Application of 4048-33-3In 2022 ,《POSS-containing polynorbornene with pendant perylene diimide: from a unique supramolecular structure to tunable luminescence properties》 appeared in Journal of Materials Chemistry C: Materials for Optical and Electronic Devices. The author of the article were Liu, Jie; Gao, Si-Yu; Zhang, Xin-Yi; Feng, Yakai; Wu, Han-Chun; Chen, Zhijian; Bermeshev, Maxim V.; Ren, Xiang-Kui. The article conveys some information:
POSS-containing polynorbornene with pendant perylene diimide (PPDI-POSS) has been synthesized, with alkyl-containing polynorbornene (PPDI-C10C8) as the reference The supermol. structure and photoluminescence properties were elucidated using UV-Vis absorption spectra, and one- and two-dimensional X-ray diffraction. The exptl. results reveal that PPDI-C10C8 possesses a lamellar structure with close PDI stacking to meet the requirement for min. free energy. However, the introduction of POSS cages endows PPDI-POSS with a unique hexagonal columnar structure and enhanced photoluminescence properties due to the steric hindrance of POSS cages. These results may contribute to the understanding of the structure-property relationship of the optical polymers and provide some useful information for the design of polymer materials with a controllable supramol. structure and tunable luminescence properties. In the experimental materials used by the author, we found 6-Aminohexan-1-ol(cas: 4048-33-3Application of 4048-33-3)
6-Aminohexan-1-ol(cas: 4048-33-3) can undergo cyclization over copper supported on γ-alumina and magnesia to form hexahydro-1H-azepine. It may be used along with glutaric acid to generate poly(ester amide)s with excellent film- and fiber forming properties.Application of 4048-33-3
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