the microemulsion shape in vitro using the renormalized intensities spectra from SANS experiments We discussed the micro arrangements of microemulsions, in vitro and in silico, employing the pair correlation function g(r) and the structure factor S(q), obtained from the three approaches with good agreement. Thus, we used the validated MD simulations to calculate the microemulsion’s dynamics properties that we discussed using the mean-squared displacement (MSD) and the diffusion coefficients We found that the presence of moderate quantities of PEO-m, from 4 to 12 PEO-m per microemulsion, does not influence the microemulsion shape, increases the stability of the microemulsion, and slightly decrease the dynamics. Our in vitro and in silico results suggest that polymer incorporation, which has interesting in vivo implications, has no disadvantageous effects on the microemulsion properties.

RSC Advances published new progress about Absorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Synthetic Route of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Kini, Girish published the artcilePassive enhancement of ammonia-water absorption by the addition of surfactants, Quality Control of 111-87-5, the main research area is ammonia water absorption surfactant.

Surface-active agents or surfactants have the potential to substantially enhance heat and mass transfer in ammonia-water absorption by reducing the surface tension of the working fluid. The enhancement is caused by interfacial turbulence at the vapor-liquid interface that results from surface tension gradients. A surfactant selection criterion is developed based on the plateau value of surface tension, critical concentration, and the critical Marangoni number required to initiate interfacial turbulence. Based on this criterion, surface-active agents, and their ideal concentrations for the enhancement of ammonia-water absorption are recommended. The preferred additives are found to be 500 PPM of 1-octanol or 2-ethyl-1-hexanol. A heat and mass transfer model is developed to predict the performance of a falling-film absorber due to the addition of surfactants at conditions representative of an absorption heat pump. The model indicates that the overall conductance of the absorber is improved by �0% by the addition of surfactants. The results from this work can guide intensification of various coupled heat and mass transfer processes using surfactants.

International Journal of Heat and Mass Transfer published new progress about Absorption. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, Quality Control of 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Dai, Yingjie published the artcileNew use for spent coffee ground as an adsorbent for tetracycline removal in water, HPLC of Formula: 111-87-5, the main research area is SCG adsorbent tetracycline removal water adsorption wastewater treatment; Hydrogen bond; Hydrophobic interaction; Oxygen-containing functional groups; Removal ratio; π–π interaction.

Spent coffee grounds (SCG-1 and SCG-2) were used to study the adsorption of tetracycline (TC) antibiotics and the effects of adsorption time, initial pH, amount of adsorbent and ionic strength were detected. The TC adsorption isotherm on SCG-1 was compared with SCG-2. The results showed that the removal efficiencies of TC (50 mg/L) of SCG-1 and SCG-2 were 83.1% and 97.2%, resp., shake for 2 h. The probability of adsorption is high and balances in about 20 min. The estimate of parameters got for TC from the Langmuir isotherm saturated adsorption quantity and adsorption balance constant were 64.89 mg/g, 0.0557 L/mg, resp. for SCG-1 and 123.46 mg/g, 0.4735 L/mg, resp. for SCG-2. The adsorption mechanism might be a π-π interaction that occurs in the interface by hydrogen bonding and the between the TC mol. and the SCGs. At last, we found that SCG has a high adsorption size for TC.

Chemosphere published new progress about Adsorbents. 111-87-5 belongs to class alcohols-buliding-blocks, name is n-Octanol, and the molecular formula is C8H18O, HPLC of Formula: 111-87-5.

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts