Simple alcohols are found widely in nature. Ethanol is the most prominent because it is the product of fermentation, a major energy-producing pathway. 72824-04-5, formula is C9H17BO2, Other simple alcohols, chiefly fusel alcohols, are formed in only trace amounts. More complex alcohols however are pervasive, as manifested in sugars, some amino acids, and fatty acids. , Application of C9H17BO2
Feng, Xiaowen;Wei, Quanyong;Li, Shaopeng;Wei, Xianzhe;Yang, Xiaofeng;Song, Zhiling;Geng, Bing;Li, Zengjun;Zhang, Jing;Yan, Mei research published 《 Organic-inorganic photoelectrochemical sensor based on aza-cope rearrangement reaction for formaldehyde》, the research content is summarized as follows. A photoelectrochem. (PEC) sensor was designed by connecting an organic recognize group 1-(4-(3-aminopropoxy)phenyl)-N-(4-nitrobenzyl)but-3-en-1-amine (FOP-1) to a modified photoelec. nanomaterial Pt-BiVO4 nano flowers (NFs) for ultra-sensitive and highly selective detection of formaldehyde (FA). The steric hindrance of the FOP-1 and the strong electron-withdrawing group nitro blocked the transfer of electrons excited to the electrode under illumination, resulting in a decrease in photocurrent. With the addition of FA, it triggered a specific aza-cope remake reaction (2-aza-cope sigmatropic rearrangement), leading to N-(4-nitrobenzyl)but-3-en-1-amin (NBEA) group removed, the steric hindrance weakened, the electron-withdrawing effect decreased, and the photocurrent signal recovered obviously. The entire sensor shows good stability and repeatability, excellent selectivity for FA, its detection limit is 0.4 μM, and the linear range is 1-1000 μM, Moreover, endogenous FA released from live MCF-7 cells and the real mice serum samples were monitored successfully by the PEC sensor, indicating its practicality potential in biol. cytol. and pathophysiol.
Application of C9H17BO2, Allylboronic acid pinacol ester is a useful research compound. Its molecular formula is C9H17BO2 and its molecular weight is 168.04 g/mol. The purity is usually 95%.
Allylboronic acid pinacol ester is an allylation reagent that is used to produce aldehydes from ketones. It reacts with water, yielding the desired product and formaldehyde as a byproduct. The reaction proceeds through a sequence of steps, in which the boronate ester first reacts with water to form an allylboronate ion and hydrogen gas. This intermediate then reacts with potassium t-butoxide to produce the desired allyl alcohol and potassium borohydride. Finally, the palladium complex catalyst reduces the carbonyl group of the starting material, converting it into an aldehyde. Allylboronic acid pinacol ester is commercially available as a white solid, but can also be synthesized from 2-chloro-5-pinacolylborane (pinacol) in high yield using catalytic cross coupling reactions., 72824-04-5.
Referemce:
Alcohol – Wikipedia,
Alcohols – Chemistry LibreTexts