Category: 100-55-0

In 2022,Zhou, Bei; Ma, Zhuang; Alenad, Asma M.; Kreyenschulte, Carsten; Bartling, Stephan; Beller, Matthias; Jagadeesh, Rajenahally V. published an article in Green Chemistry. The title of the article was 《Cobalt-catalysed CH-alkylation of indoles with alcohols by borrowing hydrogen methodology》.Quality Control of 3-Pyridinemethanol The author mentioned the following in the article:

A general heterogeneous cobalt-catalyzed CH-alkylation of indoles with alcs. was reported. Utilizing this straightforward borrowing hydrogen methodol., a series of substituted and functionalized indoles were easily coupled with benzylic, heterocyclic, and aliphatic alcs. including methanol to prepare >65 substituted indoles in good to excellent yields. The resulting products represented an interesting class of heterocyclic compounds widely used in organic synthesis and medicinal chem. Key for this synthesis was the use of specific cobalt-nanoparticles supported on N-doped carbon, which were conveniently prepared by the pyrolysis of a templated material generated in-situ by mixing cobalt-nitrate, zinc-nitrate, 2,6-diaminopyridine, and colloidal silica, and subsequent removal of silica. In the part of experimental materials, we found many familiar compounds, such as 3-Pyridinemethanol(cas: 100-55-0Quality Control of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. When pyridine is adsorbed on oxide surfaces or in porous materials, the following species are commonly observed: (i) pyridine coordinated to Lewis acid sites, (ii) pyridine H-bonded to weakly acidic hydroxyls, and (iii) protonated pyridine. At high coverage, physisorbed pyridine and protonated dimers can also be observed.Quality Control of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Li, Weikang; Huang, Ming; Liu, Jiahao; Huang, Yong-Liang; Lan, Xiao-Bing; Ye, Zongren; Zhao, Cunyuan; Liu, Yan; Ke, Zhuofeng published their research in ACS Catalysis in 2021. The article was titled 《Enhanced Hydride Donation Achieved Molybdenum Catalyzed Direct N-Alkylation of Anilines or Nitroarenes with Alcohols: From Computational Design to Experiment》.COA of Formula: C6H7NO The article contains the following contents:

An example of homogeneous Mo-catalyzed direct N-alkylation of anilines or nitroarenes with alcs. is presented. The DFT aimed design suggested the easily accessible bis-NHC-Mo(0) complex features a strong hydride-donating ability, achieving effective N-alkylation of anilines or challenging nitroarenes with alcs. The enhanced hydride-donating strategy should be useful in designing highly active systems for borrowing hydrogen transformations. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0COA of Formula: C6H7NO)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.COA of Formula: C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,Synthesis included an article by Kawano, Teruhiro; Watari, Ryo; Kayaki, Yoshihito; Ikariya, Takao. SDS of cas: 100-55-0. The article was titled 《Catalytic Hydrogenation of Carboxamides with a Bifunctional Cp*Ru Catalyst Bearing an Imidazol-2-ylidene with a Protic Aminoethyl Side Chain》. The information in the text is summarized as follows:

Synthesis of a Cp*Ru complex bearing an NH2-functionalized N-heterocyclic carbene (C-NH) I (R = CH3) was achieved by treatment of Cp*RuBr(isoprene) with an equimolar amount of a silver complex, which was generated from Ag2O and 1-(2-aminoethyl)-3-methylimidazolium bromide, in CH3CN at room temperature The new Cp*RuBr(C-NH) complex I showed a higher catalytic performance than the related Cp*RuCl(P-NH) and Cp*RuCl(N-NH) complexes. In the reaction of N-arylcarboxamides R1C(O)NR2R3 (R1 = H, C6H5, pyridin-3-yl; R2 = R3 = CH3; R2 = H, R3 = C6H5; R2R3 = -C(O)(CH2)3-, etc.), the amine products R2R3NH were obtained in satisfactory yields under mild temperature conditions. In the part of experimental materials, we found many familiar compounds, such as 3-Pyridinemethanol(cas: 100-55-0SDS of cas: 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.SDS of cas: 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2019,ACS Omega included an article by Waiba, Satyadeep; Das, Animesh; Barman, Milan K.; Maji, Biplab. Formula: C6H7NO. The article was titled 《Base Metal-Catalyzed Direct Olefinations of Alcohols with Sulfones》. The information in the text is summarized as follows:

Herein, a base-metal nickel-catalyzed direct olefination of alcs. with sulfones is reported. The reaction operates under low catalyst loading and does not require an external redox reagent. A wide range of trans-stilbenes and styrenes were synthesized in good yields and selectivities. Biol. active stilbene DMU-212 could also be synthesized in a single step under these conditions. Mechanistic studies involving kinetic isotope effect, deuterium labeling experiments, and catalytic and stoichiometric reactions with possible catalytic intermediates were performed to elucidate a plausible mechanism. The results came from multiple reactions, including the reaction of 3-Pyridinemethanol(cas: 100-55-0Formula: C6H7NO)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. In industry and in the lab, pyridine is used as a reaction solvent, particularly when its basicity is useful, and as a starting material for synthesizing some herbicides, fungicides, and antiseptics.Formula: C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Frost, James R.; Cheong, Choon Boon; Akhtar, Wasim M.; Caputo, Dimitri F. J.; Christensen, Kirsten E.; Stevenson, Neil G.; Donohoe, Timothy J. published an article in 2021. The article was titled 《Hydrogen borrowing catalysis using 1° and 2° alcohols: Investigation and scope leading to α and β branched productsã€? and you may find the article in Tetrahedron.Recommanded Product: 100-55-0 The information in the text is summarized as follows:

The alkylation of a variety of ketones, e.g., 1-cyclopropyl-3-(furan-2-yl)propan-1-one using 1° R1OH (R1 = n-Bu, Bn, cyclopropylmethyl, etc.) or 2° alcs. R2R3CHOH (R2 = Me, Et; R3 = Et, Ph, thiophen-2-yl, cyclobutyl, etc.; R2R3 = cyclohexyl, 1,4-dioxaspiro[4.5]decan-8-yl, cyclopentyl, etc.) under hydrogen borrowing catalysis is described. Initial research focused on the α-alkylation of cyclopropyl ketones with higher 1° alcs. (i.e. larger than MeOH), leading to the formation of α-branched products, e.g., 1-cyclopropyl-2-(furan-2-ylmethyl)hexan-1-one. The search for addnl. substrates with which to explore this chem. led to discover that di-ortho-substituted aryl ketones were also privileged scaffolds, with Ph* (C6Me5) ketones being the optimal choice. Further investigations revealed that this motif was crucial for alkylation with 2° alcs. forming β-branched products, which also provided an opportunity to study diastereoselective and intramol. hydrogen borrowing processes. The experimental process involved the reaction of 3-Pyridinemethanol(cas: 100-55-0Recommanded Product: 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is a relatively complex molecule and exhibits a number of different bands in IR spectra. Among others, the bands characterizing the ν8a and ν19b modes have been found to be sensitive to the coordination or protonation of the molecule. Note that the band that is diagnostic for the PyH+ ion at about 1545 cmâˆ?1 (ν19b mode) does not overlap with any of the other bands.Recommanded Product: 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Xia, Yu-Yan; Lv, Qing-Yang; Yuan, Hua; Wang, Jia-Yi published an article in 2021. The article was titled 《Selective oxidation of alcohols to nitriles with high-efficient Co-[Bmim]Br/C catalyst systemã€? and you may find the article in Chemical Papers.Computed Properties of C6H7NO The information in the text is summarized as follows:

An efficient method for catalyzing the ammoxidation of aromatic alcs. to aromatic nitriles was developed, in which a new heterogeneous catalyst based on transition metal elements was employed, the new catalyst was named Co-[Bmim]Br/C-700 and then characterized by X-ray photo-electronic spectroscopy, transmission electron microscope and X-ray diffraction. The reaction was carried out by two consecutive dehydrogenations under the catalysis of Co-[Bmim]Br/C-700, which catalytically oxidized the alc. to the aldehyde, and then the aldehyde was subjected to ammoxidation to the nitrile. The catalyst system was suitable for a wide range of substrates and nitriles obtained in high yields, especially, the conversion rate of benzyl alc., 4-methoxybenzyl alc., 4-chlorobenzyl alc. and 4-nitrobenzyl alc. reached 100%. The substitution of ammonia and oxygen for toxic cyanide to participate in the reaction accords with the theory of green chem. The results came from multiple reactions, including the reaction of 3-Pyridinemethanol(cas: 100-55-0Computed Properties of C6H7NO)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. When pyridine is adsorbed on oxide surfaces or in porous materials, the following species are commonly observed: (i) pyridine coordinated to Lewis acid sites, (ii) pyridine H-bonded to weakly acidic hydroxyls, and (iii) protonated pyridine. At high coverage, physisorbed pyridine and protonated dimers can also be observed.Computed Properties of C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

In 2022,Ma, Zhuang; Zhou, Bei; Li, Xinmin; Kadam, Ravishankar G.; Gawande, Manoj B.; Petr, Martin; Zboril, Radek; Beller, Matthias; Jagadeesh, Rajenahally V. published an article in Chemical Science. The title of the article was 《Reusable Co-nanoparticles for general and selective N-alkylation of amines and ammonia with alcoholsã€?Quality Control of 3-Pyridinemethanol The author mentioned the following in the article:

A general cobalt-catalyzed N-alkylation of amines with alcs. by borrowing hydrogen methodol. to afford alkylated amines I [R = Pr-n, cyclohexyl, Ph, etc.; R1 = Ph, 4-MeC6H4, 4-FC6H4, etc.] was reported. The optimal catalyst for this transformation was prepared by pyrolysis of a specific templated material, which was generated in situ by mixing cobalt salts, nitrogen ligands and colloidal silica and subsequent removal of silica. Applying this novel Co-nanoparticle-based material, >100 primary, secondary and tertiary amines including N-methylamines and selected drug mols. were conveniently prepared starting from inexpensive and easily accessible alcs. and amines or ammonia. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Quality Control of 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is very deactivated towards electrophilic substitution with respect to benzene. For this reason classical formylation, using methods such as the Gattermann or Vilsmeier reactions, are not generally successful. Quality Control of 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Computed Properties of C6H7NOIn 2022 ,《Heterogeneous Catalysis for Oxidation of Alcohol via 1-Methyl-2-azaadamanane N-oxyl Immobilized on Magnetic Polystyrene Nanosphereã€?appeared in ChemistrySelect. The author of the article were Guo, Xiaqun; Li, Meichao; Wang, Jianli; Li, Chunmei; Hu, Xinquan; Jin, Liqun; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu. The article conveys some information:

A highly promising heterogeneous strategy was describedn in which a catalytic amount of 1-methyl-2-azaadamanane N-oxyl immobilized on magnetic polystyrene nanosphere (1-Me-AZADO/MPNs) was used and a series of carbonyl compounds were obtained from various alcs. in 73-99% isolated yields and high selectivity (>99%) under Anelli conditions, thus offering a greener and more convenient methods in the synthesis of carbonyl compounds The attractive features of convenient magnetic separation (within seconds), good recyclability (up to 20 runs) and fast reaction rates (5-20 min) were very efficient to improve the utility of azaadamantane-type-nitroxyl radicals in the oxygenation. After reading the article, we found that the author used 3-Pyridinemethanol(cas: 100-55-0Computed Properties of C6H7NO)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Computed Properties of C6H7NO

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

Product Details of 100-55-0In 2021 ,《SBA-15 Supported 1-Methyl-2-azaadamantane N-Oxyl (1-Me-AZADO) as Recyclable Catalyst for Oxidation of Alcoholã€?was published in Organic Letters. The article was written by Tian, Yangwu; Guo, Xiaqun; Li, Meichao; Li, Chunmei; Hu, Xinquan; Jin, Liqun; Sun, Nan; Hu, Baoxiang; Shen, Zhenlu. The article contains the following contents:

An SBA-15 supported 1-methyl-2-azaadamantane N-oxyl (1-Me-AZADO) was designed, synthesized and investigated its catalytic performance for selective oxidation of alcs. under Anelli’s conditions. The first example of immobilization of 1-Me-AZADO was very important to advance the oxgenation effectively because this supported N-oxyl had excellent catalytic activity for oxidation of alcs. to carbonyl compounds, and more importantly, it could be conveniently recovered and reused at least 6 times without significant effect on its catalytic efficiency. The experimental part of the paper was very detailed, including the reaction process of 3-Pyridinemethanol(cas: 100-55-0Product Details of 100-55-0)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine and pyridine-derived structures are privileged pharmacophores in medicinal chemistry and an essential functionality for organic chemists. As the prototypical π-deficient heterocycle, pyridine illustrates distinctive chemistry as both substrate and reagent. Product Details of 100-55-0

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts

《One-Pot Synthesis of 4-Quinolone via Iron-Catalyzed Oxidative Coupling of Alcohol and Methyl Areneã€?was published in Organic Letters in 2020. These research results belong to Lee, Seok Beom; Jang, Yoonkyung; Ahn, Jiwon; Chun, Simin; Oh, Dong-Chan; Hong, Suckchang. Recommanded Product: 3-Pyridinemethanol The article mentions the following:

Herein, we describe the iron(III)-catalyzed oxidative coupling of alc./methyl arene with 2-amino Ph ketone to synthesize 4-quinolone. Alcs. and Me arenes are oxidized to the aldehyde in the presence of an iron catalyst and di-tert-Bu peroxide, followed by a tandem process, condensation with amine/Mannich-type cyclization/oxidation, to complete the 4-quinolone ring. This method tolerates various kinds of functional groups and provides a direct approach to the synthesis of 4-quinolones from less functionalized substrates. In the experimental materials used by the author, we found 3-Pyridinemethanol(cas: 100-55-0Recommanded Product: 3-Pyridinemethanol)

3-Pyridinemethanol(cas: 100-55-0) belongs to pyridine. Pyridine is widely used in the precursor to agrochemicals and pharmaceuticals. Also, it is used as an important reagent and organic solvent.Recommanded Product: 3-Pyridinemethanol

Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts