In organic chemistry, atoms other than carbon and hydrogen are generally referred to as heteroatoms. The most common heteroatoms are nitrogen, oxygen and sulfur. Now I present to you an article called C-C* Platinum(II) Complexes with Electron-Withdrawing Groups and Beneficial Auxiliary Ligands: Efficient Blue Phosphorescent Emission, published in 2021-08-02, which mentions a compound: 12080-32-9, mainly applied to platinum cyclometalated aryl imidazolylidene complex diketonate borate preparation photoluminescence; crystal mol structure platinum cyclometalated aryl imidazolylidene diketonate borate; redox potential platinum cyclometalated aryl imidazolylidene diketonate borate; phosphorescence platinum cyclometalated aryl imidazolylidene diketonate borate, Synthetic Route of C8H12Cl2Pt.
Cyclometalated arylimidazolylidene platinum complexes with diketonate and dipyrazolylborate auxiliary ligands were prepared and examined for photoluminescence and photophys. properties. The combination of strong electron-withdrawing groups in cyclometalated N-heterocyclic carbene ligands (C-C*) with known beneficial auxiliary ligands in phosphorescent platinum(II) complexes leads to efficient light-to-deep-blue emission with quantum yields of up to 92%. All compounds were characterized and investigated regarding their photophys., electrochem., and thermal properties, and three complexes could addnl. be characterized by solid-state structures. D. functional theory calculations (PBE0/6-311G* with dispersion correction) are reported.
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