《Nickel-catalysed chemoselective C-3 alkylation of indoles with alcohols through a borrowing hydrogen method》 was written by Bains, Amreen K.; Biswas, Ayanangshu; Adhikari, Debashis. COA of Formula: C7H7BrO And the article was included in Chemical Communications (Cambridge, United Kingdom) in 2020. The article conveys some information:
An inexpensive, air-stable, isolable nickel catalyst is reported that can perform chemoselective C3-alkylation of indoles with a variety of alcs. following “”borrowing hydrogen””. A one-pot, cascade C3-alkylation starting from 2-aminophenyl Et alcs., and thus obviating the need for pre-synthesized indoles, further adds to the broad scope of this method. The reaction is radical-mediated, and is significantly different from other examples, often dictated by metal-ligand bifunctionality. In the experiment, the researchers used many compounds, for example, (4-Bromophenyl)methanol(cas: 873-75-6COA of Formula: C7H7BrO)
(4-Bromophenyl)methanol(cas: 873-75-6) undergoes three-component reaction with acetylferrocene and arylboronic acid to give ferrocenyl ketones containing biaryls.COA of Formula: C7H7BrO It undergoes oxidation reaction in the presence of polyvinylpolypyrrolidone-supported hydrogen peroxide, silica sulfuric acid and ammonium bromide to yield 4-bromobenzaldehyde.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts