Tamoradi, Taiebeh; Ghorbani-Choghamarani, Arash; Ghadermazi, Mohammad published the artcile< Synthesis of new zirconium complex supported on MCM-41 and its application as an efficient catalyst for synthesis of sulfides and the oxidation of sulfur containing compounds>, Quality Control of 699-12-7, the main research area is sulfide preparation oxidation adenine zirconium nanocatalyst green chem; thiol oxidative coupling adenine zirconium nanocatalyst green chem.
The synthesis of new zirconium complex supported on mesoporous silica by anchoring of adenine on the wall of functionalized MCM-41 and then reacted with ZrOCl2 was described. The resultant MCM-41-Adenine-Zr was characterized by FT-IR, XRD, TEM, SEM, TGA, EDX, ICP and BET techniques. It was exhibited that the MCM-41-Adenine-Zr can be used as an efficient and thermally stable nanocatalyst for the oxidation of sulfides such as dipropylsulfide, tetrahydrothiophene, benzylphenylsulfide, etc.; oxidative coupling of thiols such as naphthalene-2-thiol, benzo[d]thiazole-2-thiol, benzo[d]oxazole-2-thiol, etc. and synthesis of sulfides such as 1,1′-thiobis(2-methoxy)-benzene, 1,1′-thiobis-benzene, 1,1′-thiobis(4-nitro)-benzene. Moreover, this heterogeneous catalyst can be easily recovered from the reaction mixture by simple filtration and reused for several consecutive cycles without noticeable change in its catalytic activity.
Applied Organometallic Chemistry published new progress about Green chemistry. 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Quality Control of 699-12-7.
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