Tyula, Yunes Abbasi; Zabardasti, Abedien; Goudarziafshar, Hamid; Kucerakova, Monika; Dusek, Michal published the artcile< A new supramolecular zinc(II) complex containing 4-biphenylcarbaldehyde isonicotinoylhydrazone ligand: Nanostructure synthesis, catalytic activities and Hirshfeld surface analysis>, Product Details of C8H10OS, the main research area is Hirshfeld surface analysis intermol interaction zinc biphenyl carboxaldehyde complex; sulfide selective oxidation sulfoxide preparation zinc biphenyl carboxaldehyde catalyst; crystal structure zinc dibromo biphenyl carboxaldehyde complex preparation.
A new potentially tridentate hydrazone ligand, 4-biphenylcarbaldehyde isonicotinoylhydrazone (4-bpinh), was prepared by the condensation of biphenyl-4-carboxaldehyde with isonicotinic acid hydrazide. Then, its nano-sized and single crystal of zinc complex were synthesized using sonochem. and heat gradient methods, resp. The structure of complex, [Zn(4-bpinh)2Br2] (1), was determined by single-crystal x-ray diffraction, FTIR, and elemental anal., and the nano-structure of complex was characterized by FTIR, XRD, and SEM. The single crystal x-ray structure of complex showed that the metal center has a distorted tetrahedral geometry and the hydrazone ligand acts as monodentate trough the pyridyl N atom. Moreover, the anal. of crystal structures indicates the existence of intermol. interactions such as N/C-H···Br/O, N/C-H···π, and π···π stacking in the stabilization of complex structure which finally gave the three-dimensional supramol. structure. Also, the impact of this interactions was more studied using Hirshfeld surface anal. and corresponding 2D fingerprint plots. Furthermore, the catalytic activity of 1 was studied in the selective oxidation of various sulfides to corresponding sulfoxides using hydrogen peroxide as the oxidative agent.
Applied Organometallic Chemistry published new progress about Crystal structure. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Product Details of C8H10OS.
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