The three-dimensional configuration of the ester heterocycle is basically the same as that of the carbocycle. Compound: Dichloro(1,5-cyclooctadiene)platinum(II)(SMILESS: C1=CCC/C=CCC/1.[Pt+2].[Cl-].[Cl-],cas:12080-32-9) is researched.HPLC of Formula: 7661-33-8. The article 《NHC-Au(I) complexes bearing trispyrazolyl borate (Tp) ligands: efficient platforms for bimetallic species》 in relation to this compound, is published in Dalton Transactions. Let’s take a look at the latest research on this compound (cas:12080-32-9).
Treatment of NHC-AuCl (NHC = IPr and IMes) complexes with equimolar amounts of KTpR2 (R = Me, H) salts in THF produces in high yields the heteroleptic complexes 3-6 with the general formula NHC-Au-TpR2. As the TpR ligand in complexes 3-6 features a k1-N type coordination toward the gold(I) center, the subsequent addition of group 10 and 11 metal precursors (NiII, PtII, CuII) results in the isolation of heterobimetallic Au/M complexes supported by TpR platforms. All new metal complexes have been fully characterized by elemental anal. and NMR spectroscopy, and in the case of 3, 4 and 6 by X-ray crystallog.
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