Category: 105-13-5

Quality Control of (4-Methoxyphenyl)methanol. Authors Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S in PERGAMON-ELSEVIER SCIENCE LTD published article about in [Cavallo, Marzia; Arnodo, Davide; Mannu, Alberto; Blangetti, Marco; Prandi, Cristina; Baldino, Salvatore] Dipartimento Chim, Via P Giuria 7, I-10125 Turin, Italy; [Baratta, Walter] Univ Udine, Dipartimento DI4A, Via Cotonificio 108, I-33100 Udine, Italy in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

The employment of easily affordable ruthenium(II)-complexes as pre-catalysts in the transfer hydrogenation of carbonyl compounds in deep eutectic media is described for the first time. The eutectic mixture tetrabutylammonium bromide/formic acid = 1/1 (TBABr/HCOOH = 1/1) acts both as reaction medium and hydrogen source. The addition of a base is required for the process to occur. An extensive optimization of the reaction conditions has been carried out, in terms of catalyst loading, type of complexes, H-2-donors, reaction temperature and time. The combination of the dimeric complex [RuCl(p-cymene)-mu-Cl](2) (0.01-0.05 eq.) and the ligand dppf (1,10-ferrocenediyl-bis(diphenylphosphine)ferrocene) in 1/1 molar ratio has proven to be a suitable catalytic system for the reduction of several and diverse aldehydes and ketones to their corresponding alcohols under mild conditions (40-60 degrees C) in air, showing from moderate to excellent tolerability towards different functional groups (halogen, cyano, nitro, phenol). The reduction of imine compounds to their corresponding amine derivatives was also studied. In addition, the comparison between the results obtained in TBABr/HCOOH and in organic solvents suggests a non-innocent effect of the DES medium during the process. (C) 2021 Elsevier Ltd. All rights reserved.

Quality Control of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Cavallo, M; Arnodo, D; Mannu, A; Blangetti, M; Prandi, C; Baratta, W; Baldino, S or send Email.

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Recommanded Product: 105-13-5. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

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Recently I am researching about NICKEL FERRITE NANOPARTICLES; AEROBIC OXIDATION; MAGNETIC NANOPARTICLES; MECHANISM; ALDEHYDES; EFFICIENT; LIGAND, Saw an article supported by the Research Council of Ahvaz Branch, Islamic Azad University, Ahvaz, Iran. Recommanded Product: (4-Methoxyphenyl)methanol. Published in ELSEVIER in AMSTERDAM ,Authors: Mehrjoyan, F; Afshari, M. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

A new magnetically recoverable catalyst consisting of phenanthroline Cu(II) complex supported on nickel ferrite nanoparticles was prepared. The synthesized catalyst was characterized by Fourier transform in-frared spectroscopy, X-ray diffraction, transmission and scanning electron microscopes, thermogravimetry, energy dispersive X-ray spectroscopy, vibrating sample magnetometry and inductively coupled plasma. Supported copper complex used for solvent free oxidation of 1-phenyl ethanol as a model. Influence of the reaction parameters (kind of oxidant, amount of the catalyst, reaction time, solvent and reaction temperature) were studied. Because of the immobilized complex has been shown to be an efficient het-erogeneous catalyst for the selective oxidation of 1-phenyl ethanol to acetophenone (94% yield) by hydro-gen peroxide so this green approach extended to other benzylic alcohols. The catalyst had been reused 10 times with no significant loss of catalytic activity. SEM, EDX, XRD, and ICP analysis of reused catalyst indicated that the catalyst was stable after the reaction. (c) 2021 Published by Elsevier B.V.

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SDS of cas: 105-13-5. Authors Uygur, M; Kuhlmann, JH; Perez-Aguilar, MC; Piekarski, DG; Mancheno, OG in ROYAL SOC CHEMISTRY published article about in [Uygur, Mustafa; Kuhlmann, Jan H.; Perez-Aguilar, Maria Carmen; Piekarski, Dariusz G.; Mancheno, Olga Garcia] Westfalische Wilhelms Univ Munster, Organ Chem Inst, Correnstr 36, D-48149 Munster, Germany; [Piekarski, Dariusz G.] Polish Acad Sci, Inst Phys Chem, Kasprzaka 44-52, PL-01224 Warsaw, Poland in 2021, Cited 80. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

A metal- and additive-free methodology for the highly selective, photocatalyzed C-H oxygenation of alkylarenes under air to the corresponding carbonyls is presented. The process is catalyzed by an imide-acridinium that forms an extremely strong photooxidant upon visible light irradiation, which is able to activate inert alkylarenes such as toluene. Hence, this is an easy to perform, sustainable and environmentally friendly oxidation that provides valuable carbonyls from abundant, readily available compounds.

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Application In Synthesis of (4-Methoxyphenyl)methanol. In 2021 J ORG CHEM published article about ALLYLATION; ALDEHYDES in [Botubol-Ares, Jose Manuel; Jesus Duran-Pena, Maria] Univ Cadiz, Fac Ciencias, Dept Quim Organ, Campus Univ Rio San Pedro S-N,4a Planta, Cadiz 11510, Spain; [Chahboun, Rachid; Jimenez, Fermin; Alvarez-Manzaneda, Enrique] Univ Granada, Fac Ciencias, Inst Biotecnol, Dept Quim Organ, Granada 18071, Spain; [Alvarez-Manzaneda, Ramon] Univ Almeria, Dept Quim & Fis, Area Quim Organ, Almeria 04120, Spain in 2021, Cited 37. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A general and efficient method for the deconjugative alpha-alkylation of alpha,beta-unsaturated aldehydes promoted by a synergistic effect between (BuOK)-Bu-t and NaH, which considerably increases the reaction rate under mild conditions, is reported. The beta,gamma-unsaturated aldehyde, resulting from the alpha-alkylation, is transformed in high yield into the corresponding allyl acetate via a lead(IV) acetate-mediated oxidative fragmentation. This strategy could be used for the construction of the carbon skeleton of a wide variety of alkyl or arylterpenoids.

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Authors Ghosh, R; Jana, NC; Panda, S; Bagh, B in AMER CHEMICAL SOC published article about in [Ghosh, Rahul; Jana, Narayan Ch; Panda, Surajit; Bagh, Bidraha] HBNI, Natl Inst Sci Educ & Res NISER, Sch Chem Sci, Bhubaneswar 752050, Odisha, India in 2021, Cited 111. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Coordination of 1,4-disubstituted 1,2,3-triazoles L-1 and L-2 with [(p-cymene)RuCl2](2) followed by dehydrochlorination in the presence of a base resulted in the formation of complexes 1 and 2, respectively. Both were tested for the transfer hydrogenation of aldehydes and ketones in air using ecologically benign and cheap ethanol as the hydrogen source in the presence of a catalytic amount of a base. Air-stable complex 1 was proved to be an active catalyst for the transfer hydrogenation of a wide variety of aromatic and aliphatic aldehydes and ketones bearing various functionalities. Catalyst 1 was also effective for the transfer hydrogenation of carbonyls using the simplest primary alcohol, methanol, under aerobic conditions. Under the present catalytic protocol, labile or reducible functionalities such as nitro, cyano, and ester groups were tolerated. Good selectivity was also observed for acyclic alpha,beta-unsaturated carbonyls. However, this catalytic protocol was not selective for 2-cyclohexen-1-one as both alkene and keto moieties were reduced. The transfer hydrogenations are believed to proceed via a ruthenium-hydride intermediate. Finally, transfer hydrogenation of acetophenone using isopropanol as a commonly used hydrogen source was also performed and the sustainable and green credentials of these catalytic protocols utilizing methanol, ethanol, and isopropanol were compared with the help of the CHEM21 green metrics toolkit.

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Aarsetoy, R; Ueland, T; Aukrust, P; Michelsen, AE; de la Fuente, RL; Ponitz, V; Brugger-Andersen, T; Grundt, H; Staines, H; Nilsen, DWT in [Aarsetoy, Reidun; Ponitz, Volker; Brugger-Andersen, Trygve; Nilsen, Dennis W. T.] Stavanger Univ Hosp, Dept Cardiol, POB 8100, N-4068 Stavanger, Norway; [Aarsetoy, Reidun; Grundt, Heidi; Nilsen, Dennis W. T.] Univ Bergen, Dept Clin Sci, Bergen, Norway; [Ueland, Thor; Aukrust, Pal; Michelsen, Annika E.] Oslo Univ Hosp, Res Inst Internal Med, Rikshosp, Oslo, Norway; [Aukrust, Pal] Oslo Univ Hosp, Sect Clin Immunol & Infect Dis, Rikshosp, Oslo, Norway; [de la Fuente, Ricardo Leon] Ctr Cardiovasc Salta, Salta, Argentina; [Grundt, Heidi] Stavanger Univ Hosp, Dept Resp Med, Stavanger, Norway; [Staines, Harry] Sigma Stat Serv, Balmullo, Scotland published Angiopoietin-2 and angiopoietin-like 4 protein provide prognostic information in patients with suspected acute coronary syndrome in , Cited 34. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Background Plasma levels of angiopoietin-2 (ANGPT2) and angiopoietin-like 4 protein (ANGPTL4) reflect different pathophysiological aspects of cardiovascular disease. We evaluated their association with outcome in a hospitalized Norwegian patient cohort (n = 871) with suspected acute coronary syndrome (ACS) and validated our results in a similar Argentinean cohort (n = 982). Methods A cox regression model, adjusting for traditional cardiovascular risk factors, was fitted for ANGPT2 and ANGPTL4, respectively, with all-cause mortality and cardiac death within 24 months and all-cause mortality within 60 months as the dependent variables. Results At 24 months follow-up, 138 (15.8%) of the Norwegian and 119 (12.1%) of the Argentinian cohort had died, of which 86 and 66 deaths, respectively, were classified as cardiac. At 60 months, a total of 259 (29.7%) and 173 (17.6%) patients, respectively, had died. ANGPT2 was independently associated with all-cause mortality in both cohorts at 24 months [hazard ratio (HR) 1.27 (95% confidence interval (CI), 1.08-1.50) for Norway, and HR 1.57 (95% CI, 1.27-1.95) for Argentina], with similar results at 60 months [HR 1.19 (95% CI, 1.05-1.35) (Norway), and HR 1.56 (95% CI, 1.30-1.88) (Argentina)], and was also significantly associated with cardiac death [HR 1.51 (95% CI, 1.14-2.00)], in the Argentinean population. ANGPTL4 was significantly associated with all-cause mortality in the Argentinean cohort at 24 months [HR 1.39 (95% CI, 1.15-1.68)] and at 60 months [HR 1.43 (95% CI, 1.23-1.67)], enforcing trends in the Norwegian population. Conclusions ANGPT2 and ANGPTL4 were significantly associated with outcome in similar ACS patient cohorts recruited on two continents. Clinical Trial Registration ClinicalTrials.gov Identifier: NCT00521976. ClinicalTrials.gov Identifier: NCT01377402.

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I found the field of Chemistry very interesting. Saw the article SBA-15 Supported 1-Methyl-2-azaadamanane N-Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcohol published in 2021. Application In Synthesis of (4-Methoxyphenyl)methanol, Reprint Addresses Li, MC; Li, CM; Shen, ZL (corresponding author), Zhejiang Univ Technol, Coll Chem Engn, Hangzhou 310014, Peoples R China.; Li, CM (corresponding author), Shaoxing Univ, Sch Chem & Chem Engn, Zhejiang Key Lab Alternat Technol Fine Chem Proc, Shaoxing 312000, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Herein, we designed and synthesized an SBA-15 supported 1-methyl-2-azaadamanane N-oxyl (1-Me-AZADO) and investigated its catalytic performance for selective oxidation of alcohols under Anelli’s conditions. The first example of immobilization of 1-Me-AZADO was very important to advance the oxgenation effectively because this supported N-oxyl has excellent catalytic activity for oxidation of alcohols to carbonyl compounds, and more importantly, it can be conveniently recovered and reused at least 6 times without significant effect on its catalytic efficiency.

Welcome to talk about 105-13-5, If you have any questions, you can contact Tian, YW; Guo, XQ; Li, MC; Li, CM; Hu, XQ; Jin, LQ; Sun, N; Hu, BX; Shen, ZL or send Email.. Application In Synthesis of (4-Methoxyphenyl)methanol

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SDS of cas: 105-13-5. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

SDS of cas: 105-13-5. Welcome to talk about 105-13-5, If you have any questions, you can contact Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF or send Email.

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Application In Synthesis of (4-Methoxyphenyl)methanol. In 2021 J SUPERCRIT FLUID published article about CARBON-DIOXIDE EXTRACTION; FLUID EXTRACTION; ANTIOXIDANT ACTIVITY; CHEMICAL-COMPOSITION; FRACTIONATION; PERFORMANCE; VOLATILES; KINETICS; LUPEOL; LINK in [Casas, Maria P.; Lopez-Hortas, Lucia; Moure, Andres; Dominguez, Herminia] Univ Vigo, Dept Chem Engn, CINBIO, Campus Ourense,Edificio Politen, Orense 32004, Spain; [Diaz-Reinoso, Beatriz] Univ Vigo, CITI, Parque Tecnol Galicia,Rua Galicia 2, Orense 32900, Spain in 2021, Cited 38. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Supercritical CO2 was used for the production of extracts from Acacia dealbata flowers. Pressures from 10 to 35 MPa and temperatures from 35? to 55?C were studied to assess their influence on the yield, antiradical properties and composition of the volatiles. The use of ethanol as modifier was also evaluated. Operating at 30 MPa and 45 ?C with 10% ethanol, up to 15% of the ethanol extractables were obtained in 3 h. The selectivity towards alcohol type compounds decreased with time and was enhanced in a sequence of static extraction with pure and ethanol modified CO2 followed by a dynamic stage. The most active fractions showed ABTS radical scavenging activity of 0.22 g Trolox/g extract. Different mathematical models were used to describe the kinetic data. The most abundant compounds in the supercritical extracts were oxygenated triterpenes whereas in conventional ethanolic extracts the main constituents were aliphatic compounds.

Application In Synthesis of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Casas, MP; Lopez-Hortas, L; Diaz-Reinoso, B; Moure, A; Dominguez, H or send Email.

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