SDS of cas: 80-46-6《Nickel Hydride Catalyzed Cleavage of Allyl Ethers Induced by Isomerization》 was published in 2021. The authors were Kathe, Prasad M.;Berkefeld, Andreas;Fleischer, Ivana, and the article was included in《Synlett》. The author mentioned the following in the article:
This report discloses the deallylation of O-allyl functional group containing compounds ROCH2CHCH2 (R = 4-chlorophenyl, (3S)-3,7-dimethyloct-6-en-1-yl, 2-(4-methylcyclohex-3-en-1-yl)propan-2-yl, etc.) and N-allyl functional group containing compound N-Allyl-N-methylbenzamide by using a combination of a Ni-H precatalyst and excess Bronsted acid. Key steps are the isomerization of the O- or N-allyl group through Ni-catalyzed double-bond migration followed by Bronsted acid induced O/N-C bond hydrolysis. A variety of functional groups are tolerated in this protocol, highlighting its synthetic value. The experimental procedure involved many compounds, such as 4-tert-Amylphenol (cas: 80-46-6) .
4-tert-acylphenol (cas:80-46-6) contains hydroxyl group. Alcohols are among the most common organic compounds. They are used as sweeteners and in making perfumes, are valuable intermediates in the synthesis of other compounds, and are among the most abundantly produced organic chemicals in industry. SDS of cas: 80-46-6
Reference:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts