HPLC of Formula: 599-64-4《Palladium-Catalyzed Perfluoroalkylative Carbonylation of Unactivated Alkenes: Access to β-Perfluoroalkyl Esters》 was published in 2021. The authors were Zhang, Youcan;Geng, Hui-Qing;Wu, Xiao-Feng, and the article was included in《Angewandte Chemie, International Edition》. The author mentioned the following in the article:
Transition-metal-catalyzed multi-component carbonylation represents an efficient strategy for the preparation of various functionalized carbonyl-containing compounds Herein, authors report a general palladium-catalyzed perfluoroalkylative carbonylation of unactivated alkenes using inexpensive and readily available carbon monoxide as the C1 source and perfluoroalkyl halides as the coupling partner. A wide range of phenols and alcs. were transformed into the corresponding β-perfluoroalkyl esters in high yields with broad functional group tolerance and good chemoselectivity. Addnl., alkyl halides can be utilized as alkoxy source as well to give the desired esters. Moreover, several pharmaceutical and bio-active mols. were also suitable substrates for this one-pot multi-component carbonylation process to give the targeted products in good yields. The experimental procedure involved many compounds, such as 4-(2-Phenylpropan-2-yl)phenol (cas: 599-64-4) .
4-(2-Phenylpropan-2-yl)phenol(cas:599-64-4) is a natural product found in Panax ginseng.HPLC of Formula: 599-64-4 4-(2-Phenylpropan-2-yl)phenol is a useful reagent for preparing and characterizing aromatic polyphosphonates as high refractive index polymers.
Reference:
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