Reference of 2,6-PyridinedimethanolIn 2022 ,《Mixed-Ligand Metal-Organic Frameworks: Synthesis and Characterization of New MOFs Containing Pyridine-2,6-dimethanolate and Benzene-1,4-dicarboxylate Ligands》 appeared in European Journal of Inorganic Chemistry. The author of the article were Mylonas-Margaritis, Ioannis; Mayans, Julia; Efthymiou, Constantinos G.; McArdle, Patrick; Papatriantafyllopoulou, Constantina. The article conveys some information:
The development of synthetic approaches towards new mixed-ligand metal organic frameworks (MOFs) was attracting considerable attention recently as they display fascinating properties due to the synergistic effect between the different ligands. Herein, the initial combination of pyridine-2,6-dimethanol (H2pdm) with benzene-1,4-dicarboxylic acid (H2bdc) provided access to three new mixed-ligand MOFs, [M3(bdc)2(Hpdm)2]n (MII = ZnII, 1; MnII, 2) and [Mn3(bdc)3(H2pdm)2]n (3). 1-3 Are the first MOFs containing H2pdm in its neutral or anionic form. 1 And 2 are isostructural 2D MOFs with a square lattice (sql) framework topol., while 3 is a 3D MOF possessing a primitive cubic (pcu) topol. Dc magnetic susceptibility measurements for 3 demonstrate antiferromagnetic interactions between the MnII ions which is a combination of intra- and intertrimer exchange pathways.2,6-Pyridinedimethanol(cas: 1195-59-1Reference of 2,6-Pyridinedimethanol) was used in this study.
2,6-Pyridinedimethanol(cas: 1195-59-1) belongs to pyridine. The basicity and metallophilic high donor number of these π-deficient systems has long favored them as ligands in metal catalysis. The last decade saw pyridine assume a stronger role as functional group for directed C–H oxidation/activation.Reference of 2,6-Pyridinedimethanol
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts