Category: 105-13-5

I found the field of Chemistry very interesting. Saw the article Novel oxovanadium and dioxomolybdenum complexes of tridentate ONO-donor Schiff base ligand: Synthesis, characterization, crystal structures, Hirshfeld surface analysis, DFT computational studies and catalytic activity for the selective oxidation of benzylic alcohols published in 2021. Recommanded Product: (4-Methoxyphenyl)methanol, Reprint Addresses Kargar, H (corresponding author), Ardakan Univ, Dept Chem Engn, Fac Engn, POB 184, Ardakan, Iran.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Two new oxovanadium and dioxomolybdenum Schiff base complexes, [VvO(L)(OCH3)(CH3OH)] and [MoVIO2(L) (CH2CH3OH)], were synthesized by treating an ONO-donor type Schiff base ligand (H2L) derived by condensation of 5-nitrosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)2 and MoO2(acac)2], respectively. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, multinuclear (1H, 13C) NMR, elemental analysis and the most authentic single crystal X-ray diffraction analysis. In both complexes the geometry around the central metal ions was distorted octahedral as revealed by the data collected from diffraction studies. Theoretical calculation of the synthesized compounds were carried out by DFT as well as TD-DFT using B3LYP method by employing the Def2-TZVP basis set. The findings of theoretical data indicated that the calculated results are in accordance with the experimental findings. Moreover, the catalytic efficiencies of both complexes were investigated by oxidizing the benzylic alcohols in the presence of urea hydrogen peroxide (UHP) in acetonitrile.

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Sakai, N; Shimada, R; Ogiwara, Y in [Sakai, Norio; Shimada, Retsu; Ogiwara, Yohei] Tokyo Univ Sci RIKADAI, Fac Sci & Technol, Dept Pure & Appl Chem, Noda, Chiba 2788510, Japan published Indium-Catalyzed Deoxygenation of Sulfoxides with Hydrosilanes in 2021, Cited 75. Category: alcohols-buliding-blocks. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Described herein is that a novel InBr3/PhSiH3 reducing system in a 1,4-dioxane solution smoothly and effectively undertook deoxygenation of a variety of sulfoxides leading to the facile preparation of sulfide derivatives. Also, it was demonstrated that the reducing system shows a higher reactivity towards sulfoxides than that towards commonly reducible functional groups, such as carboxylic acids, esters, amides, and sulfones.

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An article Iron-Catalyzed Regioselective Alkenylboration of Olefins WOS:000591817800001 published article about ENANTIOSELECTIVE ARYLBORATION; ALKENES; HYDROBORATION; SCOPE; DICARBOFUNCTIONALIZATION; MECHANISM; SECONDARY; ACCESS; BORYL in [Yu, Xiaolong; Zheng, Hongling; Zhao, Haonan; Lee, Boon Chong; Koh, Ming Joo] Natl Univ Singapore, Dept Chem, 12 Sci Dr 2, Singapore 117549, Singapore in 2021, Cited 70. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. SDS of cas: 105-13-5

The first examples of an iron-catalyzed three-component synthesis of homoallylic boronates from regioselective union of bis(pinacolato)diboron, an alkenyl halide (bromide, chloride or fluoride), and an olefin are disclosed. Products that bear tertiary or quaternary carbon centers could be generated in up to 87 % yield as single regioisomers with complete retention of the olefin stereochemistry. With cyclopropylidene-containing substrates, ring cleavage leading to trisubstituted E-alkenylboronates were selectively obtained. Mechanistic studies revealed reaction attributes that are distinct from previously reported alkene carboboration pathways.

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Recommanded Product: (4-Methoxyphenyl)methanol. Tao, J; Jatoi, A; Crawford, J; Lam, WWT; Ho, JC; Wang, XF; Pang, H in [Tao, Jun; Lam, Wendy W. T.; Pang, Herbert] Univ Hong Kong, Li Ka Shing Fac Med, Sch Publ Hlth, Hong Kong, Peoples R China; [Jatoi, Aminah] Mayo Clin, Dept Oncol, Rochester, MN USA; [Crawford, Jeffrey] Duke Univ, Med Ctr, Duke Canc Inst, Durham, NC USA; [Ho, James C.] Univ Hong Kong, Li Ka Shing Fac Med, Dept Med, Hong Kong, Peoples R China; [Wang, Xiaofei; Pang, Herbert] Duke Univ, Sch Med, Dept Biostat & Bioinformat, Durham, NC USA; [Lam, Wendy W. T.] Univ Hong Kong, Jockey Club Inst Canc Care, Hong Kong, Peoples R China published Role of dietary carbohydrates on risk of lung cancer in 2021, Cited 53. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Objectives: Inconsistent findings have been reported on the link between dietary carbohydrates and lung cancer. This study aims to comprehensively evaluate the role of dietary carbohydrates on lung cancer risk. Materials and methods: The prospective study is based on the PLCO trial, which recruited 113,096 eligible participants across the United States. Participants had to have completed baseline and diet history questionnaires. The incidence of lung cancer was acquired through self-report and medical record follow-up. A multivariable logistic model adjusted for confounders was used to estimate odds ratios (ORs) and 95 % confidence intervals (CIs) of dietary carbohydrates, fiber, whole grains, glycemic index (GI) and glycemic load (GL) for lung cancer. Similar methods were applied in analyzing the carbohydrates and fiber from different food sources. Multinomial logistic models were used for sensitivity analysis with lung cancer subtypes as outcomes. Results: Dietary carbohydrates and GL were inversely associated with lung cancer incidence in the PLCO population. Among various carbohydrates, 30-g daily consumption of dietary fiber was related to a lower risk of lung cancer (fourth vs first quartile OR: 0.62, 95 % CI: 0.54-0.72) compared with 8.8-g. Furthermore, consuming whole grains 2.3 servings per day as opposed to 0.3 servings per day was associated with a lower risk of lung cancer (OR: 0.73, 95 % CI: 0.64-0.83). A higher risk of lung cancer was seen for the consumption of high-GI food (OR: 1.19, 95 % CI: 1.05?1.35) and refined carbohydrates from soft drinks (OR: 1.23, 95 % CI: 1.04?1.46). Conclusion: Carbohydrates and fiber from fruits, vegetables and whole grains are associated with lower lung cancer risk. Refined carbohydrates from processed food, such as soft drinks, appear to increase risk.

Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Tao, J; Jatoi, A; Crawford, J; Lam, WWT; Ho, JC; Wang, XF; Pang, H or send Email.

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Authors Wang, K; Chen, H; Dai, XY; Huang, XP; Feng, ZQ in ROYAL SOC CHEMISTRY published article about CASCADE SYNTHESIS; QUINAZOLINONES; SYSTEM; 4(3H)-QUINAZOLINONES; 2-NITROBENZAMIDES; AMINOBENZAMIDES; CYCLIZATION; CHEMISTRY; EFFICIENT; STRATEGY in [Wang, Ke; Chen, Hao; Dai, Xinyan; Huang, Xupeng; Feng, Zhiqiang] Chinese Acad Med Sci & Peking Union Med Coll, Inst Mat Med, Beijing Key Lab Act Subst Discovery & Drugabil Ev, 1 Xiannongtan St, Beijing 100050, Peoples R China in 2021, Cited 41. COA of Formula: C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Palladium-catalyzed 2-substituted quinazolin-4(3H)-one formation from readily available o-nitrobenzamides and alcohols using hydrogen transfer is described. Various quinazolin-4(3H)-ones were obtained in good to high yields. The cascade reaction including alcohol oxidation, nitro reduction, condensation, and dehydrogenation occurs without any added reducing or oxidizing agent.

Welcome to talk about 105-13-5, If you have any questions, you can contact Wang, K; Chen, H; Dai, XY; Huang, XP; Feng, ZQ or send Email.. COA of Formula: C8H10O2

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An article Ultrasmall amphiphilic zeolitic nanoreactors for the aerobic oxidation of alcohols in water WOS:000649428200001 published article about METAL-ORGANIC FRAMEWORK; SELECTIVE OXIDATION; SOLID NANOPARTICLES; CATALYZED REACTIONS; PHASE INVERSION; EMULSIONS; PARTICLES; INTERFACE; CLUSTERS; SIZE in [Jing, Wendan; Li, Hui; Liu, Bolun; Wang, Runwei; Qiu, Shilun; Zhang, Zongtao] Jilin Univ, State Key Lab Inorgan Synth & Preparat Chem, Changchun 130012, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] PetroChina, Res Inst Petr Explorat & Dev, Beijing 100083, Peoples R China; [Xiao, Peiwen; Luo, Jianhui] CNPC, Key Lab Nano Chem KLNC, Beijing 100083, Peoples R China in 2021, Cited 43. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Quality Control of (4-Methoxyphenyl)methanol

Organic reactors in a green solvent (water) is the goal of sustainable development. Green nanoreactors with excellent amphiphilicity and catalytic activity are strongly desired. Herein, a novel amphiphilic nanoreactor Pd@amZSM-5 with ultrasmall size has been successfully synthesized via a simple one-step oil bath method, subjected to the modification-etching-modification strategy and in situ reduction of Pd2+. Ultrasmall Pd@amZSM-5 nanoreactors (60 nm) with hierarchical structures showed outstanding amphiphilicity for forming Pickering emulsions with fine uniform droplets (50 mu m). Fine droplets formed short diffusion distances, which can significantly improve the catalytic activity in biphasic reactions. Moroever, the ultrasmall Pd@amZSM-5 nanoreactors demonstrated excellent catalytic activity for the selective oxidation of alcohols in water using air as the oxidant. Alkali was not present in the reaction system. The hydrophilic aminopropyl groups on the surface of the Pd@amZSM-5 nanoreactors not only changed the affinity of the zeolite surface and provided targeting points for Pd nanoparticles but also provided an alkaline environment for the selective oxidation of alcohols. The ultrasmall Pd@amZSM-5 nanoreactors presented excellent universality for aromatic alcohols (with >90% conversion and >90% selectivity) and allylic alcohols (with 100% conversion and 100% selectivity).

Quality Control of (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Jing, WD; Li, H; Xiao, PW; Liu, BL; Luo, JH; Wang, RW; Qiu, SL; Zhang, ZT or send Email.

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In 2021 POLYHEDRON published article about ONE-POT SYNTHESIS; SELECTIVE ALKYLATION; EFFICIENT; COMPLEX; ANILINES; SUBSTITUTION; OXIDATION; AMIDES in [Feng, Xinshu; Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Guangzhou 510006, Peoples R China in 2021, Cited 40. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

A series of air-stable N-heterocyclic carbene (NHC) Ir(III) complexes (Ir1-6), bearing various combinations of chlorine, pyridine and NHC ligands, were assayed for the N-alkylation of amines with alcohols. It was found that Ir3, with two monodentate 1,3-bis-methyl-imidazolylidene (IMe) ligands, emerged as the most active complex. A large variety of amines and primary alcohols were efficiently converted into mono-N-alkylated amines in 53-96% yields. As a special highlight, for the challenging MeOH, selective N-monomethylation could be achieved using KOH as a base under an air atmosphere. Moreover, this catalytic system was successfully applied to the gram-scale synthesis of some valuable compounds. (C) 2021 Elsevier Ltd. All rights reserved.

Category: alcohols-buliding-blocks. Welcome to talk about 105-13-5, If you have any questions, you can contact Feng, XS; Huang, M or send Email.

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Recently I am researching about AEROBIC OXIDATION; BENZYLIC ALCOHOLS; C-H; COPPER; ALDEHYDES; MILD, Saw an article supported by the . Published in PERGAMON-ELSEVIER SCIENCE LTD in OXFORD ,Authors: Kargar, H; Bazrafshan, M; Fallah-Mehrjardi, M; Behjatmanesh-Ardakani, R; Rudbari, HA; Munawar, KS; Ashfaq, M; Tahir, MN. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Recommanded Product: (4-Methoxyphenyl)methanol

For the first time, two new oxovanadium and dioxomolybdenum Schiff base complexes, VOL(OMe) and MoO2L, were synthesized through the reaction of a ONO tridentate Schiff base ligand (H2L) derived from the condensation of 5-bromosalicylaldehyde and nicotinic hydrazide with oxo and dioxo acetylacetonate salts of vanadium and molybdenum, [VO(acac)(2) and MoO2(acac)2], respectively. The synthesized ligand and complexes were characterized by various spectroscopic techniques like FT-IR, H-1 NMR, C-13 NMR, elemental analysis (CHN) and the most authentic single crystal X-ray diffraction analysis (SC-XRD). The geometry around the central metal ion in MoO2L was distorted octahedral as revealed by the data collected from diffraction studies. Non-covalent interactions that are responsible for crystal packing are explored by Hirshfeld surface analysis. Theoretical calculations of the synthesized compounds, carried out by DFT at B3LYP/Def2-TZVP level of theory, indicated that the calculated results are in agreement with the experimental findings. Moreover, the catalytic activities of both complexes were investigated for the selective oxidation of benzylic alcohols using urea hydrogen peroxide (UHP) in acetonitrile. (C) 2021 Elsevier Ltd. All rights reserved.

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An article Highly Enantioselective Ring-Opening of meso-Epoxides with O- and N-Nucleophiles Catalyzed by a Chiral Sc(III)/bipyridine Complex WOS:000613421500001 published article about SCANDIUM TRIFLATE; EFFICIENT in [Malatinec, Stefan; Bednarova, Eva; Tanaka, Hiroki; Kotora, Martin] Charles Univ Prague, Fac Sci, Dept Organ Chem, Chem, Albertov 6, Prague 12843 2, Czech Republic; [Tanaka, Hiroki] Okayama Univ, Res Inst Interdisciplinary Sci, Kita Ku, 3-1-1 Tsushimanaka, Okayama 7008530, Japan in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Category: alcohols-buliding-blocks

The ring-opening of epoxides is a synthetically significant process widely applied in all kinds of chemistry. Herein, we report the catalytic and highly enantioselective variant of this reaction exploiting our recent endeavors to design and synthesize chiral bipyridine type ligands. A Sc-complex with a newly developed bipyridine ligand exhibited high reactivity and stereocontrol in the desymmetrization of meso-epoxides with various alcohols. The respective enantiomerically enriched 1,2-alkoxyalcohols were obtained with e.r. values of up to 99.5:0.5 for various alcohols regardless of their nature (benzyl, alkyl, cycloalkyl, allyl, propargyl, etc.). We attempted ring-opening of meso-epoxides with anilines as well; however, it proceeded with lower enantioselectivity and was strongly depended on the electronic effect of substituents attached to the aromatic ring.

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Recommanded Product: (4-Methoxyphenyl)methanol. Biriukov, KO; Vinogradov, MM; Afanasyev, OI; Vasilyev, DV; Tsygankov, AA; Godovikova, M; Nelyubina, YV; Loginov, DA; Chusov, D in [Biriukov, Klim O.; Vinogradov, Mikhail M.; Afanasyev, Oleg, I; Tsygankov, Alexey A.; Godovikova, Maria; Nelyubina, Yulia, V; Loginov, Dmitry A.; Chusov, Denis] Russian Acad Sci INEOS RAS, AN Nesmeyanov Inst Organoelement Cpds, Vavilova St 28, Moscow, Russia; [Vasilyev, Dmitry V.] Forschungszentrum Julich, Helmholtz Inst Erlangen Nurnberg Renewable Energy, Egerlandstr 3, D-91058 Erlangen, Germany; [Loginov, Dmitry A.; Chusov, Denis] GV Plekhanov Russian Univ Econ, 36 Stremyanny Per, Moscow 117997, Russia published Carbon monoxide-driven osmium catalyzed reductive amination harvesting WGSR power in 2021, Cited 71. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Herein, we present the first example of Os-catalyzed efficient reductive amination under water-gas shift reaction conditions. The developed catalytic systems are formed in situ in aqueous solutions, employ as small as 0.0625 mol% osmium and are capable of delivering reductive amination products for a broad range of aliphatic and aromatic carbonyl compounds and amines. The scope of the reaction, active catalytic systems, possible limitations of the method and DFT-supported mechanistic considerations are discussed in detail in the manuscript.

Welcome to talk about 105-13-5, If you have any questions, you can contact Biriukov, KO; Vinogradov, MM; Afanasyev, OI; Vasilyev, DV; Tsygankov, AA; Godovikova, M; Nelyubina, YV; Loginov, DA; Chusov, D or send Email.. Recommanded Product: (4-Methoxyphenyl)methanol

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