Category: 106-21-8

Simple H₂-free hydrogenation of unsaturated monoterpenoids catalyzed by Raney nickel was written by Philippov, Alexey A.;Chibiryaev, Andrey M.;Martyanov, Oleg N.. And the article was included in Mendeleev Communications in 2019.Application of 106-21-8 The following contents are mentioned in the article:

A series of monoterpenoids (citral, carvone, menthone, camphor) as well as cyclohexanone and hex-5-en-2-one were subjected to transfer hydrogenation with PrⁱOH/Raney nickel system at 82 or 150 °C. Among monoterpenoids, citral and carvone underwent full conversion at 82 °C within 5 h. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application of 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. The most common reactions of alcohols can be classified as oxidation, dehydration, substitution, esterification, and reactions of alkoxides.Application of 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Silver-catalyzed remote Csp³-H functionalization of aliphatic alcohols was written by Zhu, Yuchao;Huang, Kaimeng;Pan, Jun;Qiu, Xu;Luo, Xiao;Qin, Qixue;Wei, Jialiang;Wen, Xiaojin;Zhang, Lizhi;Jiao, Ning. And the article was included in Nature Communications in 2018.HPLC of Formula: 106-21-8 The following contents are mentioned in the article:

Herein, a silver-catalyzed δ-selective Csp³-H bond functionalization of abundant and inexpensive aliphatic alcs is reported. Valuable oximonitrile substituted alcs. I (R = Et, n-Bu, Bn, etc.) are easily obtained by using well-designed sulfonyl reagents under simple and mild conditions. This protocol realizes the challenging δ-selective C-C bond formation of simple alkanols. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8HPLC of Formula: 106-21-8).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. A strong base can deprotonate an alcohol to yield an alkoxide ion (R―O−). For example, sodamide (NaNH2), a very strong base, abstracts the hydrogen atom of an alcohol. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.HPLC of Formula: 106-21-8

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Rh(III)-Catalyzed three-component C-H functionalization reaction with vinylene carbonate: Late-stage C-H esterification of indole derivatives was written by Li, Bin-Shi;Guo, Huai-Xuan;Sun, Wei;Sun, Meng. And the article was included in Tetrahedron Letters in 2022.Name: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

An efficient and robust Rh(III)-catalyzed three-component C-H esterification reaction of indole derivatives with vinylene carbonate to access indolyl acetates was developed. This protocol exhibited high efficiency, good yields and excellent functional group tolerance. Significantly, this method provided a powerful approach for the late-stage modification of indole-based substrates and natural alcs. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Name: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Secondary alcohols are easily oxidized without breaking carbon-carbon bonds only as far as the ketone stage. No further oxidation is seen except under very stringent conditions.Name: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Continuous flow Reductive Alkylation of Methanol by Aldehydes. Synthesis of O-Methyl Ethers and 1,1-Dimethoxyacetals was written by Radjagobalou, Robbie;Rouffeteau, Virgile;Deleu, Alexia;Nabokoff, Pierre;Cossy, Janine;Len, Christophe. And the article was included in Molecular Catalysis in 2022.Application In Synthesis of 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

A mild and efficient continuous-flow catalytic reductive alkylation of methanol by various linear and branched aliphatic aldehydes, at 140°C, using a Pd/C cartridge (1 wt% – 5 wt%) under 1 bar of hydrogen, was developed to produce O-Me ethers in high yields and tolyl derivatives from aryl aldehydes. When the pourcentage of Pd/C was lower than 1 wt%, 1,1-dimethoxyacetals were obtained from aldehydes. To rationalize these results, a mechanism was proposed. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Application In Synthesis of 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. Under carefully controlled conditions, simple alcohols can undergo intermolecular dehydration to give ethers. This reaction is effective only with methanol, ethanol, and other simple primary alcohols.Application In Synthesis of 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Anionic Amphiphilic Cyclodextrins Bearing Oleic Grafts for the Stabilization of Ruthenium Nanoparticles Efficient in Aqueous Catalytic Hydrogenation was written by Cocq, Aurelien;Leger, Bastien;Noel, Sebastien;Bricout, Herve;Djedaini-Pilard, Florence;Tilloy, Sebastien;Monflier, Eric. And the article was included in ChemCatChem in 2020.Name: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Oleic succinyl β-cyclodextrin was proved to be efficient for the stabilization of ruthenium nanoparticles (NPs) in aqueous medium. The catalytic activity of these NPs was evaluated in the aqueous hydrogenation of petrosourced and biosourced unsaturated compounds such as benzene and furfural derivatives The catalytic system can be easily recycled and reused up to nine runs without any loss of activity and selectivity, demonstrating its robustness. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Name: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Under appropriate conditions, inorganic acids also react with alcohols to form esters. To form these esters, a wide variety of specialized reagents and conditions can be used. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Name: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

N,N-Dimethylformamide-stabilized ruthenium nanoparticle catalyst for β-alkylated dimer alcohol formation via Guerbet reaction of primary alcohols was written by Nagata, Tatsuki;Okada, Kanji;Kondo, Ryota;Toyao, Takashi;Shimizu, Ken-ichi;Suzuki, Takeyuki;Obora, Yasushi. And the article was included in RSC Advances in 2022.Formula: C10H22O The following contents are mentioned in the article:

N,N-Dimethylformamide-stabilized Ru nanoparticles (NPs) provided a highly efficient catalyst for the Guerbet reaction of primary alcs. DMF-modified Ru NPs were synthesized, and characterized by transition electron microscopy, and X-ray absorption spectroscopy, XPS, and Fourier-transform IR spectroscopy. The Ru NP catalyst was highly durable during catalytic reactions under external additive/solvent-free conditions. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Similar to water, an alcohol can be pictured as having an sp3 hybridized tetrahedral oxygen atom with nonbonding pairs of electrons occupying two of the four sp3 hybrid orbitals. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Metal-Free, Visible-Light-Induced Selective C-C Bond Cleavage of Cycloalkanones with Molecular Oxygen was written by Xin, Hong;Duan, Xin-Hua;Liu, Le;Guo, Li-Na. And the article was included in Chemistry – A European Journal in 2020.COA of Formula: C10H22O The following contents are mentioned in the article:

A metal-free, visible-light-induced oxidative C-C bond cleavage of cycloketones with mol. oxygen is described. Cooperative Bronsted-acid catalysis and photocatalysis enabled selective C-C bond cleavage of cycloketones to generate an array of γ, δ- and ε-keto esters under very mild conditions. Mechanistic studies indicate that singlet mol. oxygen (¹O₂) is responsible for this transformation. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8COA of Formula: C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. The oxygen atom of the strongly polarized O―H bond of an alcohol pulls electron density away from the hydrogen atom. This polarized hydrogen, which bears a partial positive charge, can form a hydrogen bond with a pair of nonbonding electrons on another oxygen atom. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.COA of Formula: C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

δ-C-H Halogenation Reactions Enabled by a Nitrogen-Centered Radical Precursor was written by Herron, Alastair N.;Hsu, Ching-Pei;Yu, Jin-Quan. And the article was included in Organic Letters in 2022.Name: 3,7-Dimethyloctan-1-ol The following contents are mentioned in the article:

Herein, new hydrazonyl carboxylic acids RN(S(O)₂R¹)N=C(Me)C(O)OH (R = octyl, 2-(adamantan-1-yl)ethyl, 4-methylpentyl, etc.; R¹ = 4-methylphenyl, 4-methoxyphenyl, 4-bromophenyl, 4-(trifluoromethyl)phenyl) precursor to nitrogen-centered radicals and its application toward remote C-H fluorination and chlorination reactions of sulfonyl-protected alkyl amines R¹S(O)₂NHR² (R² = 4-fluorooctyl, 2-(2-fluorocyclobutyl)ethyl, 4-fluoro-4-methylpentyl, etc.) via 1,5-HAT were disclosed. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Name: 3,7-Dimethyloctan-1-ol).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Because alcohols are easily synthesized and easily transformed into other compounds, they serve as important intermediates in organic synthesis. A multistep synthesis may use Grignard-like reactions to form an alcohol with the desired carbon structure, followed by reactions to convert the hydroxyl group of the alcohol to the desired functionality.Name: 3,7-Dimethyloctan-1-ol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Direct Synthesis of Mono-α-arylated Ketones from Alcohols and Olefins via Ni-Catalyzed Oxidative Cross-Coupling was written by Yang, Peng-Fei;Shu, Wei. And the article was included in Organic Letters in 2020.Computed Properties of C10H22O The following contents are mentioned in the article:

Controlled synthesis of α-monoarylated ketones is significant yet challenging due to the site-selectivity issues and nonproductive overarylation reactions. Herein, we reported the direct synthesis of α-arylated ketones enabled by Ni-catalyzed dehydrogenative cross-coupling reaction cascade between alcs. and olefins. The use of readily available and cost-effective alcs. and olefins provides a straightforward access to monoarylated ketones in good yields with exclusive selectivity without using any advanced synthetic intermediates. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Computed Properties of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Converting an alcohol to an alkene requires removal of the hydroxyl group and a hydrogen atom on the neighbouring carbon atom. Dehydrations are most commonly carried out by warming the alcohol in the presence of a strong dehydrating acid, such as concentrated sulfuric acid.Computed Properties of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Manganese-Catalyzed Dual-Deoxygenative Coupling of Primary Alcohols with 2-Arylethanols was written by Wang, Yujie;Shao, Zhihui;Zhang, Kun;Liu, Qiang. And the article was included in Angewandte Chemie, International Edition in 2018.Synthetic Route of C10H22O The following contents are mentioned in the article:

Reported herein is a general and efficient dual-deoxygenative coupling of primary alcs. with 2-arylethanols catalyzed by a well-defined Mn/PNP pincer complex. This reaction is the first example of the catalytic dual-deoxygenation of alcs. using a non-noble-metal catalyst. Both deoxygenative homocoupling of 2-arylethanols (17 examples) and their deoxygenative cross-coupling with other primary alcs. (20 examples) proceeded smoothly to form the corresponding alkenes by a dehydrogenation and deformylation reaction sequence. This study involved multiple reactions and reactants, such as 3,7-Dimethyloctan-1-ol (cas: 106-21-8Synthetic Route of C10H22O).

3,7-Dimethyloctan-1-ol (cas: 106-21-8) belongs to alcohols. Alkyl halides are often synthesized from alcohols, in effect substituting a halogen atom for the hydroxyl group. Tertiary alcohols cannot be oxidized at all without breaking carbon-carbon bonds, whereas primary alcohols can be oxidized to aldehydes or further oxidized to carboxylic acids.Synthetic Route of C10H22O

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts