Category: 106-21-8

Citral-to-Menthol Transformations in a Continuous Reactor over Ni/Mesoporous Aluminosilicate Extrudates Containing a Sepiolite Clay Binder was written by Simakova, Irina L.;Vajglova, Zuzana;Maki-Arvela, Paivi;Eranen, Kari;Hupa, Leena;Peurla, Markus;Makila, Ermei M.;Warna, Johan;Murzin, Dmitry Yu.. And the article was included in Organic Process Research & Development in 2022.Recommanded Product: 106-21-8 The following contents are mentioned in the article:

One-pot continuous synthesis of menthols from citral was performed over 5 wt % Ni supported on a mesoporous aluminosilicate catalyst with sepiolite as a binder at 70°C with a selectivity of 75% to menthols. Catalyst deactivation with time-onstream resulted in a decrease of the conversion and selectivity to menthol at the expense of higher selectivity to isopulegols. Stereoselectivity to isopulegols and menthols only slightly changed with conversion and TOS. A kinetic model capable of describing exptl. data for transformations of citral to menthol in a continuous mode was developed. It was based on a detailed reaction network and also comprised deactivation on both metal and acid sites. Numerical data fitting confirmed a good correspondence between the exptl. data and calculations This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Recommanded Product: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sustainable ABA triblock methacrylate copolymers incorporating both high and low Tg terpene-derived monomers was written by Atkinson, Rachel L.;Elsmore, Matthew;Smith, Sean;Reynolds-Green, Morgan;Topham, Paul D.;Toolan, Daniel T. W.;Derry, Matthew J.;Monaghan, Olivia;Taresco, Vincenzo;Irvine, Derek J.;Stockman, Robert A.;De Focatiis, Davide S. A.;Howdle, Steven M.. And the article was included in European Polymer Journal in 2022.Application of 106-21-8 The following contents are mentioned in the article:

We report the synthesis of novel terpene-based monomers: nopinyl acrylate and methacrylate, from naturally abundant β-pinene. A very high Tg value was observed for poly(nopinyl methacrylate) when synthesized by free radical polymerization, and well-defined polymers have been produced via RAFT polymerization This exciting new high Tg material shows promise as a hard block in thermoplastic elastomers. ABA triblock copolymers have been synthesized which also incorporate a low Tg renewable soft block, poly(tetrahydrogeraniol methacrylate), using a divergent, difunctional RAFT polymerization method. Initial phase separation behavior and adhesive properties have been investigated to highlight the potential of these copolymer materials as renewably sourced thermoplastic elastomers. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Application of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Effect of ripening with Penicillium roqueforti on texture, microstructure, water distribution and volatiles of chicken breast meat was written by Guo, Liping;Yu, Bing;Wang, Shuling;Zhu, Yinglian;Li, Peng;Wang, Baowei;Huang, Ming;Sun, Jingxin. And the article was included in International Journal of Food Science and Technology in 2019.SDS of cas: 106-21-8 The following contents are mentioned in the article:

Summary : In this study, the influence of ripening with Penicillium roqueforti on texture, microstructure, protein structure, water mobility and volatile flavor compounds of chicken breast meat was investigated. SEM (SEM) and transmission electron microscope (TEM) images showed that the granule formed and chicken myofibril fractured after ripening. Reduction in α-helix and increases in β-sheet structure content accompanied by decrease in hardness and springiness and increase in gumminess were found in ripened chicken breast meat. Low field NMR (LF-NMR) revealed that increasing intra-myofibrillar water and decreasing extra-myofibrillar water resulted in the higher water-holding capacity after ripening with P. roqueforti. In addition, chicken breast meat ripened with P. roqueforti contained more volatile flavor compounds, in particular aldehydes. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8SDS of cas: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.SDS of cas: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

High pressure phase behaviour for the CO₂ + n-dodecane + 3,7-dimethyl-1-octanol system was written by Latsky, C.;Mabena, N. S.;Schwarz, C. E.. And the article was included in Journal of Supercritical Fluids in 2019.Quality Control of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

In this work, the solute-solute interaction which exist in the CO₂ + n-dodecane+ 3,7-dimethyl-1-octanol system was investigated. Solubility data were measured for three mixtures containing solventfree n-dodecane fractions of 0.50, 0.75 and 0.85, between 308 K and 348 K and pressures up to 14.9 MPa, with solvent mass fractions ranging from 0.375 to 0.984, using a static synthetic method. The data revealed significant solute-solute interactions, which resulted in the occurrence of co-solvency in the two n-dodecane rich mixtures The phase behavior data of the system was modeled, using the RK-ASPEN model. The modeling results indicated that, with the inclusion of a solute-solute interaction parameter, the fitted model was capable of correlating fairly accurate solubility data, but it can only approx. vapor-liquid-equilibrium data. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Quality Control of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Quality Control of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Viaticene A – An Unusual Tetraterpene Cuticular Lipid Isolated from the Springtail Hypogastrura viatica was written by Bello, Jan E.;Stamm, Patrick;Leinaas, Hans Petter;Schulz, Stefan. And the article was included in European Journal of Organic Chemistry in 2019.COA of Formula: C10H22O The following contents are mentioned in the article:

The cuticles of springtails are extremely wear and friction resistant, super-hydrophobic, non-fouling, and self-cleaning. As such, the chem. of the lipids covering these cuticles is of great interest as a model for biomimetic super-hydrophobic surfaces, although only few of these lipids have been structurally elucidated. Hypogastrura viatica, a surface-dwelling springtail, produces highly branched tetraterpene hydrocarbons with an unprecedented [6+2]-terpene connectivity as components of the epicuticular lipid layer. The structure of the major lipid component, viaticene A, was elucidated through isolation, spectroscopic anal., chem. derivatization, synthesis, as well as stereochem. anal. of the core unit obtained from ozonolysis of the isolated lipid. Viaticenes A and B represent a new class of irregular tetraterpenoid natural products. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8COA of Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.COA of Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Ozone-Mediated Amine Oxidation and Beyond: A Solvent-Free, Flow-Chemistry Approach was written by Skrotzki, Eric A.;Vandavasi, Jaya Kishore;Newman, Stephen G.. And the article was included in Journal of Organic Chemistry in 2021.COA of Formula: C10H22O The following contents are mentioned in the article:

