Extended knowledge of 1787246-78-9

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Wang, Lei; Li, Sun; Bluemel, Marcus; Puttreddy, Rakesh; Peuronen, Anssi; Rissanen, Kari; Enders, Dieter published an article about the compound: (5aS,10bR)-2-(2,6-Diethylphenyl)-4,5a,6,10b-tetrahydro-2H-indeno[2,1-b][1,2,4]triazolo[4,3-d][1,4]oxazin-11-ium tetrafluoroborate( cas:1787246-78-9,SMILESS:CCC1=C(C(CC)=CC=C1)N2N=C3[N+]([C@]4([C@@]([H])(OC3)CC5=C4C=CC=C5)[H])=C2.F[B-](F)(F)F ).Application of 1787246-78-9. Aromatic heterocyclic compounds can be classified according to the number of heteroatoms or the size of the ring. The authors also want to convey more information about this compound (cas:1787246-78-9) through the article.

A novel NHC-catalyzed annulation protocol for the asym. synthesis of biol. important β-lactam fused spirocyclopentane oxindoles with four contiguous stereocenters, including two quaternary carbon centers, was developed. Alternatively, spirocyclopentane oxindoles containing an enaminone moiety can be achieved using the same starting materials, isatin-derived enals, and N-sulfonyl ketimines, in the presence of a slightly different NHC catalytic system. This switchable annulation strategy enables the selective assembly of both heterocyclic scaffolds with good yields and excellent enantioselectivities for a broad range of substrates.

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