Minozzi, Clementine; Grenier-Petel, Jean-Christophe; Parisien-Collette, Shawn; Collins, Shawn K. published the artcile< Photocatalyic Appel reaction enabled by copper-based complexes in continuous flow>, Name: 2-(Phenylthio)ethanol, the main research area is aliphatic alc copper photocatalyst Appel reaction continuous flow; alkylbromide preparation; carboxylic acid copper catalyst photochem reaction continuous flow; anhydride preparation; Appel; continuous flow; copper; halides; photocatalysis.
A copper-based photocatalyst, Cu(tmp)(BINAP)BF4, was found to be active in a photoredox Appel-type conversion of alcs. to bromides. The catalyst was identified from a screening of 50 complexes and promoted the transformation of primary and secondary alcs. to their corresponding bromides and carboxylic acids to their anhydride. The protocol was also amendable and optimized under continuous flow conditions.
Beilstein Journal of Organic Chemistry published new progress about Aliphatic alcohols Role: RCT (Reactant), SPN (Synthetic Preparation), RACT (Reactant or Reagent), PREP (Preparation). 699-12-7 belongs to class alcohols-buliding-blocks, and the molecular formula is C8H10OS, Name: 2-(Phenylthio)ethanol.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts