So far, in addition to halogen atoms, other non-metallic atoms can become part of the aromatic heterocycle, and the target ring system is still aromatic.Cabeza, Javier A.; Garcia-Alvarez, Pablo; Laglera-Gandara, Carlos J.; Perez-Carreno, Enrique researched the compound: Dichloro(1,5-cyclooctadiene)platinum(II)( cas:12080-32-9 ).Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II).They published the article 《Phosphane-functionalized heavier tetrylenes: synthesis of silylene- and germylene-decorated phosphanes and their reactions with Group 10 metal complexes》 about this compound( cas:12080-32-9 ) in Dalton Transactions. Keywords: Group 10 silylene germylene decorated phosphane complex preparation; crystal structure silylene phosphane palladium nickel germylene complex. We’ll tell you more about this compound (cas:12080-32-9).
The stable phosphine-functionalized heavier tetrylenes E(tBu2bzam)pyrmPtBu2 (E = Si (1Si), Ge (1Ge); tBu2bzam = N,N’-di-tertbutylbenzamidinate; HpyrmPtBu2 = di-tert-butyl(2-pyrrolylmethyl)phosphine) were prepared by reacting the amidinatotetrylenes E(tBu2bzam)Cl (E = Si, Ge) with LipyrmPtBu2. The reactions of 1Si and 1Ge with selected M0 and MII (M = Ni, Pd, Pt) metal precursors gave square-planar [MCl2{κ2E,P-E(tBu2bzam)pyrmPtBu2}] (M = Ni, Pd, Pt; E = Si, Ge), tetrahedral [Ni{κ2E,P-E(tBu2bzam)pyrmPtBu2}(cod)] (E = Si, Ge; cod = 1,5-cyclooctadiene) and triangular [M{κ2E,P-E(tBu2bzam)pyrmPtBu2}(PPh3)] (M = Pd, Pt; E = Si, Ge) complexes, showing that 1Si and 1Ge are excellent Si,P- and Ge,P-chelating ligands that, due to their large steric bulk, are able to stabilize three-coordinate Pd0 and Pt0 complexes.
In some applications, this compound(12080-32-9)Application In Synthesis of Dichloro(1,5-cyclooctadiene)platinum(II) is unique.If you want to know more details about this compound, you can contact with the author or consult more relevant literature.
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