Ozone is a powerful oxidant, most commonly used for oxidation of alkenes to carbonyls. The synthetic utility of other ozone-mediated reactions is hindered by its high reactivity and propensity to overoxidize organic mols., including most solvents. This challenge can largely be mitigated by adsorbing both substrate and ozone onto silica gel, providing a solvent-free oxidation method. In this manuscript, a flow-based packed bed reactor approach is described that provides exceptional control of reaction temperature and time to achieve improved control and chemoselectivity over this challenging transformation. A powerful method to oxidize primary amines into nitroalkanes is achieved. Examples of pyridine, C-H bond, and arene oxidations are also demonstrated, confirming the system is generalizable to diverse ozone-mediated processes. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8COA of Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.COA of Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Monoterpene substituted thiazolidin-4-ones as novel TDP1 inhibitors: Synthesis, biological evaluation and docking was written by Ivankin, Dmitry I.;Dyrkheeva, Nadezhda S.;Zakharenko, Alexandra L.;Ilina, Ekaterina S.;Zarkov, Timofey O.;Reynisson, Johannes;Luzina, Olga A.;Volcho, Konstantin P.;Salakhutdinov, Nariman F.;Lavrik, Olga I.. And the article was included in Bioorganic & Medicinal Chemistry Letters in 2022.Formula: C10H22O The following contents are mentioned in the article:

In this paper, novel thiazolidin-4-one derivatives I [R = R¹OC₆H₄, R²; R¹ or R² = 3,7-dimethyloctyl, 3,7-dimethyloct-6-en-1-yl, Ph, etc.] with a benzyl and monoterpene substituents were synthesized. Compounds with a monoterpene fragment attached via a phenyloxy linker were active against TDP1 with IC₅₀ values in the 1-3μM range, while direct attachment of monoterpene moiety to the thiazolidin-4-one fragment had no activity. Mol. modeling predicted two plausible binding modes of the active compounds both effectively blocking access to the catalytic site of TDP. At non-toxic concentrations the active ligands potentiated the efficacy of the TOP1 poison topotecan in human cervical cancer HeLa cells, but not in non-cancerous HEK293A cells. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sustainable Synthesis of Renewable Terpenoid-Based (Meth)acrylates Using the CHEM21 Green Metrics Toolkit was written by Droesbeke, Martijn A.;Du Prez, Filip E.. And the article was included in ACS Sustainable Chemistry & Engineering in 2019.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

Terpenes and their subclass terpenoids are natural products, extracted from various plants and trees. As a result of their structural diversity, they offer versatile functionalization possibilities when incorporated into synthetic polymers. This investigation aims at synthesizing a range of terpenoid-based (meth)acrylates via widely reported or less conventional methods and at screening these different synthetic methodologies in terms of their green credentials. The underlying goal has been to both qual. and quant. determine the most atom efficient and sustainable pathway with the help of the recently developed CHEM21 green metrics toolkit. At the same time, this study shows the ease of this evaluation system and encourages a more widespread use of this toolkit not only in polymer science but also in other areas of chem. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Catalytic Reductions Without External Hydrogen Gas: Broad Scope Hydrogenations with Tetrahydroxydiboron and a Tertiary Amine was written by Korvinson, Kirill A.;Akula, Hari K.;Malinchak, Casina T.;Sebastian, Dellamol;Wei, Wei;Khandaker, Tashrique A.;Andrzejewska, Magdalena R.;Zajc, Barbara;Lakshman, Mahesh K.. And the article was included in Advanced Synthesis & Catalysis in 2020.Synthetic Route of C10H22O The following contents are mentioned in the article:

Aryl bromides, iodides, chlorides, and triflates, benzylic halides and ethers, benzyl carbamates, alkenes, alkynes, azides, and aldehydes underwent reductive cleavage, hydrogenation, and reduction reactions using B₂(OH)₄ as reductant in the presence of Pd/C and 4-methylmorpholine. Aryl dihalides containing two different halogen atoms underwent selective reduction, with reduction of I favored over reduction of Br and Cl, and Br reduction favored over the reduction of Cl. Cyano groups were unaffected, but nitro group and ketones underwent reduction to a low extent. B₂(OD)₄ and N,N-bis(methyl-d₃)pyridin-4-amine (DMAP-d₆) were used as reagents for the reductive deuteration of aryl halides. Hydrogen gas has been observed to form with this reagent combination. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Multimodal character of shear viscosity response in hydrogen bonded liquids was written by Arrese-Igor, S.;Alegria, A.;Colmenero, J.. And the article was included in Physical Chemistry Chemical Physics in 2018.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

The impact of supramol. aggregate formation on the shear viscosity response of hydrogen bonded liquids was investigated. In particular, we study the shear mech. response of several monoalcs. showing exponential and non-exponential shape dielec. Debye-like relaxation. In addition to the structural relaxation, distinctive of the glass transition, and the terminal crossover to pure viscous flow, characteristic of simple liquid flow, systematic anal. of complex viscosity curves evidences the presence of an addnl. intermediate process between those two. While the recovery of pure viscous flow would reflect the complete relaxation of the hydrogen bonded aggregates the intermediate process correlates with the rotational dynamics of hydroxyl groups, potentially caused by the breaking of individual hydrogen bonds. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts