Application In Synthesis of 3,7-Dimethyloctan-3-olIn 2020, Gao, Yongyuan;Wu, Zhengguang;Yu, Lei;Wang, Yi;Pan, Yi published 《Alkyl Carbazates for Electrochemical Deoxygenative Functionalization of Heteroarenes》. 《Angewandte Chemie, International Edition》published the findings. The article contains the following contents:
The C-O bond cleavage for activation of alcs. is synthetically useful and practically challenging. This work describes carbazate as a new type of electrochem. activated alkylating agent derived from ubiquitous alcs. for direct functionalization of heteroarenes under mild electrolytic conditions. The simple undivided cell at low oxidative potentials with carbon/platinum electrode set-ups offers excellent substrate tolerance, affording a variety of primary, secondary and tertiary alkyl-decorated heterocycles in good chem. yields. Furthermore, the mechanism for this electrochem. deoxyalkylation reaction was studied.3,7-Dimethyloctan-3-ol (cas: 78-69-3) were involved in the experimental procedure.
3,7-Dimethyloctan-3-ol(cas:78-69-3) is a fatty alcohol that is 3-octanol substituted by methyl groups at positions 3 and 7.Application In Synthesis of 3,7-Dimethyloctan-3-ol Metabolite observed in cancer metabolism. It has a role as a human metabolite.
Reference:
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Alcohols – Chemistry LibreTexts