Most of the natural products isolated at present are heterocyclic compounds, so heterocyclic compounds occupy an important position in the research of organic chemistry. A compound: 7661-33-8, is researched, SMILESS is O=C1N(C2=CC=C(Cl)C=C2)CCC1, Molecular C10H10ClNOJournal, Organometallics called Dinuclear Copper(I) Complexes as Precatalysts in Ullmann and Goldberg Coupling Reactions, Author is Haldon, Estela; Alvarez, Eleuterio; Nicasio, M. Carmen; Perez, Pedro J., the main research direction is copper bisazaindolylmethane dinuclear complex preparation crystal structure; cross coupling catalyst copper bisazaindolylmethane dinuclear complex; Ullmann coupling catalyst copper bisazaindolylmethane dinuclear complex; Goldberg coupling catalyst copper bisazaindolylmethane dinuclear complex.Reference of 1-(4-Chlorophenyl)pyrrolidin-2-one.
The use of structurally well-characterized Cu(I) species as precatalysts in C-N and C-S bond forming reactions is described. Two new dinuclear Cu(I) complexes containing two isomeric ligands of bis(7-azaindolyl)methane were synthesized and fully characterized by NMR and x-ray diffraction studies. Both Cu(I) species exhibit a 1:1 Cu/L ratio and were used as precatalysts in the N-arylation of 2-pyrrolidinone and S-arylation of thiols with aryl iodides. The complexes efficiently catalyze these cross-coupling reactions, affording high yields of products under mild conditions.
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