Wang, Daoyong;Shuler, William G.;Pierce, Conor J.;Hilinski, Michael K. published 《An Iminium Salt Organocatalyst for Selective Aliphatic C-H Hydroxylation》 in 2016. The article was appeared in 《Organic Letters》. They have made some progress in their research.Safety of 3,7-Dimethyloctan-3-ol The article mentions the following:
The first examples of catalysis of aliphatic C-H hydroxylation by an iminium salt are presented. The method allows the selective organocatalytic hydroxylation of unactivated 3° C-H bonds at room temperature using hydrogen peroxide as the terminal oxidant. Hydroxylation of an unactivated 2° C-H bond is also demonstrated. Furthermore, improved functional group compatibility over other catalytic methods is reported in the form of selectivity for aliphatic C-H hydroxylation over alc. oxidation On the basis of initial mechanistic studies, an oxaziridinium species is proposed as the active oxidant. To complete the study, the researchers used 3,7-Dimethyloctan-3-ol (cas: 78-69-3) .
3,7-Dimethyloctan-3-ol(cas:78-69-3) is a fatty alcohol that is 3-octanol substituted by methyl groups at positions 3 and 7.Safety of 3,7-Dimethyloctan-3-ol Metabolite observed in cancer metabolism. It has a role as a human metabolite.
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts