Category: 106-21-8

Recyclable cobalt(0) nanoparticle catalysts for hydrogenations was written by Bueschelberger, Philipp;Reyes-Rodriguez, Efrain;Schoettle, Christian;Treptow, Jens;Feldmann, Claus;Jacobi von Wangelin, Axel;Wolf, Robert. And the article was included in Catalysis Science & Technology in 2018.SDS of cas: 106-21-8 The following contents are mentioned in the article:

The search for new hydrogenation catalysts that replace noble metals is largely driven by sustainability concerns and the distinct mechanistic features of 3d transition metals. Several combinations of cobalt precursors and specific ligands in the presence of reductants or under high-thermal conditions were reported to provide active hydrogenation catalysts. This study reports a new method of preparation of small, monodisperse Co(0) nanoparticles (3-4 nm) from the reduction of com. CoCl₂ in the absence of ligands or surfactants. High catalytic activity was observed in hydrogenations of alkenes, alkynes, imines, and heteroarenes (2-20 bar H₂). The magnetic properties enabled catalyst separation and multiple recyclings. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8SDS of cas: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.SDS of cas: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Non-thermal microwave effects in radical polymerization of bio-based terpenoid (meth)acrylates was written by Castagnet, Thibault;Agirre, Amaia;Ballard, Nicholas;Billon, Laurent;Asua, Jose M.. And the article was included in Polymer Chemistry in 2020.Application In Synthesis of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Microwave-assisted polymerization represents an opportunity to develop efficient polymerization strategies for the synthesis of (bio)macromols. with improved properties. The possibilities will increase tremendously if non-thermal microwave effects, i.e. effect of microwaves on the kinetic constants, are operative, because we can increase at the same time conversion and mol. weight This work investigates these effects in the free radical polymerization of bio-based terpenoid (meth)acrylates finding that terpenoid acrylates present a strong non-thermal microwave effect, whereas the methacrylate ones do not show any effect. The reasons for these findings are discussed and the results compared with the apparently conflicting literature. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application In Synthesis of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Application In Synthesis of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Multicatalytic Transformation of (Meth)acrylic Acids: a One-Pot Approach to Biobased Poly(meth)acrylates was written by Fouilloux, Hugo;Qiang, Wei;Robert, Carine;Placet, Vincent;Thomas, Christophe M.. And the article was included in Angewandte Chemie, International Edition in 2021.Synthetic Route of C10H22O The following contents are mentioned in the article:

Shifting from petrochem. feedstocks to renewable resources can address some of the environmental issues associated with petrochem. extraction and make plastics production sustainable. Therefore, there is a growing interest in selective methods for transforming abundant renewable feedstocks into monomers suitable for polymer production Reported herein are one-pot catalytic systems, that are active, productive, and selective under mild conditions for the synthesis of copolymers from renewable materials. Each system allows for anhydride formation, alc. acylation and/or acid esterification, as well as polymerization of the formed (meth)acrylates, providing direct access to a new library of unique poly(meth)acrylates. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Catalytic conversion of citronellal to citronellol over skeletal Ni catalyst was written by Sudiyarmanto, S.;Adilina, I. B.;Aditya, R. R.;Sukandar, D.;Tursiloadi, S.. And the article was included in Journal of Physics: Conference Series in 2020.Recommanded Product: 106-21-8 The following contents are mentioned in the article:

Catalytic conversion of citronellal to citronellol was performed via hydrogenation over skeletal Ni catalyst. The reaction parameters applied include variation of reactant-catalyst ratio, reaction temperature, pressure, and time. Citronellal 78% obtained from the fractionation of citronella oil was used as the reactant. The reaction was carried out using reactant-catalyst ratio of 1:5% and 1:10% at temperatures of 100°C, 150°C and 200°C and pressure of 10 bar, 15 bar and 20 bar for 1 and 3 h. Results show that the optimum reaction condition was at 100°C with reactant-catalyst ratio of 1:10% under pressure of 20 bar for 1 h giving 100% conversion of citronellal, 51.78% yield of citronellol and 40.39% selectivity. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Recommanded Product: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Metal-free alcohol-directed regioselective heteroarylation of remote unactivated C(sp³)-H bonds was written by Wu, Xinxin;Zhang, Hong;Tang, Nana;Wu, Zhen;Wang, Dongping;Ji, Meishan;Xu, Yan;Wang, Min;Zhu, Chen. And the article was included in Nature Communications in 2018.Application In Synthesis of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

A practical and elusive metal-free alc.-directed heteroarylation of remote unactivated C(sp³)-H bonds was disclosed. Phenyliodine bis(trifluoroacetate) (PIFA) was used as the only reagent to enable the coupling of alcs. and heteroaryls. Alkoxy radicals were readily generated from free alcs. under the irradiation of visible light, which trigged the regioselective hydrogen-atom transfer (HAT). A wide range of functional groups were compatible with the mild reaction conditions. Two unactivated C-H bonds were cleaved and one new C-C bond was constructed during the reaction. This protocol provides an efficient strategy for the late-stage functionalization of alcs. and heteroaryls. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application In Synthesis of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Application In Synthesis of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sulfamides direct radical-mediated chlorination of aliphatic C-H bonds was written by Short, Melanie A.;Shehata, Mina F.;Sanders, Matthew A.;Roizen, Jennifer L.. And the article was included in Chemical Science in 2020.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

Herein, sulfamides served as amine surrogates to guide intermol. chlorine-transfer at γ-C(sp³) centers. This unusual position-selectivity arised because accessed sulfamidyl radical intermediates engaged preferentially in otherwise rare 1,6-hydrogen-atom transfer (HAT) processed through seven-membered transition states. The site-selectivity of C-H abstraction could be modulated by adjusting steric and electronic properties of sulfamide nitrogen substituents, an ability that had not been demonstrated with other substrate classes. The disclosed reaction relied on a light-initiated radical chain-propagation mechanism to oxidize C(sp³)-H bonds efficiently. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

A General Strategy for Aliphatic C-H Functionalization Enabled by Organic Photoredox Catalysis was written by Margrey, Kaila A.;Czaplyski, William L.;Nicewicz, David A.;Alexanian, Erik J.. And the article was included in Journal of the American Chemical Society in 2018.Synthetic Route of C10H22O The following contents are mentioned in the article:

Synthetic transformations that functionalize unactivated aliphatic C-H bonds in an intermol. fashion offer unique strategies for the synthesis and late-stage derivatization of complex mols. Herein we report a general approach to the intermol. functionalization of aliphatic C-H bonds using an acridinium photoredox catalyst and phosphate salt under blue LED irradiation This strategy encompasses a range of valuable C-H transformations, including the direct conversions of a C-H bond to C-N, C-F, C-Br, C-Cl, C-S, and C-C bonds, in all cases using the alkane substrate as the limiting reagent. Detailed mechanistic studies are consistent with the intermediacy of a putative oxygen-centered radical as the hydrogen atom-abstracting species in these processes. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Aliphatic Radical Relay Heck Reaction at Unactivated C(sp³)-H Sites of Alcohols was written by Chuentragool, Padon;Yadagiri, Dongari;Morita, Taiki;Sarkar, Sumon;Parasram, Marvin;Wang, Yang;Gevorgyan, Vladimir. And the article was included in Angewandte Chemie, International Edition in 2019.Recommanded Product: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

A radical relay Heck reaction which allows selective remote alkenylation of aliphatic alcs. at unactivated β-, γ-, and δ-C(sp³)-H sites is reported. The use of an easily installed/removed Si-based auxiliary enables selective I-atom/radical translocation events at remote C-H sites followed by the Heck reaction. Notably, the reaction proceeds smoothly under mild visible-light-mediated conditions at room temperature, producing highly modifiable alkenol products such as HOCRR¹R² [R = Me, n-Pr, i-Bu, etc.; R¹ = H, Me; R² = CH₂C(Me)₂CH=CHCN, CH₂CHMeCH=CH(4-ClC₆H₄), CH₂CHEtCH=CHCN, etc.] from readily available alcs. feedstocks. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Recommanded Product: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

An Atom-Economic and Stereospecific Access to Trisubstituted Olefins through Enyne Cross Metathesis Followed by 1,4-Hydrogenation was written by Ratsch, Friederike;Schmalz, Hans-Guenther. And the article was included in Synlett in 2018.Application In Synthesis of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

The combination of intermol. enyne cross metathesis and subsequent 1,4-hydrogenation opens a stereocontrolled and atom-economic access to trisubstituted olefins. By investigating different combinations of functionalized alkyne and alkene substrates, it was found that the outcome (yield, E/Z ratio) of the Grubbs II-catalyzed enyne cross-metathesis step depends on the substrate’s structure, the amount of the alkene (used in excess), and the (optional) presence of ethylene. In any case, the 1,4-hydrogenation, catalyzed by 1,2-dimethoxybenzene-Cr(CO)₃, proceeds stereospecifically to yield exclusively the E-products from both the E-and Z-1,3-diene intermediates obtained by metathesis. A rather broad scope and functional group compatibility of the method is demonstrated by means of 15 examples. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application In Synthesis of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. Alcohols may be oxidized to give ketones, aldehydes, and carboxylic acids. These functional groups are useful for further reactions. Oxidation of organic compounds generally increases the number of bonds from carbon to oxygen (or another electronegative element, such as a halogen), and it may decrease the number of bonds to hydrogen.Application In Synthesis of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

δ-C-H Mono- and Dihalogenation of Alcohols was written by Herron, Alastair N.;Liu, Dongxin;Xia, Guoqin;Yu, Jin-Quan. And the article was included in Journal of the American Chemical Society in 2020.Recommanded Product: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Alkoxy radicals have long been known to enable remote C-H functionalization via 1,5-hydrogen atom abstraction. However, methods for their generation traditionally have relied upon highly oxidizing metals, UV radiation, or preformed peroxide intermediates, which has prevented the development of many desirable transformations. Herein we report a new bench-stable precursor that decomposes to free alkoxy radicals via a previously unreported single-electron oxidation pathway. This new precursor enables the fluorination and chlorination of remote C-H bonds under exceptionally mild conditions with exceedingly high monoselectivity. Iterative use of this precursor enables the introduction of a second halogen atom, granting access to remote dihalide motifs, including CF₂ and CFCl. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Recommanded Product: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts