Category: 106-21-8

Cross β-alkylation of primary alcohols catalysed by DMF-stabilized iridium nanoparticles was written by Kobayashi, Masaki;Yamaguchi, Hiroki;Suzuki, Takeyuki;Obora, Yasushi. And the article was included in Organic & Biomolecular Chemistry in 2021.Synthetic Route of C10H22O The following contents are mentioned in the article:

A simple method for the cross β-alkylation of linear alcs. R(CH₂)₂OH (R = octyl, cyclohexylmethyl, Ph, 3-benzyl-4-hydroxybutyl, etc.) with benzyl alcs. R¹CH₂OH (R¹ = Ph, cyclopropyl, thiophen-2-yl, etc.) in the presence of DMF-stabilized iridium nanoparticles was developed. The nanoparticles were prepared in one-step and thoroughly characterized. Furthermore, the optimum reaction conditions have a wide substrate scope and excellent product selectivity. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
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Chemoselective Aliphatic C-H Bond Oxidation Enabled by Polarity Reversal was written by Dantignana, Valeria;Milan, Michela;Cusso, Olaf;Company, Anna;Bietti, Massimo;Costas, Miquel. And the article was included in ACS Central Science in 2017.SDS of cas: 106-21-8 The following contents are mentioned in the article:

Using nonracemic manganese complexes, alkanes, alcs., amides, and amines underwent chemoselective and regioselective hydroxylation with H₂O₂ at unactivated C-H bonds when performed in fluorinated alc. solvents (particularly hexafluoroisopropanol and 2,2,2-trifluoroethanol) to yield monohydroxylated products with improved chemoselectivities relative to reactions performed in MeCN. The initial hydroxylated product is oxidized much less readily in fluoroalc. solvents than in MeCN. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8SDS of cas: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.SDS of cas: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Sulfonium ion-promoted traceless Schmidt reaction of alkyl azides was written by Ardiansah, Bayu;Tanimoto, Hiroki;Tomohiro, Takenori;Morimoto, Tsumoru;Kakiuchi, Kiyomi. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2021.Category: alcohols-buliding-blocks The following contents are mentioned in the article:

Schmidt reaction by sulfonium ions is described. General primary, secondary, and tertiary alkyl azides such as 3-phenylpropyl azide, (3-azidopentyl)benzene, 1,12-diazidooctadecane, 7-azido-3,7-dimethyloctan-1-ol, etc. were converted to the corresponding carbonyl compounds such as 2-phenylpropanal, 1-phenylpentan-2-one, 12-oxooctadecanal, 1-phenylpropan-2-one, N-benzylpropan-2-amine, etc. and 2-phenylimino-indan-1,3-dione without any trace of the activators. This bond scission reaction through 1,2-migration of C-H and C-C bonds was accessible to the one-pot substitution reaction. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Category: alcohols-buliding-blocks).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Category: alcohols-buliding-blocks

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Alcohol – Wikipedia,
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Regioselective synthesis of the 4,5-dialkoxy-2-nitroanilines bearing two different alkoxy substituents was written by Grolik, Jaroslaw;Reka, Pawel;Gorczyca, Magdalena;Stadnicka, Katarzyna. And the article was included in Tetrahedron Letters in 2022.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

This article reported the regioselective and chemoselective synthesis of 4,5-dialkoxy-2-nitroanilines I [R¹ = Me, Et, i-Bu, etc.; R² = Me, i-Pr, n-Bu, etc.] substituted with two alkoxys at C-4 and C-5. Here the optimization protocol of the transetherification reaction used to synthesize 20 new compounds with good to excellent yields (50-92%) was showed. A simple and efficient one-step procedure was described that could be applied to obtain a significant number of pharmacol. active compounds, including antimalarial drug Primaquine analogs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alcohols are weak acids. The most acidic simple alcohols (methanol and ethanol) are about as acidic as water, and most other alcohols are somewhat less acidic. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
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γ-Alkylation of Alcohols Enabled by Visible-Light Induced 1,6-Hydrogen Atom Transfer was written by Shu, Wei;Zhang, Hui;Huang, Yan. And the article was included in Organic Letters in 2019.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

Site-selective remote alkylation of alc. is attractive but challenging in organic synthesis. Herein, we report a novel visible-light mediated γ-alkylation of alc. derivatives via the formation of C_sp3-C_sp3 bond through C_sp3-H bond functionalization under mild conditions. The use of sulfamate esters enables the directed, otherwise rare 1,6-HAT to generate γ-selective C-centered radical, which is complementary to δ-selective 1,5-HAT of alcs. This redox-neutral protocol provides a general and operationally simple method to access γ-alkylated alcs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.HPLC of Formula: 106-21-8

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Alcohol – Wikipedia,
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A general and efficient Mn-catalyzed acceptorless dehydrogenative coupling of alcohols with hydroxides into carboxylates was written by Shao, Zhihui;Wang, Yujie;Liu, Yaqian;Wang, Qian;Fu, Xiaoling;Liu, Qiang. And the article was included in Organic Chemistry Frontiers in 2018.Formula: C10H22O The following contents are mentioned in the article:

Herein, a sustainable method was developed for the synthesis of carboxylic acids RCO₂H [R = Me, Ph, 3-pyridyl, etc.] via manganese-catalyzed acceptorless dehydrogenation of alcs. generating H₂ as the sole byproduct. A wide range of carboxylic acids were synthesized with high yields and excellent functional group tolerance. The reaction proceeded selectively in the presence of a well-defined manganese pincer complex at a very low catalyst loading. Mechanistic studies including control experiments, NMR spectroscopy and X-ray crystallog. identified the resting state and key intermediates in the catalytic cycle. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Grignard and organolithium reagents are powerful tools for organic synthesis, and the most common products of their reactions are alcohols.Formula: C10H22O

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Surprisingly selective sulfate extraction by a simple monofunctional di(imino)guanidinium micelle-forming anion receptor was written by Williams, Neil J.;Seipp, Charles A.;Garrabrant, Kathleen A.;Custelcean, Radu;Holguin, Erick;Keum, Jong K.;Ellis, Ross J.;Moyer, Bruce A.. And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2018.Reference of 106-21-8 The following contents are mentioned in the article:

The authors report a novel di(imino)guanidinium anion extractant with unparalleled selectivity for sulfate in a liquid-liquid separation system. In addition to a 4.4 order-of-magnitude enhancement in affinity compared to a standard benchmark, the alkylated di(imino)guanidinium receptor is economically synthesized and features good compatibility with application-relevant aliphatic solvents. Small-angle x-ray scattering results reveal the formation of reverse-micelles, which together with the significant organic-phase water content challenge traditional notions of selectivity in extraction of superhydrophilic anions. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Reference of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Reference of 106-21-8

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Alcohol – Wikipedia,
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In Water and under Mild Conditions: α-Alkylation of Ketones with Alcohols by Phase-Transfer-Assisted Borrowing Hydrogen Catalysis was written by Rakers, Lena;Schaefers, Felix;Glorius, Frank. And the article was included in Chemistry – A European Journal in 2018.Related Products of 106-21-8 The following contents are mentioned in the article:

Borrowing hydrogen is a powerful and green technique that allows readily available alcs. to be used as alkylating agents and produces water as the only byproduct. Nevertheless, harsh conditions such as high temperatures and organic solvents are usually required. Herein, we present a strategy to perform the α-alkylation of ketones in aqueous media at mild temperatures by combining borrowing hydrogen with phase-transfer catalysis. A broad scope of Me ketones was functionalized with alkyl and benzyl alcs. in moderate to good yields at 40 °C.The protocol was also highly effective at large scale and room temperature This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Related Products of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Related Products of 106-21-8

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Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Transition Metal Free Stannylation of Alkyl Halides: The Rapid Synthesis of Alkyltrimethylstannanes was written by Li, Songyi;Lian, Chang;Yue, Guanglu;Zhang, Jianning;Qiu, Di;Mo, Fanyang. And the article was included in Journal of Organic Chemistry in 2022.Safety of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

A transition metal free stannylation reaction of alkyl bromides and iodides with hexamethyldistannane was developed. This protocol is operationally convenient and features a rapid reaction and good functional group tolerance. A wide range of functionalized primary and secondary alkyl and benzyl tri-Me stannanes were prepared in moderate to excellent yields. The success of the gram-scale procedure and tandem Stille coupling reaction has allowed this protocol to demonstrate potential for application in organic synthesis. Both exptl. and theor. studies reveal the mechanistic details of this stannylation reaction. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Safety of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Safety of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Total phenolic content of methanol extract from buni fruits (Antidesma bunius L.) water was written by Yasser, M.;Rafi, Mohamad;Wahyuni, Wulan Tri;Asfar, Andi Muhamad Iqbal Akbar;Widiyanti, Setyo Erna. And the article was included in Journal of Physics: Conference Series in 2020.Recommanded Product: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Buni Fruit Water was extracted with methanol solvent using Ultrasound technol. at a temperature of 50°C for 45 min. Total Phenolic Content contained in the methanol extract of buni fruits water is 67 mg / g in GAE. The results of interpretation using GCMS obtained three phenolic compounds, namely 3-(Hydrazinomethyl) Phenol, 5 Allyl-2 Methoxy Phenol and 3 (3,5-di-Tertier Bu, 4-Hydroxyphenyl) Propionic Acid. IR Spectrum anal. results obtained aromatic and OH group as a marker of the presence of phenolic compounds These results indicate that the Buni fruit water can be developed as functional food. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Recommanded Product: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Recommanded Product: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts