Vielhaber, Thomas; Faust, Kirill; Topf, Christoph published the artcile< Group 6 Metal Carbonyl Complexes Supported by a Bidentate PN Ligand: Syntheses, Characterization, and Catalytic Hydrogenation Activity>, HPLC of Formula: 403-41-8, the main research area is phosphinoethylamino chromium carbonyl complex preparation catalyst hydrogenation benzaldehyde; molybdenum phosphinoethylamino carbonyl complex preparation catalyst hydrogenation benzaldehyde; tungsten phosphinoethylamino carbonyl complex preparation catalyst hydrogenation benzaldehyde; crystal structure phosphinoethylamino chromium molybdenum tungsten carbonyl complex; mol structure phosphinoethylamino chromium molybdenum tungsten carbonyl complex.
The authors report on the preparation of P-N donor ligand complexes [M(CO)4(PN)], where M = Cr, Mo, W and PN is 2-(diphenylphosphino)ethylamine. The organometallic compounds were readily obtained upon reacting the resp. metal hexacarbonyls with equimolar amounts of the pertinent ligand in the presence of Et4NBr. The PN-ligated metal carbonyls were fully characterized by standard spectroscopic techniques and x-ray crystallog. The ability of the title compounds to function as homogeneous hydrogenation catalysts was probed in the reduction of acetophenone and benzaldehyde derivatives to yield the corresponding alcs. The reaction setup was easily assembled by simply combining the components in the autoclave on the bench outside an inert-gas-operated glovebox system.
Organometallics published new progress about Alcohols Role: SPN (Synthetic Preparation), PREP (Preparation). 403-41-8 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H9FO, HPLC of Formula: 403-41-8.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts