Category: 105-13-5

An article The Detosylation of Chiral 1,2-Bis(tosylamides) WOS:000670661000054 published article about INNER-SPHERE PROCESSES; OUTER-SPHERE; QUANTITATIVE-EVALUATION; SULFONYL GROUP; DEPROTECTION; MAGNESIUM; REDUCTION; CLEAVAGE; ELEMENTS; LITHIUM in [Gaston, Jayden J.; Tague, Andrew J.; Smyth, Jamie E.; Butler, Nicholas M.; Yu, Haibo; Keller, Paul A.] Univ Wollongong, Sch Chem & Mol Biosci, Mol Horizons, Wollongong, NSW 2522, Australia; [Gaston, Jayden J.; Tague, Andrew J.; Smyth, Jamie E.; Butler, Nicholas M.; Yu, Haibo; Keller, Paul A.] Illawarra Hlth & Med Res Inst, Wollongong, NSW 2522, Australia; [Willis, Anthony C.] Australian Natl Univ, Sch Chem, Canberra, ACT 2601, Australia; [Hommes, Nico van Eikema; Clark, Timothy] Friedrich Alexander Univ Erlangen Nurnberg, Comp Chem Ctr, Dept Chem & Pharm, D-91052 Erlangen, Germany in 2021, Cited 52. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Formula: C8H10O2

The deprotection of chiral 1,2-bis(tosylamides) to their corresponding 1,2-diamines is mostly unsuccessful under standard conditions. In a new methodology, the use of Mg/MeOH with sufficient steric additions allows the facile synthesis of 1,2-diamines in 78-98% yields. These results are rationalized using density functional theory and the examination of inner and outer-sphere reduction mechanisms.

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HPLC of Formula: C8H10O2. Authors Huang, M; Li, YW; Lan, XB; Liu, JH; Zhao, CY; Liu, Y; Ke, ZF in ROYAL SOC CHEMISTRY published article about in [Huang, Ming] Guangdong Pharmaceut Univ, Sch Clin Pharm, Affiliated Hosp 1, Clin Pharm, Guangzhou 510006, Peoples R China; [Huang, Ming; Li, Yinwu; Lan, Xiao-Bing; Liu, Jiahao; Zhao, Cunyuan; Ke, Zhuofeng] Sun Yat Sen Univ, Sch Chem, PCFM Lab, Sch Mat Sci & Engn, Guangzhou 510275, Peoples R China; [Liu, Yan] Guangdong Univ Technol, Sch Chem Engn & Light Ind, Guangzhou 510006, Peoples R China in 2021, Cited 67. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Metal hydride complexes are key intermediates for N-alkylation of amines with alcohols by the borrowing hydrogen/hydrogen autotransfer (BH/HA) strategy. Reactivity tuning of metal hydride complexes could adjust the dehydrogenation of alcohols and the hydrogenation of imines. Herein we report ruthenium(s) complexes with hetero-bidentate N-heterocyclic carbene (NHC)-phosphine ligands, which realize smart pathway selection in the N-alkylated reaction via reactivity tuning of IRu-H) species by hetero-bidentate ligands. In particular, complex 6cb with a phenyl wingtip group and BArr counter anion, is shown to be one of the most efficient pre-catalysts for this transformation (temperature is as low as 70 degrees C, neat conditions and catalyst loading is as low as 0.25 mol%). A large variety of (hetero)aromatic amines and primary alcohols were efficiently converted into mono-N-alkylated amines in good to excellent isolated yields. Notably, aliphatic amines, challenging methanol and diamines could also be transformed into the desired products. Detailed control experiments and density functional theory (DFT) calculations provide insights to understand the mechanism and the smart pathway selection via [Ru-H] species in this process.

HPLC of Formula: C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Product Details of 105-13-5. Authors Li, WZ; Wang, ZX in ROYAL SOC CHEMISTRY published article about in [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, CAS Key Lab Soft Matter Chem, Hefei 230026, Anhui, Peoples R China; [Li, Wei-Ze; Wang, Zhong-Xia] Univ Sci & Technol China, Dept Chem, Hefei 230026, Anhui, Peoples R China; [Wang, Zhong-Xia] Collaborat Innovat Ctr Chem Sci & Engn, Tianjin 300072, Peoples R China in 2021, Cited 99. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

alpha-Alkylation of methyldiarylphosphine oxides with (hetero)arylmethyl alcohols was performed under nickel catalysis. Various arylmethyl and heteroarylmethyl alcohols can be used in this transformation. A series of methyldiarylphosphine oxides were alkylated with 30-90% yields. Functional groups on the aromatic rings of methyldiarylphosphine oxides or arylmethyl alcohols including OMe, NMe2, SMe, CF3, Cl, and F groups can be tolerated. The conditions are also suitable for the alpha-alkylation reaction of dialkyl methylphosphonates.

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Banik, A; Ahmed, J; Sil, S; Mandal, SK in [Banik, Ananya; Ahmed, Jasimuddin; Sil, Swagata; Mandal, Swadhin K.] Indian Inst Sci Educ & Res Kolkata, Dept Chem Sci, Mohanpur 741246, India published Mimicking transition metals in borrowing hydrogen from alcohols in 2021, Cited 68. Computed Properties of C8H10O2. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

Borrowing hydrogen from alcohols, storing it on a catalyst and subsequent transfer of the hydrogen from the catalyst to an in situ generated imine is the hallmark of a transition metal mediated catalytic N-alkylation of amines. However, such a borrowing hydrogen mechanism with a transition metal free catalytic system which stores hydrogen molecules in the catalyst backbone is yet to be established. Herein, we demonstrate that a phenalenyl ligand can imitate the role of transition metals in storing and transferring hydrogen molecules leading to borrowing hydrogen mediated alkylation of anilines by alcohols including a wide range of substrate scope. A close inspection of the mechanistic pathway by characterizing several intermediates through various spectroscopic techniques, deuterium labelling experiments, and DFT study concluded that the phenalenyl radical based backbone sequentially adds H+, H and an electron through a dearomatization process which are subsequently used as reducing equivalents to the C-N double bond in a catalytic fashion.

Computed Properties of C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Name: (4-Methoxyphenyl)methanol. Recently I am researching about METAL-ORGANIC FRAMEWORKS; SELECTIVE OXIDATION; AEROBIC OXIDATION; EFFICIENT OXIDATION; QUANTUM DOTS; CARBON DOTS; NANOPARTICLES; GOLD; DRIVEN; OXYGEN, Saw an article supported by the National Natural Science Foundation of ChinaNational Natural Science Foundation of China (NSFC) [21703128, U1510105, 21733009, 21771082, 21573136]; Shanxi University of Scientific Instrument Center. Published in ELSEVIER SCIENCE SA in LAUSANNE ,Authors: Shi, ZQ; Qu, XJ; Dai, JY; Zou, HB; Zhang, ZT; Wang, RW; Qiu, SL. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Exploring catalytic processes performed under natural conditions is interesting, but there remains a great challenge in developing highly efficient catalysts for natural oxidation of alcohols. Herein, we report a chloroplast-like catalyst comprised of photoactive carbon dots (CDs), catalytically active Pt nanoparticles, and amphiphilic nanotubes. Under simulated and real natural reaction conditions, our catalysts exhibited remarkable activity and long-term reusability for the oxidation of various alcohols, significantly outperforming that of other counterpart catalysts and reported thermal/photocatalytic systems. It was demonstrated that when the carbon dots and the amphiphilic nanotubes respectively played a role in the light-harvesting and the substrate transport the Pt/CDs heterointerface acted as the active center for the matter conversion. Such an elaborate cooperation, an advanced process in the photosynthesis of plant, contributed to the excellent catalytic performance. This contribution provides a new design concept for artificial photocatalysts, which is very promising for developing sustainable catalytic processes.

Welcome to talk about 105-13-5, If you have any questions, you can contact Shi, ZQ; Qu, XJ; Dai, JY; Zou, HB; Zhang, ZT; Wang, RW; Qiu, SL or send Email.. Name: (4-Methoxyphenyl)methanol

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An article Zinc Stabilized Azo-anion Radical in Dehydrogenative Synthesis of N-Heterocycles. An Exclusively Ligand Centered Redox Controlled Approach WOS:000664333800072 published article about NITROGEN-HETEROCYCLES; ELECTRONIC-STRUCTURES; COMPLEXES; OXIDATION; HYDROGENATION; REACTIVITY in [Das, Siuli; Mondal, Rakesh; Chakraborty, Gargi; Guin, Amit Kumar; Paul, Nanda D.] Indian Inst Engn Sci & Technol, Dept Chem, Howrah 711103, India; [Das, Abhishek] Indian Assoc Cultivat Sci, Sch Chem Sci, Kolkata 700032, India in 2021, Cited 79. Product Details of 105-13-5. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5

Herein we report an exclusively ligand-centered redox controlled approach for the dehydrogenation of a variety of N-heterocycles using a Zn(II)-stabilized azo-anion radical complex as the catalyst. A simple, easy-to-prepare, and bench-stable Zn(II)-complex (1b) featuring the tridentate arylazo pincer, 2-((4-chlorophenyl)diazenyl)-1,10-phenanthroline, in the presence of zinc-dust, undergoes reduction to form the azo-anion radical species [1b]which efficiently dehydrogenates various saturated N-heterocycles such as 1,2,3,4-tetrahydro-2-methylquinoline, 1,2,3,4-tetrahydro-isoquinoline, indoline, 2-phenyl-2,3-dihydro-1H-benzoimidazole, 2,3-dihydro-2-phenylquinazolin-4(1H)-one, and 1,2,3,4-tetrahydro-2-phenylquinazolines, among others, under air. The catalyst has further been found to be compatible with the cascade synthesis of these N-heterocycles via dehydrogenative coupling of alcohols with other suitable coupling partners under air. Mechanistic investigation reveals that the dehydrogenation reactions proceed via a one-electron hydrogen atom transfer (HAT) pathway where the zinc-stabilized azo-anion radical ligand abstracts the hydrogen atom from the organic substrate(s), and the whole catalytic cycle proceeds via the exclusive involvement of the ligand-centered redox events where the zinc acts only as the template.

Product Details of 105-13-5. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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Formula: C8H10O2. Shahnavaz, Z; Zaharani, L; Khaligh, NG; Mihankhah, T; Johan, MR in [Shahnavaz, Zohreh; Zaharani, Lia; Khaligh, Nader Ghaffari; Johan, Mohd Rafie] Univ Malaya, Inst Postgrad Studies, Nanotechnol & Catalysis Res Ctr, 3rd Floor,Block A, Kuala Lumpur 50603, Malaysia; [Mihankhah, Taraneh] Iran Univ Sci & Technol, Sch Civil Engn, Dept Water & Environm Engn, Environm Res Lab, Tehran 16765163, Iran published Synthesis, Characterisation, and Determination of Physical Properties of New Two-Protonic Acid Ionic Liquid and its Catalytic Application in the Esterification in 2021, Cited 35. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5.

A new ionic liquid was synthesised, and its chemical structure was elucidated by FT-IR, 1D NMR, 2D NMR, and mass analyses. Some physical properties, thermal behaviour, and thermal stability of this ionic liquid were investigated. The formation of a two-protonic acid salt namely 4,4′-trimethylene-N,N’-dipiperidinium sulfate instead of 4,4′-trimethylene-N,N’-dipiperidinium hydrogensulfate was evidenced by NMR analyses. The catalytic activity of this ionic liquid was demonstrated in the esterification reaction of n-butanol and glacial acetic acid under different conditions. The desired acetate was obtained in 62-88% yield without using a Dean-Stark apparatus under optimal conditions of 10 mol-% of the ionic liquid, an alcohol to glacial acetic acid mole ratio of 1.3 : 1.0, a temperature of 75-100 degrees C, and a reaction time of 4 h. alpha-Tocopherol (alpha-TCP), a highly efficient form of vitamin E, was also treated with glacial acetic acid in the presence of the ionic liquid, and O-acetyl-alpha-tocopherol (Ac-TCP) was obtained in 88.4% yield. The separation of esters was conducted during workup without the utilisation of high-cost column chromatography. The residue and ionic liquid were used in subsequent runs after the extraction of desired products. The ionic liquid exhibited high catalytic activity even after five runs with no significant change in its chemical structure and catalytic efficiency.

Welcome to talk about 105-13-5, If you have any questions, you can contact Shahnavaz, Z; Zaharani, L; Khaligh, NG; Mihankhah, T; Johan, MR or send Email.. Formula: C8H10O2

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Recently I am researching about CATALYZED SELECTIVE OXIDATION; AEROBIC OXIDATION; HYDROGEN-PEROXIDE; C-N; COPPER; METAL; ALDEHYDES; NANOPARTICLES; COMPLEXES; EFFICIENT, Saw an article supported by the DST, IndiaDepartment of Science & Technology (India) [CSIR/02/1151/20, SERB/EMR /2016/006898]; S&T department Govt. of Odisha [27562800512107/20/1919]; Planning and convergence department, Govt. of Odisha [L.N./716/P/ 2016]; University Grants Commission (UGC)University Grants Commission, India [F-4-5(58)/2014 (BSR/FRP)]; Oyster Scholar Fund; NSFNational Science Foundation (NSF) [CHE-1039925]. Published in WILEY-V C H VERLAG GMBH in WEINHEIM ,Authors: Behera, PK; Choudhury, P; Sahu, SK; Sahu, RR; Harvat, AN; McNulty, C; Stitgen, A; Scanlon, J; Kar, M; Rout, L. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol. Recommanded Product: (4-Methoxyphenyl)methanol

Though concept of oxygen bridged bimetallic catalyst for organic reaction is not well understood. Herein, we have tried to explain the concept by experimental as well as its support by full DFT study. We report here a competent protocol for dehydrogenative oxidation of benzylic alcohol using an oxygen bridged bimetallic CuMoO4 nano catalyst. Careful demonstration reveals that oxidation is not effective either with mono-metallic Cu (II) or Mo(VI); instead combination of both the metals through the oxygen bridge [Cu-O-Mo] unexpectedly and interestingly catalyzed the reaction efficiently. The new concept is strongly supported by computational DFT study. DFT study reveals dehydrogenative oxidation is preferred at copper centre over molybdenum and aromatic benzyl alcohols are greatly stabilised. Interaction barrier energy of monometallic CuO and MoO3 catalyst is much higher than bimetallic CuMoO4. Hydrogen transfer has larger barrier heights for CuO (31.5 kcal/mol) and MoO3 (40.3 kcal/mol) than bimetallic CuMoO4.

Recommanded Product: (4-Methoxyphenyl)methanol. Welcome to talk about 105-13-5, If you have any questions, you can contact Behera, PK; Choudhury, P; Sahu, SK; Sahu, RR; Harvat, AN; McNulty, C; Stitgen, A; Scanlon, J; Kar, M; Rout, L or send Email.

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In 2021 CHEM SCI published article about DIELS-ALDER REACTION; HYDROXY-O-QUINODIMETHANES; PHOTOASSISTED SYNTHESIS; ABSOLUTE STEREOCHEMISTRY; NATURAL-PRODUCT; ANALOGS THEREOF; SILYL ETHERS; XESTOQUINONE; SPONGE; HALENAQUINONE in [Lu, Xiao-Long; Qiu, Yuanyou; Yang, Baochao; Gao, Shuanhu] East China Normal Univ, Sch Chem & Mol Engn, Shanghai Key Lab Green Chem & Chem Proc, 3663N Zhongshan Rog, Shanghai 200062, Peoples R China; [He, Haibing; Gao, Shuanhu] East China Normal Univ, Shanghai Engn Res Ctr Mol Therapeut & New Drug De, 3663N Zhongshan Rd, Shanghai 200062, Peoples R China in 2021, Cited 76. The Name is (4-Methoxyphenyl)methanol. Through research, I have a further understanding and discovery of 105-13-5. Computed Properties of C8H10O2

The asymmetric total synthesis of (+)-xestoquinone and (+)-adociaquinones A and B was achieved in 6-7 steps using an easily accessible meso-cyclohexadienone derivative. The [6,6]-bicyclic decalin B-C ring and the all-carbon quaternary stereocenter at C-6 were prepared via a desymmetric intramolecular Michael reaction with up to 97% ee. The naphthalene diol D-E ring was constructed through a sequence of Ti(Oi-Pr)(4)-promoted photoenolization/Diels-Alder, dehydration, and aromatization reactions. This asymmetric strategy provides a scalable route to prepare target molecules and their derivatives for further biological studies.

Computed Properties of C8H10O2. Bye, fridends, I hope you can learn more about C8H10O2, If you have any questions, you can browse other blog as well. See you lster.

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I found the field of Oncology; Respiratory System very interesting. Saw the article Role of dietary carbohydrates on risk of lung cancer published in 2021. Name: (4-Methoxyphenyl)methanol, Reprint Addresses Pang, H (corresponding author), Li Ka Shing Fac Med, Sch Publ Hlth, Pok Fu Lam, 7 Sassoon Rd, Hong Kong, Peoples R China.. The CAS is 105-13-5. Through research, I have a further understanding and discovery of (4-Methoxyphenyl)methanol

Objectives: Inconsistent findings have been reported on the link between dietary carbohydrates and lung cancer. This study aims to comprehensively evaluate the role of dietary carbohydrates on lung cancer risk. Materials and methods: The prospective study is based on the PLCO trial, which recruited 113,096 eligible participants across the United States. Participants had to have completed baseline and diet history questionnaires. The incidence of lung cancer was acquired through self-report and medical record follow-up. A multivariable logistic model adjusted for confounders was used to estimate odds ratios (ORs) and 95 % confidence intervals (CIs) of dietary carbohydrates, fiber, whole grains, glycemic index (GI) and glycemic load (GL) for lung cancer. Similar methods were applied in analyzing the carbohydrates and fiber from different food sources. Multinomial logistic models were used for sensitivity analysis with lung cancer subtypes as outcomes. Results: Dietary carbohydrates and GL were inversely associated with lung cancer incidence in the PLCO population. Among various carbohydrates, 30-g daily consumption of dietary fiber was related to a lower risk of lung cancer (fourth vs first quartile OR: 0.62, 95 % CI: 0.54-0.72) compared with 8.8-g. Furthermore, consuming whole grains 2.3 servings per day as opposed to 0.3 servings per day was associated with a lower risk of lung cancer (OR: 0.73, 95 % CI: 0.64-0.83). A higher risk of lung cancer was seen for the consumption of high-GI food (OR: 1.19, 95 % CI: 1.05?1.35) and refined carbohydrates from soft drinks (OR: 1.23, 95 % CI: 1.04?1.46). Conclusion: Carbohydrates and fiber from fruits, vegetables and whole grains are associated with lower lung cancer risk. Refined carbohydrates from processed food, such as soft drinks, appear to increase risk.

Welcome to talk about 105-13-5, If you have any questions, you can contact Tao, J; Jatoi, A; Crawford, J; Lam, WWT; Ho, JC; Wang, XF; Pang, H or send Email.. Name: (4-Methoxyphenyl)methanol

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